Search Results (8,324)

In this study, we report the synthesis and characterization of a novel photocatalyst composite composed of functionalized carbon nanotubes (f-CNT) and phenyl-modified graphitic carbon nitride (PhCN). The incorporation of the phenyl group extends the absorption range into the visible spectrum compared to pure g-C₃N₄. Additionally, the formation of the heterostructure in the f-CNT/PhCN composite exhibits improved charge transfer efficiency, facilitating the separation and transfer of photogenerated electron-hole pairs and reducing recombination rates. The photocatalytic performance of this composite was evaluated by the degradation of Rhodamine B (RhB) under visible light irradiation. The f-CNT/PhCN composite exhibits remarkable efficiency in degrading RhB, achieving 60% degradation after 4 h, and 100% after 24 h under low-power white LED excitation. This represents a substantial improvement over the non-functionalized CNT/PhCN composite, which shows much lower performance. In contrast, pure PhCN demonstrates very little activity. Structural and optical properties were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), Raman spectroscopy, and UV–Vis spectroscopy. Time-resolved photoluminescence measurements were used to study the behavior of photoexcited carriers, confirming that the composite improves charge transfer efficiency for photogenerated carriers by approximately 30%. The results indicate that the functionalization of CNTs significantly enhances the photocatalytic properties of the composite, making f-CNT/PhCN a promising candidate for environmental remediation applications, particularly in the degradation of organic pollutants in wastewater. Full article

Power cyber–physical systems such as multi-area power systems (MAPSs) have gained considerable attention due to their integration of power electronics with wireless communications technologies. Incorporating a communication setup enhances the sustainability, reliability, and efficiency of these systems. Amidst these exceptional benefits, such systems’ distributed nature invites various cyber-attacks. This work focuses on the equal power sharing of MAPSs in the event of false data injection (FDI) attacks. The proposed work uses a sliding mode control (SMC) mechanism to ensure timely detection of challenges such as FDI attacks and load change, making MAPSs reliable and secure. First, a SMC-based strategy is deployed to enable the detection and isolation of compromised participants in MAPS operations to achieve equal power sharing. Second, time-varying FDI attacks on MAPSs are formulated and demonstrate their impact on equal power sharing. Third, a robust adaptive sliding mode observer is used to accurately assess the state of the MAPS to handle state errors robustly and automatically adjust parameters for identifying FDI attacks and load changes. Lastly, simulation results are presented to explain the useful ability of the suggested method. Full article

Fly ash (FA) is the main solid waste emitted from coal-fired power plants. Due to its high yield, low utilization rate, and occupation of a large amount of land, it exerts enormous pressure on the Earth’s environment. With the deepening of the concept of sustainable development, exploring the reuse of industrial waste such as FA has become a key strategy. If FA can be combined with commonly used jewelry in people’s lives, it will be of great significance to promote the high-net-worth utilization of FA. Therefore, this study synthesized a fly-ash-based composite material with color-changing function and combined it with necklaces as the main material. In the first stage, after blending fly ash and slag, an alkaline activator with a total mass of 10% was added. When the proportion of fly ash was 60%, the compressive strength of the prepared fly-ash-based composite material reached 10.1 MPa. This was attributed to the reaction between sodium silicate in the alkaline activator and free CaO, MgO, and other substances in the fly ash to form hydrated silicate colloids, which solidify the fly ash and transform it into a complex three-dimensional network skeleton. In the second stage, a UV resistant coating with thermochromic function was obtained by blending acrylic resin, TiO₂, and a thermosensitive color-changing agent. It was applied to the surface of fly-ash-based composite materials, and the results showed that as the content of the color-changing agent increased, the number of pores on the surface of the coating gradually decreased. When the content of color-changing agent was 10%, the prepared 10%FAB not only had good surface color but also had good thermal stability, UV absorption ability, superhydrophobicity, and mechanical properties. Therefore, 10%FAB was selected as the basic material for jewelry design. In the third stage, the traditional Chinese technique of “gold inlaid with jade” was utilized to develop jewelry applications for the FA composites. As such, 10%FAB was processed into necklaces, which not only had modern design aesthetics but also had good color-changing effects above 30 °C. And after a long period of UV aging experiments, the necklace did not show any wrinkles, bubbles, or other phenomena. Due to the excitation of TiO₂ hole–electron pairs, the necklace’s UV absorption ability was further improved. This study demonstrates the potential application of industrial waste in decorative products, expands the high-end utilization of fly ash as a low-cost material, and provides new ideas for building a low-carbon lifestyle. Full article

The development of supercapacitors with ultrahigh power density, high energy density, and compatible integration for wearable microelectronic devices is significant but challenging. Herein, a bimetallic metal–organic framework (Ni/Co-MOF) with oriented nanosheets was obtained via triethylamine (TEA) guiding using a hydrothermal treatment, in which the TEA guides the vertically oriented array structures of the Ni/Co-MOF and ensures a fast ion/electron transmission path. Subsequently, an asymmetric supercapacitor was rationally designed by applying the bimetallic MOF cathode and an activated carbon (AC) anode. The obtained Ni/Co-MOF sample offers a high storage capacity of 2034 F g⁻¹ at 0.5 A g⁻¹ by harnessing the optimized Ni/Co-MOF with uniformly oriented nanosheet arrays. The constructed asymmetric supercapacitors exhibited a large voltage window of 1.4 V in 3.0 M KOH and an outstanding energy density of 29.5 Wh kg⁻¹ at a power density of 199.1 W kg⁻¹ was obtained, with a remarkable capacitance retention of 89% after 2000 cycles. Full article

Two novel membranes based on collagen and two polyphenols, taxifolin pentaglutarate (TfG5) and a conjugate of taxifolin with glyoxylic acid (DfTf), were prepared. Fourier transform infrared spectroscopy examination confirmed the preservation of the triple helical structure of collagen. A scanning electron microscopy study showed that both materials had a porous structure. The incorporation of DfTf into the freeze-dried collagen matrix increased the aggregation of collagen fibers to a higher extent than the incorporation of TfG5, resulting in a more compact structure of the material containing DfTf. It was found that NIH/3T3 mouse fibroblasts were attached to, and relatively evenly spread out on, the surface of both newly obtained membranes. In addition, it was shown that the membranes enhanced skin wound healing in rats with a chemical burn induced by acetic acid. The treatment with the materials led to a faster reepithelization and granulation tissue formation compared with the use of other agents (collagen without polyphenols and buffer saline). It was also found that, in the wound tissue, the level of thiobarbituric acid reactive substances (TBARS) was significantly higher and the level of low-molecular-weight SH-containing compounds (RSH) was significantly lower than those in healthy skin, indicating a rise in oxidative stress at the site of injury. The treatment with collagen membranes containing polyphenols significantly decreased the TBARS level and increased the RSH level, suggesting the antioxidant/anti-inflammatory effect of the materials. The membrane containing TfG5 was more effective than other ones (the collagen membrane containing DfTf and collagen without polyphenols). On the whole, the data obtained indicate that collagen materials containing DfTf and TfG5 have potential as powerful therapeutic agents for the treatment of burn wounds. Full article

This paper proposes the design and construction of the prototype of a solid-state relay (SSR) that is controlled remotely through an interface developed in an Android application using a WIFI connection. Likewise, the prototype has a system for measuring electrical variables such as voltage, current, and power factor, whose values are also visualized in the application for monitoring the system’s load. Experimental results demonstrate the effective control of various load profiles, including resistive and resistive–inductive loads. The SSR successfully regulates the firing angle of an electronic device called TRIAC, allowing precise control over the load. Key features include a network snubber and heatsink, enhancing the durability and reliability of the system. The main contribution of this work is the integration of IoT-based remote control and monitoring with a robust SSR design, offering enhanced functionality and reliability for domotic applications. This integration facilitates improved productivity, resource management, and equipment monitoring in smart home environments, addressing the current gap in the availability of intelligent SSR solutions. Full article

Lithium-ion batteries have become a beacon in modern energy storage, powering from small electronic devices to electric vehicles (EVs) and critical medical equipment. Since their commercial introduction in the 1990s, significant advancements in materials science and engineering have enhanced battery capacity, safety, and lifespan. However, the complexity of lithium-ion battery dynamics has necessitated the development of advanced charging and control strategies to optimize performance, safety, and longevity. This work proposes a comparative analysis of three advanced control methods for lithium-ion battery charging: reinforcement learning, fuzzy logic, and classic proportional–integral–derivative (PID) control. Traditional charging methods often fail to address the complexities of battery dynamics, leading to suboptimal performance. Our study evaluates these intelligent control strategies using MATLAB-Simulink simulations to enhance charging efficiency, speed, and battery lifespan. The findings indicate that reinforcement learning offers superior adaptability, fuzzy logic provides robust handling of nonlinearity, and PID control ensures reliable performance with minimal computational resources. Full article

The paper proposes a new local method of controlling the on-load tap changer (OLTC) of a transformer to mitigate negative voltage phenomena in low-voltage (LV) networks with a high penetration of photovoltaic (PV) installations. The essence of the method is the use of the load compensation (LC) function with settings determined via artificial neural network (ANN) algorithms. The proposed method was compared with other selected local methods recommended in European regulations, in particular with those currently required by Polish distribution system operators (DSOs). Comparative studies were performed using the model of the 116-bus IEEE test network, taking into account the unbalance in the network and the voltage variation on the medium voltage (MV) side. Full article

The article considers the problem of an influence of partial shading on the characteristics of photovoltaic modules (PV modules). Different manners of connections of silicon solar cells contained in such modules are considered, e.g., classical PV modules (I and II generation of modules) and modules made using half-cut technology (III generation of modules). A model of PV modules was proposed. This model has the form of a network for the SPICE program and takes into account the influence of partial shading of the PV module caused by clouds or terrain and architectural obstacles on its current and voltage. The form of the model was described, and the DC characteristics of the considered classical and half-cut modules, calculated using the formulated model, were compared to the measurement results under different shading conditions. Some calculations using the proposed model were performed for different methods to connect solar cells in PV modules. The obtained results were discussed. Full article

DC converter stations have a high voltage level, a long transmission distance, and complex internal equipment, and contain power electronic devices, which seriously endanger the stable operation of the system itself and the active distribution network at the receiving end when faults occur. Accurate fault analysis and diagnosis are critical to the safe and stable operation of power systems. Traditional fault diagnosis methods often rely on a single source of information, leading to issues such as insufficient information utilization and incomplete diagnostic scope when applied to DC transmission systems. To address these problems, a fault diagnosis method for converter stations based on preliminary identification of the fault range and the fusion of evidence information of the switch signal and electrical quantity is proposed. First, the preprocessing of converter station sequential event recording (SER) events and a statistical analysis of event characteristics are completed to initially determine the range of the fault.Then, a fuzzy Petri net model and a BP neural network model are constructed on the basis of the fault data from a real-time digital simulation system (RTDS), and the corresponding evidence information of the switch signal and electrical quantity are obtained via iterative inference and deep learning methods. Finally, on the basis of D-S evidence theory, a comprehensive diagnosis result is obtained by fusing the switch and electric evidence information. Taking the fault data of a DC converter station as an example, the proposed method is analyzed and compared with the traditional method, which is based on single information. The results show that the proposed method can reliably and accurately identify fault points in the protected area of the converter station. Full article

An extreme bandgap Al_0.64Ga_0.36N quantum channel HEMT with Al_0.87Ga_0.13N top and back barriers, grown by MOCVD on a bulk AlN substrate, demonstrated a critical breakdown field of 11.37 MV/cm—higher than the 9.8 MV/cm expected for the channel’s Al_0.64Ga_0.36N material. We show that the fraction of this increase is due to the quantization of the 2D electron gas. The polarization field maintains electron quantization in the quantum channel even at low sheet densities, in contrast to conventional HEMT designs. An additional increase in the breakdown field is due to quantum-enabled real space transfer of energetic electrons into high-Al barrier layers in high electric fields. These results show the advantages of the quantum channel design for achieving record-high breakdown voltages and allowing for superior power HEMT devices. Full article

A phase change materials (PCM)-based heat sink is an effective way to cool intermittent high-power electronic devices in aerospace applications such as airborne electronics and aircraft external carry. Optimizing the heat sink is significant in designing a compact and efficient system. This paper proposes an optimization procedure for the PCM/expanded graphite (EG)-based heat sink to minimize the temperature of the heat source. The numerical model is built to estimate the thermal response, and a surrogate model is fitted using the Kriging model. An optimization algorithm is constructed to predict the optimum parameters of the heat sink, and the effects of heat sink volume, heat flux, and working time on the optimal parameters of the heat sink are investigated. This shows that the numerical results agree well with the experimental data, and the proposed optimization method effectively obtains the optimal EG mass fraction and the geometric dimensions of the PCM enclosure. The optimal EG mass fraction increases with the rise in heat sink volume and decreases with the increase in heat flux and working time. The optimal ratio of the height to the length of the heat sink is 0.43. This study provides practical guidance for the optimal design of a PCM/EG-based heat sink. Full article

This paper presents a new means to control the processes involving energy conversion. Electric machines fed by electronic converters provide a useful power defined by the inner product of two generalized energetic variables: effort and flow. The novelty in this paper is controlling the desired energetic variables by a Data-Driven Control (DDC) law, which comprises the effort and flow and the corresponding process control. The same desired useful power might be obtained with different controls at different efficiencies. Solving the regularization problem is based on building a knowledge database that contains the maximum efficiency points. Knowing a reasonable number of optimal efficiency operation points, an interpolation Radial Base Function (RBF) control was built. The RBF algorithm can be found by training and testing the optimal controls for any admissible operation points of the process. The control scheme developed for Permanent Magnet Synchronous Motor (PMSM) has an inner DDC loop that performs converter control based on measured speed and demanded torque by the outer loop, which handles the speed. A comparison of the DDC with the Model Predictive Control (MPC) of the PMSM highlights the advantages of the new control method: the method is free from the process nature and guarantees higher efficiency. Full article

The weakness of the fiber–matrix interface restricts the practical application of basalt fiber (BF) as a reinforcing material. In order to improve the interfacial adhesion between the BF and epoxy matrix, surface activation of the BF was carried out using low-pressure O₂ and H₂-Ar plasma under various conditions. The interfacial shear strength (IFSS), evaluated by a micro-droplet de-bonding test, was adopted to demonstrate the bonding effects at the BF/epoxy interphase. Compared to bare BF, the IFSS between the modified fibers and epoxy matrix was efficiently improved with an increment of 38.4% and 14.4% for O₂ plasma and H₂-Ar plasma treatment, respectively. Scanning Electron Microscope (SEM) and Atomic Force Microscopy (AFM) analysis indicated that H₂-Ar plasma-treated BF had a much rougher and more rugged surface than O₂ plasma-treated samples. X-ray Photoelectron Spectroscopy (XPS) and surface energy results revealed that O₂ plasma activation could effectively increase the content of oxygenous groups on the BF surface, thus resulting in a higher total surface energy value. Based on the results, O₂ plasma modification at a power of 200 W and pressure of 80 Pa for 0.5 min was considered to be the most favorable condition for the surface activation of BF. Full article

In the present study, polysaccharides were isolated from the leaves (WSPRaL) and stems (WSPRaS) of Rhamnus alaternus with yields of 3% and 3.25% for WSPRaS and WSPRaL, respectively. Crude WSPRaL was composed of proteins (260.740 ± 0.98 µg/mg), lipids (53.34 ± 2.38 µg/mg), total sugars (482.716 ± 3.02 µg/mg), and reducing sugars (420.240 ± 1.68 µg/mg). In contrast, WSPRaS contained proteins (269.629 ± 1.48 µg/mg), lipids (13.33 ± 0.28 µg/mg), total sugars (569.135 ± 3.82 µg/mg), and reducing sugars (531.732 ± 2.59 µg/mg). FTIR, TLC, and HPLC analyses revealed that the carbohydrate fraction of WSPRaS consisted mainly of glucuronic acid, glucose, galactose, xylose, mannose, and arabinose, whereas WSPRaL consisted of galacturonic acid, sucrose, glucose, rhamnose, xylose, mannose, and arabinose. Scanning electron microscopy (SEM) analysis was used to determine the microstructure of the water-soluble polysaccharides. The physicochemical properties were evaluated using Fourier transform infrared (FT-IR) spectroscopy and ultraviolet‒visible (UV‒visible) absorption spectroscopy. The total antioxidant activities of the crude polysaccharides were evaluated using various assays: DPPH radical scavenging (IC₅₀ WSPRaL = 615 ± 2.05 µg/mL, IC₅₀ WSPRaS = 628 ± 2.38 µg/mL), ABTS radical scavenging (470 ± 5.78 µg/mL and 559 ± 4.32 µg/mL for WSPRaL and WSPRaS, respectively), reducing power (IC₅₀ WSPRaS = 141.76 ± 3.16 µg/mL, IC₅₀ WSPRaL = 203.89 ± 1.07 µg/mL), and chelating capacity (IC₅₀ WSPRaS = 225 ± 1.75 µg/mL, IC₅₀ WSPRaL = 219 ± 2.51 µg/mL). In addition, the antibacterial and biofilm inhibitory activities of both polysaccharides were tested against pathogenic strains, and the polysaccharides significantly inhibited plant growth. Overall, the results indicate that the crude polysaccharides extracted from R. alaternus are promising for use as functional and bioactive ingredients in the food and nutraceutical industries. These results highlight the potential of both polysaccharides as natural products in various sectors, including food, cosmetics, pharmaceuticals, and medicine, due to their significant biological properties. Full article