DBL 5587 2012-04-gb
DBL 5587 2012-04-gb
DBL 5587 2012-04-gb
Foreword
This Daimler-Benz Supply Specification contains general requirements for components in passenger cars
and commercial vehicles for elastomeric materials which are not already covered by existing component
DBLs, e.g. for the engine, transmission and major assembly area etc. DBL 5587 is the result of the
consolidation of the individual DBLs 5561, 5563, 5565, 5567, 5568 and DBL 5569 which no longer apply
to new design.
DBL 5587 shall therefore be regarded as a supplement. In particular, in the case of static and dynamic
gaskets and elastomer hoses, for example, special requirements are described in the appropriate
individual DBLs.
Changes
First edition
Contents
1 Scope ............................................................................................................................................... 2
2 Normative references ....................................................................................................................... 4
3 Terms and definitions ....................................................................................................................... 5
4 General requirements ....................................................................................................................... 5
5 Abbreviated material designation for documentation ....................................................................... 5
6 Technical data of polymers .............................................................................................................. 6
6.1 Permanent set tests ............................................................................................................................ 6
6.2 Technical data of polymers in as-supplied condition .......................................................................... 6
6.3 Resistance properties of polymers ..................................................................................................... 6
Annex A (normative) ...................................................................................................................................... 7
A.1 Technical data of polymers in as-supplied condition (I) ..................................................................... 7
Table 3 ........................................................................................................................................................... 7
A.2 Technical data of polymers in as-supplied condition (II) .................................................................... 8
Table 4 ........................................................................................................................................................... 8
Annex B (normative) ...................................................................................................................................... 9
B.1 Heat aging and ozone (I) .................................................................................................................... 9
Table 5 ........................................................................................................................................................... 9
B.2 Heat aging and ozone (II) ................................................................................................................. 10
Table 6 ......................................................................................................................................................... 10
Annex C (normative).................................................................................................................................... 11
C.1 Resistances (I) .................................................................................................................................. 11
Table 7 ......................................................................................................................................................... 11
C.2 Resistances (II) ................................................................................................................................. 12
Table 8 ......................................................................................................................................................... 12
C.3 Resistances (III) ................................................................................................................................ 13
Table 9 ......................................................................................................................................................... 13
Annex D (normative).................................................................................................................................... 14
Reference to DBLs "Not for new design" .................................................................................................... 14
Table 10 ....................................................................................................................................................... 14
1 Scope
This Daimler-Benz Supply Specification applies to elastomeric materials with general requirements for
components in passenger cars and commercial vehicles which are not already covered by existing
component DBLs, e.g. for the engine, transmission and major assembly area etc. DBL 5587 is the result
of the consolidation of the individual DBLs 5561, 5563, 5565, 5567, 5568 and DBL 5569 which no longer
apply to new design (also refer to Annex D).
DBL 5587 shall therefore be regarded as a supplement. In particular, in the case of static and dynamic
gaskets and elastomer hoses, for example, the appropriate individual DBLs shall be applied.
*) The cold reference value is a pure material characteristic. The temperatures indicated above as cold
reference value characterize the temperature at which the elastomer stiffens (by approximately 2.5
times in comparison with the standard atmosphere room temperature of 23 °C) and becomes hard.
This value does not necessarily mean that the function of a component no longer exists at temperatures
lower than the cold reference value. This depends on the mechanical stress. The cold reference value
therefore is not an application temperature of a component limited towards low temperatures.
The indication of the cold reference value is intended to show the differences between the elastomers of
the different product versions in the low-temperature range.
2 Normative references
The following referenced documents are indispensable for the application of this document. For dated
references, only the edition cited applies. For undated references, the latest edition of the referenced
document (including any amendments) applies.
DBL 5555 Supply Specification – Finished Parts and Semi-Finished Products Made of
Organic Polymer Materials - General Conditions and Test Methods
DBL 5561 Elastomer Parts Suitable for Thermal Stressing from 80 to 130 °C, with Moderate
Resistance to Lubricants and Fuels
DBL 5563 Elastomer Parts Suitable for Thermal Stressing from 70 to 120 °C, with Good
Resistance to Lubricants, Fuels and Coolant
DBL 5565 Elastomer Parts, Suitable for Thermal Stressing from 120 °C to 150 °C, with
Good Resistance to Lubricants and Fuels
DBL 5567 Elastomer Parts Heat-Tolerant to 140 to 175 °C; with Good Resistance to
Petroleum-Based Products
DBL 5568 Elastomer Parts Heat-Tolerant to 150 to 250 °C; Moderately Resistant to
Petroleum-Based Products
DBL 5569 Elastomer Parts Heat-Tolerant to 200 to 275 °C; with Good Resistance to
Automotive Fuels
DBL 8585 Supply Specification – Negative Substance List for the Selection of Materials
DIN 51604-2 Methanolic FAM Testing Fluid for Polymer Materials - Composition and
Requirements
DIN EN ISO 868 Plastics and Ebonite - Determination of Indentation Hardness by Means of a
Durometer (Shore Hardness)
DIN EN ISO 1183-1A Methods for Determining the Density of Non-Cellular Plastics
DIN EN 14214 Automotive Fuels – Fatty Acid Methyl Esters (FAME) for Diesel Engines –
Requirements and Test Methods
DIN ISO 34-1 Rubber, Vulcanized or Thermoplastic — Determination of Tear Strength
DIN ISO 48 Rubber, Vulcanized or Thermoplastic – Determination of Hardness (Hardness
Between 10 IRHD and 100 IRHD)
DIN ISO 1817 Rubber, Vulcanized - Determination of the Effect of Liquids
ISO 37 Rubber, Vulcanized or Thermoplastic — Determination of Tensile Stress-Strain
Properties
ISO 188 Rubber, Vulcanized or Thermoplastic – Accelerated Ageing and Heat Resistance
Tests
ISO 815-1 Rubber, Vulcanized or Thermoplastic – Determination of Compression Set
ISO 1431-1 Rubber, Vulcanized or Thermoplastic – Resistance to Ozone Cracking
PV : Product version
ACM : Acrylic rubber
AEM : Ethylene acrylic rubber
CR : Chloroprene rubber
DBL : Daimler Benz Supply Specification
DIN : Deutsches Institut für Normung (German Institute for Standardization)
DSC : Differential Scanning Calorimetry
DVR : Compression set
EN : European standard
EPDM : Ethylene Propylene Diene Monomer rubber
FAM : Fachausschuss für Mineralöl- und Brennstoffnormung (Expert Committee on Mineral Oil
and Fuel Standardization)
FKM : Fluororubber
FVMQ : Fluorosilicone rubber
HNBR per : Hydrogenated acryonitrile butadiene rubber, peroxydic crosslinking
IRHD : International Rubber Hardness Degrees
ISO : International Organization for Standardization
NBR : Nitrile butadiene rubber
NR : Natural rubber
RME : Rapeseed-oil methyl ester
VMQ : Silicone rubber
ZVR : Tension set
4 General requirements
For safety requirements, homologation (in particular, exhaust emissions) and quality, the existing statutory
requirements and laws shall be complied with. In addition, the relevant requirements of the Daimler Group
apply.
All materials, procedures, processes, components, and systems shall conform to the current regulatory
(governmental) requirements regarding regulated substances and recyclability. DBL 8585 shall be
observed.
For applications where the component is permanently subject to static or dynamic stress, long-term
deformation tests (compression or tension set) shall be carried out for the award of material approval after
42 days in hot air or the relevant service product/substance (also refer to Technical Data in Annexes).
Where the component geometry allows test pieces to be produced for compression set or tension set, tests
shall be performed on both the component and on sheet material. The relevant test values shall be
submitted by the supplier no later than 10 weeks before the time of initial sampling .
The resistance tests listed in Annex B with regard to resistance to heat aging and ozone (Tables 5 and 6)
are standard tests which are always required for approval according to a product version.
The resistance tests listed in Annex C with regard to resistance to service products and fuel (Tables 7 to 9)
shall only be performed partially in cases where the component can come into contact with a specific
service product (e.g. engine oil enriched with fuel, transmission oil, lubricating grease or similar) or with fuel.
The test conditions and the target values shall be agreed in each individual case with the Mercedes-Benz
development department responsible and/or PWT. In general, testing is performed for 42 days at maximum
continuous temperature.
Annex A (normative)
A.1 Technical data of polymers in as-supplied condition (I)
Table 3
Permitted
tolerance with
As-supplied condition Required limits reference to
sample value1)
Product version 00 10 20 21 30 Test method
CR,
Polymer NBR/CR NBR HNBR HNBR ECO
blend
Density g/cm3 ± 0,02 DIN EN ISO 1183-1, immersion method A
Hardness Shore A indicate when sampling ±5 DIN EN ISO 868, reading time 3 s
Micro hardness IRHD ±5 DIN ISO 48 M
Tensile strength, min. +5 / -2
Nominal hardness range
Shore A
≤ 50 8 10 – – 6 ISO 37
> 50..> 80 MPa 11 12 15 12 7 Dumb-bell type 2
≥ 80 – – Deviation
Elongation at break, min. Test speed 200 mm/min
Nominal hardness range
– – 280
Shore A
≤ 50 325 300 200 180 250 + 100
> 50..> 80 % 250 250 3 3 5 - 50
≥ 80 – 150
DIN ISO 34-1, method A, test piece thickness 2 mm
Tear strength, at least N/mm 6 6 – – 6 ±3
Subject specimen to shear
ISO 815-1, test piece type B from 2 mm sheet
Compression set
material (3 discs laminated),
Test temperature °C 100 100 125 125 125 ±2 method B;
Compression set value, max. % 50 50 45 50 45 ±5 Test duration (22+2) h
Cold reference (stiffness)
°C -30 -25 -15 -30 -30 ±3 DBL 5555 (DSC)
value
1) Refer to DBL 5555
耐热老化
Heat aging resistance Storage in
air oven in accordance with ISO
Test temperature 测试温度 °C 150 150 150 150 225
188
Test duration 测试时间 d 42 with forced air
circulation,
Tensile strength, min. 拉伸强度 MPa 7 10 4 4 6 +5 / -2 air speed
Change in tensile strength, max. % 30 30 30 30 30 0,25 to 3 m/s;
Elongation at break, min. 断裂伸长率 air changes >30/h
Nominal hardness range Shore
A
≤ 50 – – 125 125 – + 100
> 50 % 125 125 100 100 100 - 50
Change in elongation at break,
% 50 50 50 50 –
max. 断裂伸长率变化
Annex C (normative)
Annex D (normative)
Reference to DBLs "Not for new design"
Table 10
DBL PV replaced by PV
20 00
DBL 5561: 2003-07
26 00
12 10
DBL 5563: 2003-06 14 10
21 10
02 20
DBL 5565: 2004-01 02 DBL 5587: 2012-04 21
22 30
00 40
DBL 5567: 1995-12 10 40
30 50
10 60
DBL 5568: 1995-12 11 60
20 65
DBL 5569: 1995-12 00 70