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Formulas and Nomenclature

of
Ionic and Covalent Compounds
Adapted from McMurry/Fay, section 2.10, p. 56-63
and the 1411 Lab Manual, p. 27-31. (References)

Contents:
Types of Compounds
Types of Ions:
     Main-Group Metals (Groups IA, IIA, and IIIA)
     Transition (B-group) and Post-Transition (Group IVA and VA) Metals
     Main-Group Nonmetals (Groups IVA, VA, VIA, and VIIA)
     Polyatomic Ions
Writing Formulas of Ionic Compounds
Nomenclature of Ionic and Covalent Compounds
     1.  Binary Ionic Compounds Containing a Metal and a Nonmetal
     2.  Ionic Compounds Containing a Metal and a Polyatomic Ion
     3.  Acids and Acid Salts
     4.  Binary Covalent Compounds Between Two Nonmetals
     5.  Hydrocarbons
Molecular Masses from Chemical Formulas
References

Types of Compounds

Ionic compounds are compounds composed of ions, charged particles that form when an atom
(or group of atoms, in the case of polyatomic ions) gains or loses electrons.

 A cation is a positively charged ion

 An anion is a negatively charged ion.

Covalent or molecular compounds form when elements share electrons in a covalent bond to

form molecules. Molecular compounds are electrically neutral.
Ionic compounds are (usually) formed when a metal reacts with a nonmetal (or a polyatomic
ion).  Covalent compounds are formed when two nonmetals react with each other.  Since
hydrogen is a nonmetal, binary compounds containing hydrogen are also usually covalent
compounds.

 Metal  +  Nonmetal  —>  ionic compound (usually)

 Metal  +  Polyatomic ion  —>  ionic compound (usually)
 Nonmetal  +  Nonmetal  —>  covalent compound (usually)
 Hydrogen  +  Nonmetal  —>  covalent compound (usually)

Types of Ions:

Main-Group Metals (Groups IA, IIA, and IIIA)

Group IA, IIA, and IIIA metals tend to form cations by losing all of their outermost (valence)
electrons. The charge on the cation is the same as the group number. The cation is given the
same name as the neutral metal atom.

Ions of Some Main-Group Metals (Groups IA - IIIA)

Group Element Cation Ion name

IA H H+ hydrogen ion
  Li Li+ lithium ion
  Na Na+ sodium ion
  K K+ potassium ion
  Cs Cs+ cesium ion
IIA Mg Mg2+ magnesium ion
  Ca Ca2+ calcium ion
  Sr Sr2+ strontium ion
  Ba Ba2+ barium ion
IIIA Al Al3+ aluminum ion

Transition (B-group) and Post-Transition (Group IVA and VA) Metals

These elements usually form ionic compounds; many of them can form more than one cation.
(The charges of the common transition metals must be memorized; Group IV and V metal
cations tend to be either the group number, or the group number minus two.)

 Many of these ions have common or trivial names formed from the stem of the element
name (the Latin name in some cases) plus the ending -ic or -ous. (-ic endings go with the
higher possible charge, -ous endings go with the lower possible charge).
 The systematic names (also known as the Stock system) for these ions are derived by
naming the metal first, followed in parentheses by the charge written in Roman numerals.
For the metals below that typically form only one charge, it is not usually necessary to
specify the charge in the compound name.
 For example, iron can form two possible ions, 2+ and 3+. The Fe2+ ion is known as the
ferrous ion (common) or the iron(II) ion (systematic); the Fe3+ ion is known as the ferric
ion (common) or the iron(III) ion (systematic).

The mercury(I) cation is a special case; it consists of two Hg+ ions joined together, and so is
always found as Hg22+. (Hence, mercury(I) chloride is Hg2Cl2, not HgCl, while mercury (II)
chloride is HgCl2.)

Ions of Some Transition Metals and Post-Transition Metals (Groups IVA and VA)

Metal Ion Systematic name Common name

Cadmium Cd2+ cadmium ion  
Chromium Cr2+ chromium(II) ion chromous ion
  Cr3+ chromium(III) ion chromic ion
Cobalt Co2+ cobalt(II) ion cobaltous ion
  Co3+ cobalt(III) ion cobaltic ion
Copper Cu+ copper(I) ion cuprous ion
  Cu2+ copper(II) ion cupric ion
Gold Au3+ gold(III) ion  
Iron Fe2+ iron(II) ion ferrous ion
  Fe3+ iron(III) ion ferric ion
Manganese Mn2+ manganese(II) ion manganous ion
  Mn3+ manganese(III) ion manganic ion
Mercury Hg22+ mercury(I) ion mercurous ion
  Hg2+ mercury(II) ion mercuric ion
Nickel Ni2+ nickel(II) ion nickelous ion
Silver Ag+ silver ion  
Zinc Zn2+ zinc ion  
—————— ——— ———————— ————————
 Tin Sn2+ tin(II) ion stannous ion
  Sn4+ tin(IV) ion stannic ion
Lead Pb2+ lead(II) ion plumbous ion
  Pb4+ lead(IV) ion plumbic ion
Bismuth Bi3+ bismuth(III) ion  
  Bi5+ bismuth(V) ion  

Main-Group Nonmetals (Groups IVA, VA, VIA, and VIIA)

Group IVA, VA, VIA, and VIIA nonmetals tend to form anions by gaining enough electrons to
fill their valence shell with eight electrons. The charge on the anion is the group number minus
eight. The anion is named by taking the element stem name and adding the ending -ide.

Ions of Some Nonmetals (Groups IVA - VIIA)

Group Element Anion Ion name

IVA C C4- carbide ion
  Si Si4- silicide ion
VA N N3- nitride ion
  P P3- phosphide ion
  As As3- arsenide ion
VIA O O2- oxide ion
  S S2- sulfide ion
VIA Se Se2- selenide ion
  Te Te2- telluride ion
VIIA F F- fluoride ion
  Cl Cl- chloride ion
  Br Br- bromide ion
  I I- iodide ion
IA H H- hydride ion

Polyatomic Ions
Polyatomic ions are ions that are composed of two or more atoms that are linked by covalent
bonds, but that still have a net deficiency or surplus of electrons, resulting in an overall charge on
the group. 

A metal plus a polyatomic ion yields an ionic compound.

Formulas and Names of Some Polyatomic Ions

Formula Name
NH4+ ammonium
H3O+ hydronium
OH- hydroxide
CN- cyanide
O22- peroxide
N3- azide
NO2- nitrite
NO3- nitrate
ClO- hypochlorite
ClO2- chlorite
ClO3- chlorate
ClO4- perchlorate
MnO4- permanganate
C2H3O2- acetate (OAc-)
C2O42- oxalate
CO32- carbonate
OCN- cyanate
SCN- thiocyanate
S2O32- thiosulfate
CrO42- chromate
Cr2O72- dichromate
SO42- sulfate
SO32- sulfite
PO43- phosphate
PO43- monohydrogen phosphate
PO43- dihydrogen phosphate
HCO3- hydrogen carbonate (bicarbonate)
HSO4- hydrogen sulfate (bisulfate)
HSO3- hydrogen sulfite (bisulfite)

 
There are some regularities in the names of these polyatomic ions.

 Thio- implies replacing an oxygen atom with a sulfur atom:

OCN- cyanate   SO42- sulfate

SCN- thiocyanate   S2O32- thiosulfate

 Replacing the first element in the formula with another element from the same group
gives a polyatomic ion with the same charge, and a similar name:

Group VIIA   Group VIA

ClO3- chlorate   SO42- sulfate
BrO3- bromate   SeO42- selenate
IO3- iodate   TeO42- tellurate
Group VA*   Group IVA
PO43- phosphate   CO32- carbonate
AsO43- arsenate   SiO32- silicate

* But note that nitrogen does not follow this pattern (i.e., nitrate, NO3-)

 Some nonmetals form a series of polyatomic ions with oxygen (all having the same
charge): ClO-, hypochlorite; ClO2-, chlorite; ClO3-, chlorate; ClO4-, perchlorate.
 The  -ate forms (formula and charge) must be memorized.  In some cases, the -
ate form has three oxygens, and in some cases four oxygens.  The charge is the
same for the entire series.
 The -ite form has one less oxygen that the -ate form.
 The hypo- stem -ite form has two less oxygens than the -ate form.
 The per- stem -ate form has one more oxygen than the -ate form.
 The -ide form is the monatomic anion (see Main-Group Nonmetals)
 The general rules for such series are summarized in the table below:

Formula Name
XOny- stem + -ate
XOn-1y- stem + -ite
XOn-2y- hypo- + stem + -ite
XOn+1y- per- + stem + -ate
Xy- stem + -ide
 Examples
SO42- sulfate
SO32- sulfite
SO22- hyposulfite
SO52- persulfate
S2- sulfide

Writing Formulas of Ionic Compounds

1. The cation is written first, followed by the monatomic or polyatomic anion.

2. The subscripts in the formula must produce an electrically neutral formula unit. (That is,
the total amount of positive charge must equal the total amount of negative charge.)
3. The subscripts should be the smallest set of whole numbers possible.
4. If there is only one of a polyatomic ion in the formula, do not place parentheses around it;
e.g., NaNO3, not Na(NO3). If there is more than one of a polyatomic ion in the
formula, put the ion in parentheses, and place the subscript after the parentheses; e.g.,
Ca(OH)2, Ba3(PO4)2, etc.

Remember the Prime Directive in writing formulas:

Ca(OH)2  CaOH2 !

Examples
Cation Anion Formula
Na+ Cl- NaCl
Ca2+ Br- CaBr2
Na+ S2- Na2S
Mg2+ O2- MgO
Fe3+ O2- Fe2O3
Na+ SO42- Na2SO4
Mg2+ NO3- Mg(NO3)2
NH4+ SO42- (NH4)2SO4

 
 Nomenclature of Ionic and Covalent Compounds

1. Binary Ionic Compounds Containing a Metal and a Nonmetal. 

A binary compound is a compound formed from two different elements. There may or may not
be more than one of each element. A diatomic compound (or diatomic molecule) contains two
atoms, which may or may not be the same.

Cl2 Not binary (only one type of atom), but diatomic (two atoms)
BrCl Binary (two different elements), and diatomic (two atoms)
H2O Binary (two different elements), but not diatomic (more than two atoms)
CH4 Binary (two different elements), but not diatomic (more than two atoms)
CHCl3 Neither binary nor diatomic

Metals combine with nonmetals to give ionic compounds. When naming binary ionic

compounds, name the cation first (specifying the charge, if necessary), then the nonmetal anion
(element stem + -ide).

Do NOT use prefixes to indicate how many of each element is present; this information is
implied in the name of the compound.

Examples
NaCl  Sodium chloride
AlBr3  Aluminum bromide
Ca3P2  Calcium phosphide
SrI2  Strontium iodide
 Iron(II) chloride or ferrous chloride
FeCl2      The cation charge must be specified 
     since iron can form more than one charge.

2. Ionic Compounds Containing a Metal and a Polyatomic Ion.

Metals combine with polyatomic ions to give ionic compounds. Name the cation first (specifying
the charge, if necessary), then the polyatomic ion as listed in the table above (or as derived from
the rules which were given).

Do NOT use prefixes to indicate how many of each element is present; this information is
implied in the name of the compound.

Examples
 NaOH Sodium hydroxide
Ca(NO3)2 Calcium nitrate
K3PO4 Potassium phosphate
(NH4)2SO4 Ammonium sulfate
NH4F Ammonium fluoride
CaCO3 Calcium carbonate
Mg(C2H3O2)2 Magnesium acetate
Fe(OH)3 Iron(III) hydroxide or ferrous hydroxide
Cr3(PO4)2  Chromium(II) phosphate
CrPO4 Chromium(III) phosphate
NaHCO3 Sodium hydrogen carbonate or sodium bicarbonate

3. Acids and Acid Salts.

Acids are compounds in which the "cation" is H+. (These are not really ionic compounds, but
we'll get into that later.) These can be named as compounds as in the previous cases, e.g., HCl is
"hydrogen chloride", but are more frequently given special "acid names" (especially when
dissolved in water, which is most frequently the case.) The word "hydrogen" is omitted, the word
"acid" is added to the end; the suffix is changed as shown below:

Compound name Acid name

-ate -ic + acid
   
-ite -ous + acid
-ide hydro- -ic + acid

Examples
Example Compound Name Acid name
HClO3 hydrogen chlorate chloric acid
H2SO4 hydrogen sulfate sulfuric acid
HClO2 hydrogen chlorite chlorous acid
HCl hydrogen chloride hydrochloric acid

Acid salts are ionic compounds that still contain an acidic hydrogen, such as NaHSO4. In naming
these salts, specify the number of acidic hydrogens in the salt. For instance:
 Examples
NaHSO4 sodium hydrogen sulfate
NaH2PO4 sodium dihydrogen phosphate
Na2HPO4 sodium hydrogen phosphate
NaHCO3 sodium hydrogen carbonate or sodium bicarbonate

The prefix bi- implies an acidic hydrogen: thus, NaHCO3 is sodium bicarbonate (or sodium
hydrogen carbonate); NaHSO3 is sodium bisulfite (or sodium hydrogen sulfite), etc.

4. Binary Covalent Compounds Between Two Nonmetals.

Two nonmetals combine to form a covalent  or molecular compound (i.e., one that is held

together by covalent bonds which result from the sharing of electrons).

In many cases, two elements can combine in several different ways to make completely different
compounds. (This cannot happen with ionic compounds, except in the cases of metals that can
form more than one charge.) For instance, carbon can share electrons with one oxygen to make
CO (carbon monoxide), or with two oxygens to make CO2 (carbon dioxide). For this reason, it is
necessary to specify how many of each element is present within the compound.

 The formula is written with the more electropositive element (the one further to
the left on the periodic table) placed first, then the more electronegative element
(the one further to the right on the periodic table).

[Important exception: when the compound contains oxygen and a halogen, the halogen is placed
first. If both elements are in the same group, the one with the higher period number is named
first.]

 The first element in the formula is given the neutral element name, and the second
one is named by replacing the ending of the neutral element name with -ide. A
prefix is used in front of each element name to indicate how many atoms of that
element are present:

1 mono-
2 di-
3 tri-
4 tetra-
5 penta-
6 hexa-
 7 hepta-
8 octa-
9 nona-
10 deca-

 If there is only one of the first element in the formula, the mono- prefix is
dropped.

Examples
SO2 sulfur dioxide
SO3 sulfur trioxide
N2O dinitrogen monoxide
NO nitrogen monoxide
NO2 nitrogen dioxide
N2O4 dinitrogen tetroxide
N2O5 dinitrogen pentoxide

5. Hydrocarbons.

Hydrocarbons contain only carbon and hydrogen, and are the simplest type of organic
compound (a compound containing carbon). 

Alkanes  contain only carbon-carbon single bonds, and are the simplest of the hydrocarbons. 

The simplest of the alkanes are the straight-chain alkanes, in which all of the carbon atoms are
linked together in a line, with no branches. (They don't get simpler than that!) 

Alkanes have the general formula CnH2n+2, and are the constituents of several important fuels,
such as natural gas and gasoline.

Organic chemistry has a completely different set of rules for nomenclature; straight-chain

alkanes are named using a prefix plus the suffix -ane. Notice that after C4, the prefixes are the
same as those listed above for binary covalent compounds.

CH4 methane
C2H6 ethane
C3H8 propane
C4H10 butane
 C5H12 pentane
C6H14 hexane
C7H16 heptane
C8H18 octane
C9H20 nonane
C10H22 decane

(Because of the tremendous variety of possible organic compounds [over six million, and still
counting], the rules for naming structures more complex than the staight-chain alkanes
are muchmore elaborate than those that those we've seen so far, but those rules will be discussed
when you take organic chemistry.) 

Molecular Masses from Chemical Formulas

The molecular mass, or molecular weight of a compound (measured in atomic mass units,

amu) is obtained by adding up the atomic masses of all of the atoms present within a unit of the
substance. 

For ionic compounds, the term formula mass or formula weight is used instead, since there
aren't really any molecules present.

The molecular/formula mass is numerically equal to the mass of one mole of the substance.

For example, the molecular weight of water would be obtained by the following process:

Molecular mass of H2O = (2 x atomic mass of H) + (1 x atomic mass of O)

                                       = (2 x 1.00797) + (1 x 15.9994) amu
                                       = 18.02 amu

References
 John McMurry and Robert C. Fay, Chemistry, 4th ed.  Upper Saddle River, NJ: 
Pearson/Prentice Hall, 2004, p. 56-63.

George E. Shankle & Harold W. Peterson, Laboratory Manual for Chemistry 1411. 

University publication at Angelo State University, San Angelo, TX  76909, p. 27-31.