Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60_STERLING_BT 2021_P2 Date: 28-11-22
Time: 02.30Pm to 05.30Pm CTA-10 Max. Marks: 180

KEY SHEET
PHYSICS
1 A,B,C 2 A,C 3 A,C 4 A,B,C 5 B,C,D 6 A,C
7 5 8 30 9 1 10 16 11 5 12 2.5
13 D 14 A 15 B 16 D 17 6 18 3
19 8

CHEMISTRY
20 A,B 21 A,B 22 A,B,C 23 B,C 24 A,B,C 25 A,B
26 13 27 40.90 28 98 29 84 30 2.75 31 6
to
40.93
32 B 33 C 34 B 35 B 36 6 37 4
38 8

MATHEMATICS
39 A,B,D 40 A,B 41 B,C 42 A,B,D 43 B,C,D 44 A,C
45 4 46 1 47 0 48 0 49 3 50 6
51 C 52 A 53 C 54 C 55 2 56 2
57 3
 Sri Chaitanya IIT Academy 28-11-2022_Sr.Super60_STERLING_BT_Jee-Adv(2021-P2)_CTA-10_Key&Sol’s

SOLUTIONS
PHYSICS
1. V3 2V 2RT
 Cons tan t , dV  dT , P  , W   PdV  400R
2 3 T V
T
U  nCv T  900 R, Q  nC T and Q  U  W  1300 R
Q 13
C  R
nT 6
2. 1 1 1 1 
  P  2 Pl1  2 Pl2  Pm Pl      1   
1
F f1  R1 R2 
 1 1 1 1 1 1 
Pl1  1.5  1       Pl2      1   
 10 15  12 f2  R1 R2 
 4  2  2 1 2
Pl2    1    Pm    
 3  15  45 f 15
1  1 2 2 1 4 2 1
  P  2         
F  12 45  15 6 45 15 18
F  18cm. If focus is negative, system will behave as concave mirror.
3. d 2 yd  2 
Path difference=0    1 t y  2mm
D 2 D  3 
d 2 y1d
When slab is removed, then path difference    0,
D 2D
y1  2d  4mm  shift  y1  y  4mm  2mm  2mm
4. F F
a1  0 when  50, F  200 a2  0 when  100, F  400
4 4
F / 4  50 300 / 4  50
F  300 N a1    5m / s 2 a2  0
5 5
If F  500 N a1  15m / s a2  2.5m / s 2
2

5. 1 2mg
mgx  kx 2 or x 
2 k
6. 1 2 1 2 1 2 1 Iv 2
KE on horizontal level mv  Iw  mv 
2 2 3 2 r2

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 Sri Chaitanya IIT Academy 28-11-2022_Sr.Super60_STERLING_BT_Jee-Adv(2021-P2)_CTA-10_Key&Sol’s

3v 2
PE mgh  mg 
4g
1 2 1 Iv 2 3v 2
Loss of KE=gain of PE mv   mg 
2 2 r2 4g
I m 1
  i.e., I  mr 2  Body is a disc or solid cylinder
2 2 2
r
1 3
I '  mr 2  mr 2  mr 2
2 2
7. Just after hinge B breaks (and F is removed too) the rod will not be in equilbrium. Let
the new reaction at A be N, then
2 g  N  2a ……….(1)
l   2l   2l 2 
2
3g
  1   2 g       gl      
2  3   3  2l
   
l
Since a    
2

l  3g  3g
a  a
2  2l  4
 3g  60
So, from (1) , we get 20  N  2   20  N   N  5N
 4  4
8. By Law of Conservation of Energy
 Los sin GPE of CM of Rod    Gainin RKE of Rod 
 l  1   2l  2
2
3g
  2 g        
 2  2  3  l

So, accelearation is an  l 2  3 g  30 ms 2
9. Now the amount of oil collected at one end, that is, mass flow rate is 5.0  103 kg / s
Density of oil,   5.0  103 kg / m3
Now let the volume of the oil flowing per second be V. Now, the volume flow rate is
Mass flow rate 5.0  103 kg / s
  1 105 m3 / s
Density 0.5  103 kg / m3
10. Radius , r  50cm  0.5m ; Volume flow rate Q  105 m3 / s
Length of pipe L  2m Coefficient of viscosity   0.02Pas
Now, let the pressure difference be P2  P1  ?
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 Sri Chaitanya IIT Academy 28-11-2022_Sr.Super60_STERLING_BT_Jee-Adv(2021-P2)_CTA-10_Key&Sol’s
Using Poiseuille’s law, we get
 r 4  P2  P1  8Q L 8  105  0.02  2
Q  2 1
P  P    16  106 Pa
8 L r 3.14  0.5 
4 4

11. F 5  102 N
Stress=   5  108 N / m 2
A 0.010  104 m 2
12. L 200.50  200 50
Elongation strian on the wire is    2.5  103
L 200 200
13. r
Effective length  l   radius  l 
2
l' l   r / 2 2l  r 2l  r
Therefore T  2  2  2 
g g 2g g
14. The net force acting downwards is mg  U  V  g  V  g  Vg      where  is
density of solid bob and  is the density of the surrounding medium
g   g  25 / 16   1 3 g
  
l l  25 / 16  5 l
15.  v  300
Since f app    f 0  2.2 10 
3
f0
 v  vs  300  3
2.2 103  270
 f0  Hz  f 0  1980 Hz  1.98kHz
300
Hence, the correct answer is (B)
16. f app  2.2 103 
300
f 0 f recede  1.8 103 
300
f0
300  vs 300  vs
Dividing equation (1) by (2), we get
22 300  vs 1200 1
  40vs   22  18  300  vs  ms  30ms 1
18 300  vs 40
Hence, the correct answer is (D).
17. Let the density of sphere be P and the mass of the sphere be M. Therefore,
M D
 100  2% . Let the diameter of sphere be D. Therefore,  100  3%
M D
M
Diameter of the sphere=Length of the sphere, we know that P 
V
3
Where V is the volume of the sphere, Volume  D
M
Therefore, we can write, Density  S 
D3
 M D
Thus,   100  3  100
 M D
Hence, the maximum error in the measurement of density is obtained as

 2%  3  3%  11%

18. Applying conservation of angular momentum about point P, we get
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 Sri Chaitanya IIT Academy 28-11-2022_Sr.Super60_STERLING_BT_Jee-Adv(2021-P2)_CTA-10_Key&Sol’s
2 v 2 v
mv0 R  MR 2  0  mvR  mR 2 
5 R 5 R
 2  2 3v 3 7
mv0 R 1    mvR 1    v  0   3m / s
 5  5 7 7

19. Let the x-axis be eastwards and the y-axis be northwards

 
v1  30iˆ and v2  40 ˆj
  
v21 (relative velocity of 2 in relation to 1)is given by v2  v1  40 ˆj  30iˆ

From the concept relative velocity, ship 1 may be assumed to be fixed and ship 2 to be
 
moving with the velocity 30iˆ  40 ˆj . This is a vector of magnitude 50 and inclined
at   tan 1  4 / 3 . The shortest distance is obviously the perpendicular distance of the
relative velocity vector from the fixed position of ship 1.
Therefore, sshortest  s12 sin  where s12 is the initial distance between 1 and 2 is
4
10   8km
5

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 Sri Chaitanya IIT Academy 28-11-2022_Sr.Super60_STERLING_BT_Jee-Adv(2021-P2)_CTA-10_Key&Sol’s

CHEMISTRY
20. On heating, borax first loses water molecules and swells up. On further heating it turns
into a transparent liquid, which solidifies into glass like material known as borax bead.
The metaborates of many transitions metals have characteristic colours and, therefore,
borax bead test can be used to identify them in the laboratory. For example, When
borax is heated in a Bunsen burner flame with CuO on a loop of platinum wire, a blue-
green coloured Co  BO2 2 bead is formed in non-luminous flame and colouless CoBO2 is
formed on heating in luminous flame.
21. All reducing sugars are muatrotating. Although (IV) is an  – hydroxyl ketone and
hence reducing but it can’t mutarotate as it not a carbohydrate, can’t form ring. In (II)
the glycosidic linkage is in between two anomeric carbons and hence ring opening
can’t occur, thus non – reducing as well as non – mutarotating.
22.

, ,
23. 2) B  OH 3  NaOH  Na  B  OH 4   H 2O can be made to proceed forward by
adding cis-diol to stabilization by chelation.
24. CH 3 NH 2   CH 3 2 NH 2
CF2Cl2  CF4
NO   NO  NO   NO
B ,O  3  B ,O  2.5
6 3
Cr O3  Cr 2 O3  Acidic nature 
25.

26. Cl HOOC Cl


MeOK in
chloroform
 
KMnO4

HOOC
A B
NO2

HOOC Cl HOOC Cl HOOC Cl HOOC Cl


conc
 
HNO3 
HOOC HOOC NO2 HOOC HOOC
NO2

DOU of C=7; DOU of B= 6; A=5

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 Sri Chaitanya IIT Academy 28-11-2022_Sr.Super60_STERLING_BT_Jee-Adv(2021-P2)_CTA-10_Key&Sol’s
27. Molar mass of Compound C is 245.5, which the no of possible products are 3.

28. Molar mass of compound B formed below is 98.

29.

30. x = 11 and y = 4

31. x = 1, Y = 6

32. Conceptual
33. Factual

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 Sri Chaitanya IIT Academy 28-11-2022_Sr.Super60_STERLING_BT_Jee-Adv(2021-P2)_CTA-10_Key&Sol’s
34.

35.

36. A  CO, B  HCN , Y  CaCN 2 , X : K 4  Fe  CN 6 

 2  2  2
37.

38.

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 Sri Chaitanya IIT Academy 28-11-2022_Sr.Super60_STERLING_BT_Jee-Adv(2021-P2)_CTA-10_Key&Sol’s

MATHEMATICS
39. f 2  0    f   0    85
2
f : R   2,2
(A) This is true of every continuous function
f  4   f  0 
(B) f   C  
4  0
f  4   f  0 
f C  
4
2  f  4   2
2  f  0   2
_______________
4  f  4   f  0   4
This f   C   1
(C) lim f  x   1
x 
Note f  x  should have a bound  which can be concluded by considering
 85 x   85 x 
f  x   2sin   f   x   85 cos  
 2   2 

f 2 0  f 0
2
  85 and lim f  x  does not exist
x 


(D) Consider H  x   f 2  x   f   x 
2
 H  0   85

By (B) choice there exists some x0 such that  f   x0    1 for some x0 in

2

 4,0  hence H  x0   f 2  x0    f   x0    4  1
2

H  x0   5 .Hence let p   4,0  for which H  p   5

(note that we have considered p as largest such negative number)
similarly let q be smallest positive number   0,4  such that H  q   5 . Hence By
Rolle’s theorem is  p, q 
H   c   0 for some c   4,4  and since H  x  is greater than 5 as we move form
x  p to x  q and f 2  x   4   f   x  2  1 in  p, q  . Thus
H   c   0  f f  f f   0
So f  f   0 and f   0
40.

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 Sri Chaitanya IIT Academy 28-11-2022_Sr.Super60_STERLING_BT_Jee-Adv(2021-P2)_CTA-10_Key&Sol’s
y  0  x  2
Let P be the point of inflection
So, P   2,2b  a  16 
Equation of tangent line passing through inflection
Point: y   b  12  x  8  a  1
Let Q   2  h,3h  1
Locus of Q : 3x  y  7  2
From equation (1) and (2), we get!
So, a  15 and b  15
41. bx  cy  a  0 , cx  ay  b  0 and common chord must be concurrent
42.
Tangent for ellipse : y  mx  m2  2
Tangent for hyperbola : y  mx  2m 2  2
 m 2  4 or m  2
 2 2   4 2 
Point of tangency for ellipse  ,  and for  , 
 6 6  6 6
43. Conceptual
44.  f    1  sin 2   g    sin   cos
 maximum and minimum values are 2 and 1 respectively.
 
 P  x   a x  2  x  1 , where a  R   0  ,

 
But P  2   2  2 then a = 1. P  x   x  2  x  1
3 2  33 2   2 1
 P   0
 4   4   4 
3 2  33 2   2 1
P   0
 4   4   4 
 5 2 1  2 1  5 2 5
P   0
 4   4   4 
 5  2   5  5 2  1  2 
P   0
 4   4  4 
 (A) and (C) are correct.
45. Conceptual
46. 44 – 46 Put tan 2 x  t  2 tan x.sec 2 xdx  dt
1  t  et  2 1 
 I  4 dt  2  e t
  dt  2
3  3 2
1  t   1  t  1  t  
2
 2cos 4 xe tan x  C
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47. Conceptual
48. Q47-Q48
f  x  g  x f  x  g  x
max  f  x  , g  x    
2 2
f  x  g  x f  x  g  x
min  f  x  , g  x    
2 2
max 1,3 x  2 , x  0
Let r  x   f  x   g  x   h  x   
min 3 x  2, 2 x  2 x  1
1 x  1

max 1,3x  2  min 3 x  2, 2 x  2  3 x  2  1  x  0
2 x  2 x  0

x  1 ;  1   3x  2  1  x  0 ; 3x  2   3x  2 
x  0 ;  3x  2   2 x  2
1 1
2
 1  3x  2  3x  3    3x  2  2 x   5 x    3x  2
2
 1  3x  3 5 x 1
  x      h x  f  x  g  x h x  x 
 2 2 2 2
3  x  1 5x
f  x  g  x 
2 2

49.  3/5 3
 x  1  : x  1
2



1
 
(I) f  x    x   cos 1 4 x3  3 x :  1  x  1 is continuous at x  1&1 not
2
 5/3
 x  1 :1  x  2

1
differentiable at x  1,  &1
2

(II) f  x   sin xcos x  sin3   x   x , x 1,2 
Let g  x    sin   x   x   sin 2   x  g   l   g   l  so differentiable at x = 1 and

cont. at x 1
 3
for sin xcos x .Double point for non differentiability are x  0, ,  ,
2 2

sin x  cos x is discontinuous at x  0, ,2 , So not differentiable at
2

x  2n ,2n 
2

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 Sri Chaitanya IIT Academy 28-11-2022_Sr.Super60_STERLING_BT_Jee-Adv(2021-P2)_CTA-10_Key&Sol’s
50.  3/5 3
 x  1  2 : x  1



1
 
(I) f  x    x   cos 1 4 x3  3 x :  1  x  1 is continuous at x  1&1 not
2
 5/3
 x  1 :1  x  2

1
differentiable at x  1,  &1
2

(II) f  x   sin xcos x  sin3   x   x , x 1,2 
Let g  x    sin   x   x   sin 2   x 

cont. at x 1

   
g  l  g  l so differentiable at x = 1 and for sin xcos x
 3
Double point for non differentiability are x  0, ,  ,
2 2

sin x  cos x is discontinuous at x  0, ,2 So not differentiable at
2

x  2n ,2n 
2
51. As f 11  c1  f 11  c2   0 & f 11  c1   f 11  c2   0 & c1 & c2are critical points.
f11  c1   0  c1 is local min, f 11  c2   0  c1 is local max
and also f  c1   f  c2  in between c1 & c2 it should have at least one max & one min.
f 1  x   0 will have 4, 6, 8,…
f  x   0 will have 2, 3, 4, 5…..
52. As f 11  c1  f 11  c2   0 & f 11  c1   f 11  c2   0 & c1 & c2are critical points.
f11  c1   0  c1 is local min
f 11  c2   0  c1 is local max
and also f  c1   f  c2  in between c1 & c2 it should have at least one max & one min.
f 1  x   0 will have 4, 6, 8,…
f  x   0 will have 2, 3, 4, 5…..
53. Conceptual
54.

x2  a  x

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 Sri Chaitanya IIT Academy 28-11-2022_Sr.Super60_STERLING_BT_Jee-Adv(2021-P2)_CTA-10_Key&Sol’s

x2  x  a  0
D0
1  4a  0
1
a
4

a  a
a a
a  a2
a2  a  0
a  a  1  0
0  a 1

x2  x  a  0
1  4a  0, a  0
1
a   ,a  0
4
1
 a0
4
a a
` a  a , a2  a
 a  a  1  0, a  1
55.

Let the radius of circle is r .

 r 
From geometry, Pm  r 2, .
 2
Now, this point lies on the curve 4  2  y   x 2 .
 r 
 
2
 4 2   r 2
 2

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 Sri Chaitanya IIT Academy 28-11-2022_Sr.Super60_STERLING_BT_Jee-Adv(2021-P2)_CTA-10_Key&Sol’s
56. 99 99
Let S   10  n T  10  n
n 1 n 1

 
99 99
2S   20  2 n  10  100  n  10  100  n
n 1 n 1

 
99
2S  10  n  10  n  S  T
n 1
2S  S  T
S
 2 1
T
57.

The region S is shown as shaded region.

Area of S 
2
3

4
3 2
 
a  b 2  c 2 , where a, b, c are sides of the small equilateral

11 3
triangles 
36

Sec: Sr.Super60_STERLING_BT Page 14