Search Results (4,241)

Steel surface protection with hard coatings is essential in metalworking, yet developing high-performance coatings is challenging. TiAlSiN coatings grown on various substrates using commercial targets have been extensively studied, but consistent data on their properties are lacking. This study focused on TiAlSiN single layers (SL) and TiAlSiN/TiN bilayers (BL), with an 800 nm thick TiAlSiN top layer and a 100 nm thick TiN mid layer. These coatings were grown on C120 tool steel discs via reactive DC magnetron sputtering using TiAlSi 75–20–5 at.% and Ti targets fabricated in-house through spark plasma sintering. The stability of coatings was assessed after thermal treatment (TT) in air at 800 °C for 1 h. SEM analysis revealed a columnar microstructure with pyramidal grains in the SL and BL coatings, and coarser pyramidal and prismatic grains in both TT coatings. EDS analysis showed a decrease in Ti, Al, Si, and N content after annealing, while O content increased due to oxide formation. High indentation hardness (9.19 ± 0.09 GPa) and low effective elastic modulus (148 ± 6 GPa) were displayed by the BL TT coating, indicating good resistance to plastic deformation and better load distribution. The highest fracture toughness was noted in the BL TT coating (0.0354 GPa), which was 16.4 times greater than the steel substrate. Better scratch resistance and low coefficient of friction (COF ≤ 0.35) were exhibited by both TT coatings. Tribological tests showed a mean COF of 0.616–0.773, comparable to the steel substrate (0.670). The lowest corrosion current density (0.1298 µA/cm²), highest polarization resistance (46.34 kΩ cm²), and a reduced corrosion rate (1.51 µm/year) in a 3.5 wt.% NaCl solution was also exhibited by the BL TT coating. These findings indicate TiAlSiN/TiN films as effective protective coatings for tool steel surfaces. Full article

Zoo enclosure design, and housing and husbandry protocols, will always be a compromise between what a species has evolved to do and what is possible to offer in a human-created environment. For some species, behaviours that are commonly performed in the wild may be constrained by husbandry practices that are used for ease or aesthetics or are accepted conventions. As zoos place more emphasis on positive animal welfare states, zoo enclosures should be scrutinised to check that what is provided, in terms of useful space, appropriate replication of habitat features, and maximal potential for natural behaviour performance, is relevant to the species and individuals being housed. For some species, zoos need to grapple with tough questions where the answer may not seem immediately obvious to ensure they are continuously improving standards of care, opportunities for the performance of species-typical behaviours, and advancing the attainment of positive welfare states. Determining the importance of flight, for example, and what this behaviour adds to the quality of life of a zoo-housed bird, is an important question that needs addressing to truly advance aviculture and how we determine bird welfare. This paper provides questions that should be answered and poses measures of what flight means to a bird, to provide evidence for the development and evolution of zoo bird housing. If we can devise some way of asking the animals in our care what they need, we can more firmly support decisions made that surround enclosure design, and housing decisions. Ultimately, this means gathering evidence on whether birds like to fly (e.g., from birds in training or demonstration activities) by applying mixed methods approaches of behavioural analysis, data on wild ecology, qualitative behavioural assessment, and cognitive bias testing to develop a robust suite of tools to address avian welfare considerations. Avian welfare scientists should attempt to define what meaningful flight is (i.e., flight that truly suggests a bird is flying) in order to support guidelines on aviary dimensions, space allowance, and welfare outputs from birds in both flighted and flight-restricted populations, and to determine what is most appropriate for an individual species. Changing the term “best practice” husbandry guidelines to “better practice” husbandry guidelines would instil the importance of regular review and reassessment of housing and management suitability for a species to ensure such care regimes remain appropriate. With an increasingly welfare-savvy public visiting zoos, it is essential that we seek more evidence to support and justify how birds are kept and ultimately use such evidence to enact changes to practices that are shown to infringe on avian welfare. Full article

Agriculture drones face important challenges regarding autonomy and construction, as flying time below the 9-minute mark is the norm, and their manufacture requires several tests and research before reaching proper flight dynamics. Therefore, correct design, analysis, and manufacture of the structure are imperative to address the aforementioned problems and ensure a robust build that withstands the tough environments of this application. In this work, the analysis and implementation of a Nylamid motor bracket, aluminum sandwich-type skeleton, and carbon fiber tube arm in a 30 kg agriculture drone is presented. The mechanical response of these components is evaluated using the finite element method in ANSYS Workbench, and the material behavior assumptions are assessed using a universal testing machine before their implementations. The general description of these models and the numerical results are presented. This early prediction of the behavior of the structure allows for mass optimization and cost reductions. The fast dynamics of drone applications set important restrictions in ductile materials such as this, requiring extensive structural analysis before manufacture. Experimental and numerical results showed a maximum variation of 8.7% for the carbon fiber composite and 13% for the Nylamid material. The mechanical properties of polyamide nylon allowed for a 51% mass reduction compared to a 6061 aluminum alloy structure optimized for the same load case in the motor brackets design. The low mechanical complexity of sandwich-type skeletons translated into fast implementation. Finally, the overall performance of the agriculture drone is evaluated through the data gathered during the flight test, showing the adequate design process. Full article

During the hot dip aluminum plating process, components such as sinking rollers, pulling rollers, and guide plates will come into long-term contact with high-temperature liquid aluminum and be corroded by the aluminum liquid, greatly reducing their service life. Therefore, the development of a material with excellent corrosion resistance to molten aluminum is used to prepare parts for the dipping and plating equipment and protect the equipment from erosion, which can effectively improve the production efficiency of the factory and strengthen the quality of aluminum-plated materials, which is of great significance for the growth of corporate profits. With AlFeNiCoCr as the binder phase and ZrB₂ as the hard phase, ZrB₂-based ceramic composites were prepared by spark plasma sintering (SPS). SEM, EDS and XRD were used to characterize the microstructure and properties of the sintered, corroded, and abraded material samples. The density, fracture toughness, corrosion rate and wear amount of the composite material were measured. The results show that ZrB₂-AlFeNiCoCr ceramics have compact structure and excellent mechanical properties, and the density, hardness and fracture toughness of ZrB₂-AlFeNiCoCr increase with the increase in sintering temperature. However, when the composite material is at 1600 °C, the relative density of the sintering at 1600 °C decreases due to the overflow of the bonding phase. Therefore, when the sintering temperature is 1500 °C, the high entropy alloy has the best performance. The average corrosion rate of ZrB₂-1500 at 700 °C liquid aluminum is 1.225 × 10⁻³ mm/h, and the wear amount in the friction and wear test is 0.104 mm³. Full article

Background: Our previous study found that the addition of pentavalent cations like niobium (Nb) to yttria-stabilized zirconia increased fracture toughness but also raised the coefficient of thermal expansion (CTE), and opacity also increased undesirably. A new surface treatment is required to boost fracture toughness without altering CTE or translucency. Methods: The surfaces of pre-sintered 3 mol% yttria-stabilized tetragonal zirconia polycrystal (3Y-TZP) and 4.2 mol% yttria-stabilized partially stabilized zirconia (4.2Y-PSZ) were treated with a Nb sol solution containing Nb₂O₅ nanoparticles. After drying and sintering, a high-Nb-content surface layer formed with a depth of approximately 1 mm. Results: The Nb content in this surface layer matched that of a bulk material with 1 mol% Nb₂O₅. The tetragonality of the surface zirconia increased, enhancing the surface fracture toughness without changing the CTE or translucency. Conclusions: Adding Nb near the surface improved the fracture toughness without affecting the CTE or translucency. This method could strengthen zirconia prostheses, allowing more reliable dental restorations. Full article

Reinforcing crack-damaged concrete structures with ultra-high-performance concrete (UHPC) proves to be more time-, labor-, and cost-efficient than demolishing and rebuilding under the dual-carbon strategy. In this study, the extended finite element method (XFEM) in ABAQUS was first employed to develop a numerical model of UHPC-reinforced single-notched concrete (U+SNC) beams, analyze their crack extension behavior, and obtain the parameters necessary for calculating fracture toughness. Subsequently, the fracture toughness and instability toughness of U+SNC were calculated using the improved double K fracture criterion. The effects of varying crack height ratios (a/h) of SNC, layer thicknesses (d) of UHPC reinforcement, and fiber contents in UHPC (V_SF) on the fracture properties of U+SNC beams were comprehensively investigated. The results indicate that (1) the UHPC reinforcement layer significantly enhances the load-carrying capacity and crack resistance of the U+SNC beams. Crack extension in the reinforced beams occurs more slowly than in the unreinforced beams; |(2) the fracture performance of the U+BNC beams increases exponentially with d. Considering both the reinforcement effect benefit and beam deadweight, the optimal cost-effective performance is achieved when d is 20 mm; (3) with constant d, increasing a/h favors the reinforcement effect of UHPC on the beams; (4) as V_SF increases, the crack extension stage in the U+BNC beam becomes more gradual, with higher toughness and flexural properties; therefore, the best mechanical properties are achieved at a V_SF of 3%. Full article

The intelligent transformation of coal mines is one of the current trends in developing China’s coal mining industry. To explore the impact of miners’ insecurity on their safety behavior under this trend, miners’ psychological resilience was introduced as the mediating variable, and team safety climate was used as the moderating variable to conduct a questionnaire survey of frontline miners. The data analysis was carried out using descriptive statistics, correlation analysis, structural equation modeling (SEM), and the fsQCA method to explore the impact of job insecurity on miners’ risk behavior through psychological resilience from the dimensions of job loss insecurity, job performance insecurity, and interpersonal insecurity. The results show that the sense of insecurity of the miners has a significant negative correlation with security behavior and a significant negative correlation with psychological toughness; miners’ psychological resilience plays an intermediary role in the correlation between job loss insecurity and miners’ risk behavior. Meanwhile, team safety climate has a significant moderating effect on the relationship between job insecurity and psychological resilience, as well as the relationship between psychological resilience and safety behavior; that is, a good team safety climate can effectively reduce the negative impact of job insecurity brought about by the transformation and upgrading of coal mines. Full article

The utilization of lightweight aggregate concrete (LWC) plays a major role in reducing the self-weight of CFST (concrete-filled steel tube) columns, which is reflected in the behavior of the structural system. This paper aims to investigate the characteristics of lightweight concrete-filled steel tubular (LWCFST) columns under an axial compressive load, using a total of (48) LWCFST column models. The simulated models were divided into four groups with different concrete compressive strength, length-to-diameter ratios (L/D), and diameter-to-thickness ratios (D/t). Four concrete compressive values were examined (30, 40, 50, and 60) MPa, three length-to-diameter ratios short (L/D = 3), medium (L/D = 6), and long (L/D = 9), and four diameter-to-thickness ratios (36, 31, 26, and 21). The method of nonlinear finite element analysis (NLFEA) was used to fulfill the objective of this study where results were presented as graphical plots between the compressive loading versus the axial and lateral strains along with the failure modes. In addition, the results were compared with the AISC360-16 and EC4 codes predictions to examine their applicability on the LWCFST columns where the AISC was overpredicted in most cases with higher percentages under lower (L/D) values, whereas the EC2 was underestimated in most cases with high percentages up to 28%, which become closer to the NLFEA predictions at higher (L/D) values. It has been revealed that the utilization of steel tubes significantly improves the LWCFST column’s mechanical performance, ductility, compressive strength, and toughness. Moreover, the structural behavior of the LWCFST columns and their associated failure modes was found to be highly affected by the geometrical properties of the CFST column (i.e., L/D ratio and D/t ratio) where specimens with small tube thickness show bad behavior. Finally, the utilization of high-strength concrete has a favorable performance compared to the utilization of thick steel tubes. Full article

Wood–polymer composites (WPCs) with polypropylene (PP) matrix suffer from low toughness, and fossil-based impact modifiers are used to improve their performance. Material substitution of virgin fossil-based materials and material recycling are key aspects of sustainable development and therefore recycled denim fabric, and elastomer were evaluated to replace the virgin elastomer modifier commonly used in commercial WPCs. Microtomography images showed that the extrusion process fibrillated the denim fabric into long, thin fibers that were well dispersed within the WPC, while the recycled elastomer was found close to the wood fibers, acting as a soft interphase between the wood fibers and PP. The fracture toughness (K_IC) of the WPC with recycled denim fabric matched the commercial WPC which was 1.4 MPa m^1/2 and improved the composite tensile strength by 18% and E-modulus by 54%. Recycled elastomer resulted in slightly lower K_IC, 1.1 MPa m^1/2, as well as strength and modulus while increasing elongation and contributing to toughness. The results of this study showed that recycled materials can potentially be used to replace virgin fossil-based elastomeric modifiers in commercial WPCs, thereby reducing the CO₂ footprint by 23% and contributing to more efficient use of resources. Full article

Tunnel boring machines (TBMs) are exposed to the impact of the ground shattering force and the friction of sandstone during excavation work, and are prone to wear and breakage, and other failures. Traditional heat treatment processes cannot simultaneously achieve the required high-energy composite structure of hard external and tough internal properties for cutter rings, leading to inadequate wear resistance and impact toughness under working conditions. This study utilizes H13 steel as the base material, and based on a study of carburizing, nitriding, and ultrasonic impact processes for H13 steel analyzing the effects of different high-energy composite modification processes on the hardness distribution, microstructure, and residual stress of H13 steel, the mechanisms by which high-energy composite modification processes affect the wear resistance and impact resistance of H13 steel are revealed. The results indicate that the wear amount and impact toughness of the sample subjected to carburizing and ultrasonic surface rolling composite strengthening were 1.9 mg and 27.34 J/cm², demonstrating the best wear and impact resistance. This combination of properties allows the H13 steel cutter ring to achieve the optimal overall performance in terms of wear resistance and impact resistance. Full article

This study aims to develop thermoplastic (TP) and thermoset (TS) based mixed matrix composite using design dependent physical compatibility. Using thermoplastic-based (PLA) skeletal lattices with diverse patterns (gyroid and grid) and different infill densities (10% and 20%) followed by infiltration of two different thermoset resin systems (epoxy and polyurethane-based) using a customized FDM 3D printer equipped with a resin dispensing unit, the optimised design and TP-TS material combination was established for best mechanical performance. Under uniaxial tensile stress, the failure modes of TP gyroid structures with polyurethane-based composites included ‘fiber pull-out’, interfacial debonding and fiber breakage, while epoxy based mixed matrix composites with all design variants demonstrated brittle failure. Higher elongation (higher area under curve) was observed in 20% infilled gyroid patterned composite with polyurethane matrix indicating the capability of operation in mechanical shock absorption application. Electron microscopy-based fractography analysis revealed that thermoset matrix properties governed the fracture modes for the thermoplastic phase. This work focused on the strategic optimisation of both toughness and stiffness of mixed matrix composite components for rapid fabrication of construction materials. Full article

Styrene–butadiene rubber (SBR) waste from the shoe industry was repurposed to produce polypropylene (PP)-based compounds, with the aim of evaluating their antistatic potential. Styrene–ethylene–propylene (SEP) was added as a compatibilizing agent, while carbon nanotubes (MWCNT) were incorporated as a conductive nanofiller. The polymer compounds were processed in an internal mixer, and injection molded. The properties evaluated included torque rheometry, melt flow index (MFI), impact strength, tensile strength, Shore D hardness, electrical conductivity, heat deflection temperature (HDT), and differential scanning calorimetry (DSC), along with scanning electron microscopy (SEM) for morphology analysis. The production of the PP/SBR/SEP (60/30/10 wt%) compound resulted in a ductile material, enhancing impact strength and elongation at break to 161.2% and 165.2%, respectively, compared to pure PP. The addition of SEP improved the compatibility of the PP/SBR system, leading to an increase in the torque curve and a reduction in the MFI. Furthermore, the SBR/SEP combination in PP accelerated the crystallization process and increased the degree of crystallinity, suggesting a nucleating effect. Carbon nanotubes, in concentrations ranging from 0.5 to 2 phr (parts per hundred resin), were added to the PP/SBR/SEP system. Only the PP/SBR/SEP/MWCNT compound with 2 phr of MWCNT was suitable for antistatic applications, exhibiting an electrical conductivity of 4.52 × 10⁻⁰⁷ S/cm. This was due to the greater distribution of MWCNT in the PP matrix, as demonstrated by SEM. In addition, remains tough at room temperature, with a 166% increase in impact strength compared to PP. However, there was a reduction in elastic modulus, tensile strength, Shore D hardness, and HDT due to increased flexibility. SBR waste can be reintegrated into the production chain to produce antistatic polymeric compounds, obtaining a tough material at room temperature. Full article

To address the issue of high fracture and wear failure rates caused by the lack of toughness and abrasion resistance in the steel used for soil-engaging components of tillage machinery, a novel composite heat treatment process, “normalizing and intercritical quenching and tempering (NIQT)”, is proposed. By regulating the austenitizing heating temperature in the intercritical area (ferrite/austenite two-phase area), the type, content, and distribution of phases in the 27MnCrB5 test sample could be precisely controlled, which further influenced the mechanical properties of the material. The results demonstrated that a multiphase composite microstructure, predominantly consisting of martensite and ferrite, could be obtained in the 27MnCrB5 steel treated by the NIQT process. The results of an EBSD test indicated that the predominant type of grain boundary following the NIQT heat treatment was a high-angle grain boundary (approximately 59.5%), which was favorable for hindering crack propagation and improving the impact toughness of the material. The results of the mechanical tests revealed that, when the quenching temperature was set to 790 °C, the 27MnCrB5 steel attained excellent comprehensive mechanical properties, with a tensile strength of 1654 MPa, elongation of 10.4%, impact energy of 77 J, and hardness of 530 HV30. Compared with conventional heat treatment processes for soil-engaging components, this novel process has the potential to enhance the performance of soil-engaging components and prolong their service life. Full article

Superhydrophobic nanocomposite coatings, prepared using adhesive and fillers, offer advantages including ease of fabrication and suitability for large-scale applications, but compared with other types of artificial superhydrophobic surfaces, poor durability still limits these surfaces from practical applications. The utilization of micro/nanoscale particles with both intrinsic hydrophobicity and robust mechanical properties to prepare coatings should significantly contribute to enhanced durability. Herein, rough and hydrophobic particles with micro/nano hierarchical structures were prepared at first, and robust superhydrophobic surfaces were fabricated using the prepared particles and additional nanoparticles. The initially prepared particles formed a rough framework of the coating, while additional nanoparticles provided inevitable nanoscale structures. A series of mechanical tests were carried out to validate the durability, and the surface with 20 wt.% NPs exhibited the best performance, withstanding 30 tape peeling tests, a 2.47 m sandpaper rubbing test (at a pressure of 5 kPa), the impact of 200 g of grit dropped from a height of 20 cm, and a 2 h acidic immersion. These appealing materials may attract attention for self-cleaning, high-speed water impact resistance, anti-icing, and anti-fouling applications in the coatings industry. Full article

Both biological and environmental factors can affect consumer behavior. Consumer behavior can also be a product of an interaction between one’s evolved biology and environmental factors. If marketers aim to increase healthy consumption behavior and decrease unhealthy behavior, they need to identify whether the behavior is a product of one’s evolved biology or environmental factors acting in isolation, or if the behavior is a product of a biology–environment interaction. Therefore, the purpose of this study is to examine the effect of biology–environment interactions on product desire. This study comprises two experiments that used a repeated-measures design. The first experiment included 315 females and examined the effect of perceived physical safety, economic well-being, and social support on the desire for beautifying and wealth-signalling products. The second experiment included 314 men and examined the effect of perceived physical safety, economic well-being, and social support on the desire for products that are used to signal wealth and toughness. The results showed that under harsh economic conditions, product desire generally decreased. However, there were significant differences in the amount of decrease between product categories in different environmental conditions. Full article