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    Gravimetric Tuto Ans PDF

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    Nisha Lauren Vishvanath
    This document provides 11 practice problems related to gravimetric analysis in analytical chemistry. The problems cover calculating masses of elements in compounds, determining minimum sample sizes, writing solubility product expressions, and calculating ion concentrations based on solubility product constants.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Gravimetric Tuto Ans PDF

    Uploaded by

    Nisha Lauren Vishvanath
    342 views2 pages
    This document provides 11 practice problems related to gravimetric analysis in analytical chemistry. The problems cover calculating masses of elements in compounds, determining minimum sample sizes, writing solubility product expressions, and calculating ion concentrations based on solubility product constants.

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    Gravimetric Tuto Ans.pdf

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    This document provides 11 practice problems related to gravimetric analysis in analytical chemistry. The problems cover calculating masses of elements in compounds, determining minimum sample sizes, writing solubility product expressions, and calculating ion concentrations based on solubility product constants.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    342 views2 pages

    Gravimetric Tuto Ans PDF

    Uploaded by

    Nisha Lauren Vishvanath
    This document provides 11 practice problems related to gravimetric analysis in analytical chemistry. The problems cover calculating masses of elements in compounds, determining minimum sample sizes, writing solubility product expressions, and calculating ion concentrations based on solubility product constants.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    SKA3013 (ANALYTICAL CHEMISTRY)

    TUTORIAL (GRAVIMETRIC)

    1. Calculate the weight of sodium present in 50.0 g Na2SO4?


    16.20 g

    2. If the salt in Problem 1 is analysed by precipitating and weighing BaSO4, what mass of
    precipitate would be obtained?

    82.04 g

    3. How many grams of CuO and As2O3 are obtained in 1.00 g Paris green,
    Cu(C2H3O2)2•3Cu(AsO2)2?
    CuO = 0.315 g
    As2O3 = 0.5846 g

    4. Iron in an ore is to be analysed gravimetrically by weighing as Fe2O3. It is desired that


    the results be obtained to four significant figures. If the iron content ranges between
    11 and 15%, what is the minimum size sample that must be taken to obtain 100.0 mg
    of precipitate?
    0.4666 g

    5. What weight of Fe2O3 precipitate would be obtained from 0.4823 g sample of iron wire
    that is 99.89 % pure?
    0.688 g

    6. How much of BaCl2. 2H2O are needed to precipitate all sulphate ions in 13.340 gram
    of Fe2 (SO4)3 sample?
    24.32 g

    7. 5 g mineral contain CuS. Sulphurs in the mineral are converted to sulphate ions and
    then precipitated to BaSO4. The precipitate obtained is 1.5 g. How many percent of
    CuS in the mineral?

    12.36%

    PREPARED BY DR MAZLINA MUSA


    SKA3013 (ANALYTICAL CHEMISTRY)

    8. 1.615 g of iron ore sample was analysed gravimetrically by dissolved in concentrated


    hydrochloric acid and precipitated with ammonia. The Fe(III) precipitate was formed
    is Fe2O3. X H2O. After filtration, the precipitate was heated at higher temperature to
    produce 0.5494 g of pure Fe2O3. Determine the percentage of iron in Fe3O4 in the
    sample.
    32.88 %

    9. Write the solubility product expressions for the following :


    a) AgSCN

    AgSCN Ag+ + SCN-

    Ksp = [Ag+] [SCN-]

    b) La(IO3)3

    La(IO3)3 La3+ + 3IO-


    Ksp = [La3+] [IO-]3

    c) Bi2S3

    Bi2S3 2Bi3+ + 3S2-


    Ksp = [Bi3+]2 [S2-]3

    10. What is the concentration of Ag+ and CrO42-in a saturated solution of Ag2CrO4 if given Ksp
    = 1.1 x 10-12 ?

    [Ag+] = 1.34 x 10-4 M

    [CrO42-] = 6.5 x 10-5 M

    11. What must be the concentration of PO43- to just start precipitating Ag3PO4 in 0.10 M
    AgNO3 solution if Ksp = 1.3 x 10-20?
    The concentration of PO43- must > 1.3 x 10-17 M.

    PREPARED BY DR MAZLINA MUSA

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