Larry Brown

Tom Holme

www.cengage.com/chemistry/brown

Chapter 3
Molecules, Moles, and
Chemical Equations
Technological University of the Philippines - Taguig Campus
Basic Arts and Sciences Department
Chemistry Section
Chapter Objectives
• Explain balancing a chemical reaction as an application of the
law of conservation of mass.

• List at least three quantities that must be conserved in

chemical reactions.

• Write balanced chemical equations for simple reactions, given

either an unbalanced equation or a verbal description.

2
Chapter Objectives
• Explain the concept of a mole in your own words.

• Interpret chemical equations in terms of both moles and

molecules.

• Interconvert between mass, number of molecules, and

number of moles.

• Determine a chemical formula from elemental analysis (i.e.,

from % compositions).

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Chapter Objectives
• Define the concentration of a solution and calculate the
molarity of solutions from appropriate data.

• Calculate the molarity of solutions prepared by dilution or

calculate the quantities needed to carry out a dilution to
prepare a solution of a specified concentration.

• Distinguish between electrolytes and nonelectrolytes and

explain how their solutions differ.

4
Chapter Objectives
• Describe the species expected to be present (ions, molecules,
etc.) in various simple solutions.

• Recognize common strong acids and bases.

• Write molecular and ionic equations for acid-base

neutralization reactions.

5
Chemical Formulas and Equations

• Chemical formulas provide a concise way to represent

chemical compounds.

• A chemical equation builds upon chemical formulas to

concisely represent a chemical reaction.

6
Writing Chemical Equations
• Chemical equations represent the transformation of one or
more chemical species into new substances.

• Reactants are the original materials and are written on the

left hand side of the equation.

• Products are the newly formed compounds and are

written on the right hand side of the equation.

Reactants → Products

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Writing Chemical Equations
• Chemical formulas represent reactants and products.

• Phase labels follow each formula.

• solid = (s)
• liquid = (l)
• gas = (g)
• aqueous (substance dissolved in water) = (aq)

• Some reactions require an additional symbol placed over

the reaction arrow to specify reaction conditions.
• Thermal reactions: heat ()
• Photochemical reactions: light (h)

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Symbols and meaning

2Na(s) + 2H2O(l) → 2NaOH(aq) + H2(g)

Methods of Balancing:
Inspection method (trial and error)
Redox Method (oxidation no. method)
Ion-electron method
Writing and Balancing Chemical
Equations

Aluminum and hydrochloric acid react to form

aluminum chloride and hydrogen gas.
Aluminum + hydrochloric acid aluminum chloride and hydrogen
gas
Writing Chemical Equations

• Different representations for the reaction between hydrogen

and oxygen to produce water.
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Balancing Chemical Equations
• The law of conservation of matter: matter is neither created
nor destroyed.

• Chemical reactions must obey the law of conservation of

matter.

• The same number of atoms for each element must

occur on both sides of the chemical equation.

• A chemical reaction simply rearranges the atoms into

new compounds.

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Balancing Chemical Equations
• Chemical equations may be balanced via inspection, which
really means by trial and error.

• Numbers used to balance chemical equations are called

stoichiometric coefficients.

• The stoichiometric coefficient multiplies the number of

atoms of each element in the formula unit of the
compound that it precedes.

• Stoichiometry is the various quantitative relationships

between reactants and products.

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Balancing Chemical Equations
• Pay attention to the
following when balancing
chemical equations:
• Do not change species
• Do not use fractions
(cannot have half a
molecule)
• Make sure you have the
same number of atoms of
each element on both
sides

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Example Problem 3.1

• Write
a balanced chemical equation describing
the reaction between propane, C3H8, and
oxygen to form carbon dioxide and water.

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Example Problem 3.1

• Silicon nitride, Si3N4, is used as a reinforcing

fiber in construction materials. It can be
synthesized from silicon tetrachloride and
ammonia. The other product is ammonium
chloride, Write the balanced chemical reaction.

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Interpreting Equations and the Mole

• Balanced chemical equations are interpreted on the

microscopic and macroscopic level.

• Microscopic interpretation visualizes reactions between

molecules.

• Macroscopic interpretation visualizes reactions between

bulk materials.

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Interpreting Chemical Equations
• Balanced chemical reactions provide stoichiometric ratios
between reactants and products. Ratios relate relative
numbers of particles.

2H2 (g) + O2 (g) ⎯⎯→ 2H2O(g)

• 2 molecules H2: 1 molecule O2: 2 molecules H2O

• 100 molecules H2: 50 molecule O2: 100 molecules H2O

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Avogadro’s Number and the Mole

• A mole is a means of counting the large number of particles in

samples.

• One mole is the number of atoms in exactly 12 grams of

12C (carbon-12).

• 1 mole contains Avogadro’s number (6.022 x 1023

particles/mole) of particles.

• The mass of 6.022 x 1023atoms of any element is the

molar mass of that element.

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Avogadro’s Number and the Mole

• One mole samples of various elements. All have the same number of
particles.
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Avogadro’s Number and the Mole

• Balanced chemical reactions also provide mole ratios

between reactants and products.

2H 2 (g) + O 2 (g) ⎯⎯
→ 2H 2 O(g)

• 2 moles H2: 1 mole O2: 2 moles H2O

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Determining Molar Mass
• The molar mass of a compound is the sum of the molar
masses of all the atoms in a compound.

 2 mol H  1.0 g H   16.0 g 

  +  1 mol O  
1 mol H   1 mol O 

= 18.0 g/mol H 2O

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Example Problem 3.5
• Determine the molar mass of each of the following
compounds:
Atomic mass:
Pb=207.20
a) PbN6 N = 14.01
C = 12.01
H = 1.01
b) C3H5N3O9 O = 16.00
Hg = 200.59

c) Hg(ONC)2

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Calculations Using Moles and Molar Mass

• Molar mass allows conversion from mass to number of

moles, much like a unit conversion.

• 1 mol C7H5N3O6= 227.133 g C7H5N3O6

1 mol C 7 H 5 N 3 O 6
300.0 g C 7 H 5 N 3O 6 
227.133 g C 7 H 5 N 3O 6

= 1.320 mol C 7 H 5 N 3 O 6

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Calculations Using Moles and Molar Mass

• Avogadro’s number functions much like a unit conversion

between moles to number of particles.

• 1 mol C7H5N3O6= 6.022  1023C7H5N3O6 molecules

• How many molecules are in 1.320 moles of

nitroglycerin?
6.022  1023 molecules C 7 H 5N O
1.320 mol C 7 H 5N O
3 6
 3 6

1 mol C 7 H 5N O
3 6

= 7.949  1023 molecules C H N O

7 5 3 6

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Example Problem 3.6
• A sample of the explosive TNT (C7H5N3O6) has a mass of
500.0g.

• How many moles of TNT are in this sample?

• How many molecules are in this sample?

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Example Problem 3.7
• How many pounds of halite (C2H6N4O5) correspond to 315
moles? (1 pound = 454 g)

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Elemental Analysis: Determining Empirical
and Molecular Formulas

• Empirical formulas can be determined from an elemental

analysis.

• An elemental analysis measures the mass percentage of

each element in a compound.

• The formula describes the composition in terms of the

number of atoms of each element.

• The molar masses of the elements provide the connection

between the elemental analysis and the formula.

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Elemental Analysis: Determining Empirical
and Molecular Formulas

• Assume a 100 gram sample size

• Percentage element  sample size = mass element in compound. (e.g.,

16% carbon = 16 g carbon)

• Convert mass of each element to moles using the molar mass.

• Divide by smallest number of moles to get mole to mole ratio for

empirical formula.

• When division by smallest number of moles results in small rational

fractions, multiply all ratios by an appropriate integer to give whole
numbers.

• 2.5  2 = 5, 1.33  3 = 4, etc.

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Example Problem 3.8
• The explosive known as RDX contains 16.22% carbon, 2.72%
hydrogen, 37.84% nitrogen, and 43.22% oxygen by mass.
Determine its empirical formula.

• Nitroglycerin contains 15.87 % C, 2,22% H, 18.50% N and

63.41% O by mass, Determine the empirical formula of the
compound.

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 Example Problem 3.8
• Nitroglycerin contains 15.87 % C, 2,22% H, 18.50% N and
63.41% O by mass, Determine the empirical formula of the
compound.

• When division by smallest number of moles results in small rational fractions,

multiply all ratios by an appropriate integer to give whole numbers.

nitroglycerine, trinitroglycerin, nitro, glyceryl

trinitrate, or 1,2,3-trinitroxypropane
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Example Problem 3.8
• Nitroglycerin contains 15.87 % C, 2,22% H, 18.50% N and
63.41% O by mass, Determine the empirical formula of the
compound.

nitroglycerine,
trinitroglycerin
glyceryl trinitrate
1,2,3-trinitroxypropane
Elemental Analysis: Determining Empirical
and Molecular Formulas

• A molecular formula is a whole number multiple

of the empirical formula.

• Molar mass for the molecular formula is a whole

number multiple of the molar mass for the
empirical formula.

• If the empirical formula of a compound is CH2 and

its molar mass is 42 g/mol, what is its molecular
formula?

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Example Problem 3.9

• An alloy contains 70.8 mol % palladium and

29.2 mol % nickel. Express the composition of
this alloy as weight percentage (wt %).

• Eighteen carat gold contains 75% gold, 16%

silver, and 9% copper by weight. Express this
composition in mol percentages.

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 Example Problem 3.9
• An alloy contains 70.8 mol % palladium and 29.2 mol %
nickel. Express the composition of this alloy as weight
percentage (wt %).

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Example Problem 3.9

• An alloy contains 70.8 mol % palladium and

29.2 mol % nickel. Express the composition of
this alloy as weight percentage (wt %).

• Eighteen carat gold contains 75% gold, 16%

silver, and 9% copper by weight. Express this
composition in mol percentages.

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Aqueous Solutions and Net Ionic Equations

• Reactions that occur in water are said to take place in

aqueous solution.

• Solution: homogeneous mixture of two or more

substances.

• Solvent: solution component present in greatest

amount.

• Solute: solution component present in lesser amount.

• The preparation of a solution is a common way to

enable two solids to make contact with one another.
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Solutions, Solvents, and Solutes
• For solutions, the concentration is a key piece of information.

• Concentration: relative amounts of solute and solvent.

• Concentrated: many solute particles are present.

• Dilute: few solute particles are present.

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Solutions, Solvents, and Solutes
Solution preparation:

• Solid CuSO4, the solute, is

transferred to a flask.

• Water, the solvent, is added.

• The flask is shaken to speed

the dissolution process.

• Two solutions of CuSO4.

• Solution on the left is
more concentrated, as
seen from its darker
color.

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Solubility Curve
Solutions, Solvents, and Solutes
• Compounds can be characterized by their solubility.

• Soluble compounds dissolve readily in water.

• Insoluble compounds do not readily dissolve in water.

• Solubility can be predicted using solubility guidelines.

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Solutions, Solvents, and Solutes
• Solubility guidelines for soluble salts

42
Solutions, Solvents, and Solutes
• Solubility guidelines for insoluble salts

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Example Problem 3.2

• Which of the following compounds would you predict are

soluble in water at room temperature?

a) KClO3

b) CaCO3

c) BaSO4

d) KMnO4

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 ELECTROLYTES AND NONELECTROLYTES

Electrolytes - compounds which conduct

electricity in the molten state or in aqueous
solutions .

Non-electrolytes - compounds which do not

conduct electricity under any conditions, solid
state, liquid state or in aqueous solutions
Electrolytic conduction
Conductivity depends primarily :
on the number of ions present
upon dissociation or ionization
speed at which these ions move
through the solution.
• Dissociation – separation of ions present in
the crystal lattice

Na+Cl-(s) --> Na+(aq) + Cl-(aq)

• Ionization - ions are created by the interaction
between polar covalent substance such as
HCl and H2O molecules.

HCl(g) + H 2O(l) --> H3O+(aq) + Cl-(aq)

Solutions, Solvents, and Solutes
• Weak electrolytes dissociate partially into ions in solution.

• Strong electrolytes dissociate completely into ions in

solution.

• Nonelectrolytes do not dissociate into ions in solution.

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Solutions, Solvents, and Solutes

a) Sugar, a nonelectrolyte, does not conduct current when dissolved in water.

b) Acetic acid, a weak electrolyte, weakly conducts current when dissolved in
water.
c) Potassium chromate, a strong electrolyte, strongly conducts current when
dissolved in water.
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Chemical Equations for Aqueous Reactions

• When a covalently bonded material dissolves in water and the

molecules remain intact, they do not conduct current. These
compounds are nonelectrolytes.

C6H12O6(s)⎯→C6H12O6(aq

• The water molecules are not shown explicitly, although

their presence is indicated by the “(aq)” on the product
side.

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Chemical Equations for Aqueous Reactions

• When an ionic solid dissolves in water, it breaks into its

constituent ions. This is called a dissociation reaction. These
compounds conduct electric current and are electrolytes.

NaCl (s) ⎯⎯
→ Na (aq) + Cl (aq) + −

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Chemical Equations for Aqueous Reactions

• Aqueous chemical reactions can be written as a molecular

equation. The complete formula for each compound is
shown.

• Note, all of the species may not be molecules.

HNO3 (aq) + NH3 (g) ⎯⎯→ NH4 NO3 (aq)

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Chemical Equations for Aqueous Reactions

• Dissociation of reactants and products is emphasized by

writing a total ionic equation.

H+ (aq) + NO− (aq)+ NH (g) ⎯⎯→ NH+ (aq) + NO− (aq)

3 3 4 3

• Note: HNO3 is a strong acid and thus dissociates completely,

while NH3 does not dissociate

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Chemical Equations for Aqueous Reactions

• Spectator ions are ions uninvolved in the chemical reaction.

When spectator ions are removed, the result is the net ionic
equation.
• Total ionic equation

H+ (aq) + NO− (aq)+ NH (g) ⎯⎯→ NH+ (aq) + NO− (aq)

3 3 4 3

• Net ionic equation

H+ (aq) + NH (g) ⎯⎯→ NH+ (aq)

3 4

Spectator ion = NO−3

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Solutions, Solvents, and Solutes
• Solubility guidelines for soluble salts

56
Solutions, Solvents, and Solutes
• Solubility guidelines for insoluble salts

57
Chemical Equations for Aqueous Reactions

Decide whether each of the following is water-soluble.

If soluble, write the ions produced.
(a) KOH
(b) CuSO4
(c) K2SO4
(d) BaBr2
(e) (NH4)2SO4
(f) BaS
Acid-Base Reactions
• Acids are substances that dissolve in water to produce H+ (or
H3O+) ions.

• Examples: HCl, HNO3, H3PO4, HCN

• Bases are substances that dissolve in water to produce OH–

ions.

• Examples: NaOH, Ca(OH)2, NH3

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Acid-Base Reactions
• Strong acids and bases completely dissociate in water.

HCl(g) + H O(l ) ⎯⎯→ H O (aq) + Cl (aq)

+ −
2 3

NaOH(s) ⎯⎯→ Na+ (aq) + OH− (aq)

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Acid-Base Reactions
• All common strong acids and bases.

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Acid-Base Reactions
• Weak acids and bases partially dissociate in water.

• Notice the two-way arrows, which emphasize that the

reaction does not proceed completely from left to right.

⎯
CH3COOH(aq) + H2O(l ) 
⎯⎯→ H 3O +
(aq) + CH 3COO −
(aq)

⎯
NH3 (aq) + H2O(l ) 
⎯⎯→ NH +
4 (aq) + OH −
(aq)

62
Acid-Base Reactions

• Some common weak acids and bases.

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Acid-Base Reactions
• Mixing an acid and a base leads to a reaction known as
neutralization, in which the resulting solution is neither acidic
nor basic.

• Net ionic equation for neutralization of strong acid and

strong base.

H O (aq) + OH (aq) ⎯⎯→ 2H O(l)

+ −
3 2

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Example Problem 3.3
• When aqueous solutions of acetic acid and potassium
hydroxide are combined, a neutralization reaction will occur.
Write the following equations:

a) molecular

b) total ionic

c) net ionic

65
Precipitation Reactions
• A precipitation reaction is an aqueous reaction that produces
a solid, called a precipitate.

• Net ionic reaction for the precipitation of lead(II) iodide.

Pb 2+ (aq) + 2I− (aq) ⎯⎯

→ PbI (s)
2

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Precipitation Reactions

• Precipitation reaction between aqueous solutions of KI and Pb(NO3)2, which are

both colorless.
• The bright yellow solid, PbI2, is produced.
• PbI2 is insoluble as predicted by the solubility guidelines.
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Example Problem 3.4
• When aqueous sodium carbonate and barium chloride are
combined, the solution becomes cloudy white with solid
barium carbonate. Write the following equations:

a) molecular

b) total ionic

c) net ionic

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Molarity
• Molarity, or molar concentration, M, is the number of moles of
solute per liter of solution.

• Provides relationship among molarity, moles solute, and

liters solution.

moles of solute
Molarity (M ) =
liter of solution

• If we know any two of these quantities, we can

determine the third.

69
Example Problem 3.10

• A solution is prepared by dissolving 45.0 g of

NaClO in enough water to produce exactly 750 mL
of solution. What is the molarity of this solution?

70
Example Problem 3.10

• A solution is prepared by dissolving 45.0 g of

NaClO in enough water to produce exactly 750 mL
of solution. What is the molarity of this solution?

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Example Problem 3.10

• Calculate the molarity of each of the following

• a. 1.45 mol HCl in 250 mL of solution.

• b. 20.00g cobalt (III) chloride dissolved in water to

make 4.50L of solution?

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Example Problem 3.10

• How many grams of solute are present in in each of

these solutions?
• A. 1.43 of mL of 5.8 M KNO3?.

• B. 3.0L of 1.43 M Na2CO3?

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Dilution
• Dilution is the process in which solvent is added to a solution
to decrease the concentration of the solution.

• The number of moles of solute is the same before and

after dilution.

• Since the number of moles of solute equals the product of

molarity and volume (M  V), we can write the following
equation, where the subscripts denote initial and final
values.
M i  Vi = M f  Vf
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Example Problem 3.11

1. A chemist requires 1.5 M hydrochloric acid, HCl, for

a series of reactions. The only solution available is
6.0 M HCl. What volume of 6.0 M HCl must be
diluted to obtain 5.0 L of 1.5 M HCl?

2. If 2.70 mL of 12.0 M NaOH is diluted to a volume

0f 150.0 mL, what is the final concnetration?

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