Search Results (2,806)

The increasing concern for sustainability in the footwear industry has spurred the exploration of eco-friendly alternatives for materials commonly used in sole manufacturing. This study examined the effect of incorporating rice straw and cellulose as fillers into soles made from either styrene–butadiene rubber (SBR) or thermoplastic polyurethane (TPU). Both fillers were used as a substitute in mass percentages ranging from 5 to 20% in the original SBR and TPU formulas, and their impact on mechanical properties such as abrasion and tear resistance, as well as thermal properties, was thoroughly evaluated. The results demonstrated that the inclusion of fillers affects the overall performance of the soles, with the optimal balance of mechanical and thermal properties observed at a 10% filler content. At this level, improvements in durability were achieved without significantly compromising flexibility or abrasion resistance. Thermal analysis revealed increased thermal stability at moderate filler contents. This research not only offers a sustainable alternative to traditional materials but also enhances sole performance by improving the composition. Furthermore, this study paves the way for future research on the feasibility of incorporating eco-friendly materials into other consumer product applications, highlighting a commitment to innovation and sustainability in product design. Full article

Biodegradable composites combining thermoplastic polymers and natural fibers could originate materials with synergetic mechanical and thermal properties, keeping their biodegradability. This paper describes biodegradable polymers’ mechanical and thermal properties, such as polylactic acid (PLA) and polyhydroxybutyrate (PHB) reinforced with curaua fibers. To improve the interface between matrix and reinforcement, the curaua fibers were treated by two routes: (1) treatment with hot water and subsequent mercerization with NaOH; (2) treatment with chlorite and subsequent mercerization with NaOH. The composites of PLA and PHB reinforced with natural or modified fibers (10 and 20 wt%) were obtained by extrusion and injection molding. The influence of fiber content and treatment on composite properties was studied by tensile and flexural tests, scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The results showed the removal of hemicellulose and lignin from the fibers, increasing their crystallinity and slightly decreasing their thermal stability after chemical treatments. Also, the DSC technique showed that the insertion of the curaua fibers increased the crystallinity index of all composites/PLA. The mercerized-curaua (20 wt%)/PLA composite showed the best result in the mechanical behavior, both in tensile and bending tests. The PHB composite, reinforced with curaua fibers and treated with hot water and mercerization (20 wt%), showed the best result regarding mechanic performance. To conclude, all composites improved mechanical properties compared to pure polymers. Full article

This technical paper delves into the creation and application of an enhanced mathematical model for semi crystalline thermoplastics based on the Pressure-Volume-Temperature (PVT) Two Domain Tait Equation. The model is designed to incorporate the impact of the cooling rate on the specific volume of the material. This is achieved by utilizing Flash differential scanning calorimetry (fDSC) measurements, thereby ensuring a direct correlation to the actual behavior of the material in reality. The practical application of the model in the context of injection molding simulation was also considered. This was done by integrating the mathematical model into the Moldflow software via the Solver API. The paper underscores the discontinuity issue inherent in the traditional Tait equation with cooling rates and proposes a solution that guarantees a correct transition from the liquid to the solid phase, even at high cooling rates and pressures. The results demonstrated a realistic PVT curve across a wide range of cooling rates and high pressures. The model was put to the test using a 3D tetrahedron meshed calculation model in the injection molding simulation. This study marks a significant step forward in the simulation of injection molding processes, as it successfully bridges the gap between real material properties and simplified simulation, paving the way for more accurate and efficient simulations in the future. Full article

Evaporative cooling systems have emerged as low-energy consumption alternatives to traditional vapor compression systems for building air conditioning. This study explored the feasibility of utilizing polymeric foamed materials produced through additive manufacturing as wetting materials in evaporative cooling systems. Specifically, two different commercial polylactic acid filaments, each containing a percentage of a chemical blowing agent, were studied. Experiments were designed to evaluate the influence of critical process parameters (line width, flow rate, speed, and layer height) on the performance of the resulting foamed materials in terms of evaporative cooling by conducting water absorption, capillarity, porosity, and wettability tests. Considering that high water absorption, capillarity, and porosity, coupled with an intermediate contact angle, are advantageous for evaporative cooling effectiveness, a low flow rate was found to be the most important parameter to improve these properties’ values. The results showed that the appropriate combination of polymer and process parameters allowed the production of foamed polymer-based materials processed by additive manufacturing technology with optimal performance. Full article

Additive manufacturing of advanced materials has become widespread, encompassing a range of materials including thermoplastics, metals, and ceramics. For the ceramics, the complete production process typically involves indirect additive manufacturing, where the green ceramic part undergoes debinding and sintering to achieve its final mechanical and thermal properties. To avoid unnecessary energy-intensive steps, it is crucial to assess the internal integrity of the ceramic in its green stage. This study aims to investigate the use of active thermography for defect detection. The approach is to examine detectability using two benchmarks: the first focuses on the detectability threshold, and the second on typical defects encountered in 3D printing. For the first benchmark, reflection and transmission modes are tested with and without a camera angle to minimize reflection. The second benchmark will then be assessed using the most effective configurations identified. All defects larger than 1.2 mm were detectable across the benchmarks. The method can successfully detect defects, with transmission mode being more suitable since it does not require a camera angle adjustment to avoid reflections. However, the method struggles to detect typical 3D-printing defects because the minimum defect size is 0.6 mm, which is the size of the nozzle. Full article

The aim of this study is to prepare new cellulose derivatives that show good feasibility and processability. Accordingly, in this study, we demonstrate Michael addition to hydroxyalkyl acrylates, that is, 2-hydroxyethyl and 4-hydroxybutyl acrylates (HEA and HBA, respectively), to synthesize amorphous cellulose derivatives under alkaline conditions. The reactions were carried out in the presence of LiOH in ionic liquid (1-butyl-2,3-dimethylimidazolium chloride)/N,N-dimethylformamide (DMF) solvents at room temperature or 50 °C for 1 h. The Fourier transform infrared and ¹H nuclear magnetic resonance (NMR) measurements of the products supported the progress of Michael addition; however, the degrees of substitution (DS) were not high (0.3–0.6 for HEA and 0.6 for HBA). The powder X-ray diffraction analysis of the products indicated their amorphous nature. The cellulosic Michael adduct from HEA with DS = 0.6 was swollen with high polar organic liquids, such as DMF. In addition to swelling with these liquids, the cellulosic Michael adduct from HBA was soluble in dimethyl sulfoxide (DMSO), leading to its ¹H NMR analysis in DMSO-d₆. This adduct was found to form a cast film with flexible properties from its DMSO solutions. Furthermore, films containing an ionic liquid, 1-butyl-3-methylimidazolium chloride, showed thermoplasticity. The Michael addition approach to hydroxyalkyl acrylates is quite effective to totally reduce crystallinity, leading to good feasibility and processability in cellulosic materials, even with low DS. In addition, the present thermoplastic films will be applied in practical, bio-based, and eco-friendly fields. Full article

This work describes the preparation of highly homogeneous thermoplastic starches (TPS’s) with the addition of 0, 5, or 10 wt.% of maltodextrin (MD) and 0 or 3 wt.% of TiO₂ nanoparticles. The TPS preparation was based on a two-step preparation protocol, which consisted in solution casting (SC) followed by melt mixing (MM). Rheology measurements at the typical starch processing temperature (120 °C) demonstrated that maltodextrin acted as a lubricating agent, which decreased the viscosity of the system. Consequently, the in situ measurement during the MM confirmed that the torque moments and real processing temperatures of all TPS/MD systems decreased in comparison with the pure TPS. The detailed characterization of morphology, thermomechanical properties, and local mechanical properties revealed that the viscosity decrease was accompanied by a slight decrease in the system homogeneity. The changes in the real processing temperatures might be quite moderate (ca 2–3 °C), but maltodextrin is a cheap and easy-to-add modifier, and the milder processing conditions are advantageous for both technical applications (energy savings) and biomedical applications (beneficial for temperature-sensitive additives, such as antibiotics). Full article

This manuscript explores the development of sustainable biopolymer composites using suberin extraction waste, specifically suberinic acid residues (SAR), as a 10% (w/w) reinforcing additive in polylactide (PLA) and thermoplastic starch–polylactide blends (M30). The materials were subjected to a detailed analysis using thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and dynamic mechanical analysis (DMA) to assess their thermal, mechanical, and structural properties. The study confirmed the amorphous nature of the biopolymers and highlighted how SAR significantly influences their degradation behavior and thermal stability. M30 exhibited a multi-step degradation process with an initial decomposition temperature (T5%) of 207.2 °C, while PLA showed a higher thermal resistance with decomposition starting at 263.1 °C. Mechanical performance was assessed through storage modulus (E′) measurements, showing reductions with increasing temperature for both materials. The research provides insights into the potential application of SAR-enriched biopolymers in sustainable material development, aligning with circular economy principles. These findings not only suggest that SAR incorporation could enhance the mechanical and thermal properties of biopolymers, but also confirm the effectiveness of the research in reassurance of the audience. Full article

Titanium (Ti) is considered the gold standard material for provisional implant restorations. Polyetheretherketone (PEEK), a polymeric thermoplastic material, has been progressively used in prosthetic, restorative, and implant dentistry. Recently, PEEK has been used in implant dentistry as a provisional implant restoration. Plaque accumulation and biofilm formation become the major concerns when infection and inflammation occur in the peri-implant tissue. Few reports were studied regarding the biofilm formation on the PEEK surface. This study aimed to compare plaque accumulation between the PEEK and Ti healing abutments. In an in vitro setting, the Ti healing abutment and PEEK healing abutment were subjected to biofilm formation; the result was collected after 24 h, 48 h, 72 h, and 7 days. Biofilms were studied following staining with crystal violet. The data were analyzed by Two-Way ANOVA. It was found that between Ti healing abutment and PEEK healing abutment materials, the biofilm formation on the PEEK surface is slightly higher than Ti, but no statistical difference (p > 0.05) was found. The results suggested that plaque accumulation between the Ti healing abutment and the PEEK healing abutment was not different. We concluded that the plaque accumulation on the surface PEEK healing abutment was similar to the conventional Ti healing abutment materials. Hence, both the PEEK and Ti healing abutments can be used as a healing abutment biomaterial according to the requirements of the prostheses in implant dentistry. Full article

Polymers synthesized with end-of-life consideration allow for recovery and reprocessing. “Living-anionic polymerization (LAP)” and hydrosilylation reaction were utilized to synthesize hair-end furan functionalized hairy nanoparticles (HNPs) with a hard polystyrene (PS) core and soft polydimethylsiloxane (PDMS) hairs via a one-pot approach. The synthesis was carried out by first preparing the living core through crosslinking styrene with divinylbenzene using sec-butyl lithium, followed by the addition of the hexamethylcyclotrisiloxane (D3) monomer to the living core. The living polymer was terminated by dimethylchlorosilane to obtain the HNPs with Si-H functional end groups. The furan functionalization was carried out by the hydrosilylation reaction between the Si-H of the functionalized HNP and 2-vinyl furan. Additionally, furan functionalized polystyrene (PS) and polydimethylsiloxane (PDMS) were also synthesized by LAP. ¹H NMR and ATR-IR spectra confirmed the successful synthesis of the target polymers. Differential scanning calorimetry showed two glass transition temperatures indicative of a polydimethylsiloxane soft phase and a polystyrene hard phase, suggesting that the HNPs are microphase separated. The furan functionalized HNPs form thermo-reversible networks upon crosslinking with bismaleimide (BMI) via a Diels−Alder coupling reaction. The kinetics of the forward Diels–Alder reaction between the functionalized polymer and BMI were studied at three different temperatures: 50 °C, 60 °C, and 70 °C by UV–Vis spectroscopy. The activation energy for the furan functionalized HNPs reaction with the bismaleimide was lower compared to the furan functionalized polystyrene and polydimethylsiloxane linear polymers. The crosslinked polymer network formed from the Diels−Alder forward reaction dissociates at around 140–154 °C, and the HNPs are recovered. The recovered HNPs can be re-crosslinked at 50 °C. The results suggest that furan functionalized HNPs are promising building blocks for preparing thermo-reversible elastomeric networks. Full article

This study presents a new approach to developing protective material structures for personal protective equipment (PPE), and in particular for protective gloves, with the use of ultrasonic and contact welding processes. The goal was to assess the quality of joints (welds) obtained between a synthetic polyamide knitted fabric (PA) and selected polymers (PLA, ABS, PET-G) in the developed materials using X-Ray microtomography (micro-CT). Quantitative and qualitative analyses were performed to determine the joint area produced by the selected welding methods for the examined materials. In this article, we assumed that obtaining a greater contact area seems to be the most promising from the point of view of future PPE utility tests characterizing protective glove structures. This research is a continuation of our previous study focused on functional 3D-printed polymeric materials for protective gloves. Full article

Additive manufacturing (AM) plays a significant role in the 4th Industrial Revolution due to its flexibility, allowing AM equipment to be connected, monitored, and controlled in real time. In advance, the minimum waste of material, the agility of manufacturing complex geometries, and the ability to use recycled materials can provide an advantage to this manufacturing method. On the other hand, the poor strength and durability of the thermoplastics used in the manufacturing process are the major drawback that keeps AM behind common production methods such as casting and machining. Fibre-reinforced polymers can enhance mechanical properties, advance AM from the commonly used polymers, and make AM competitive against conventional production methods. The main focus of the current review is to examine the work conducted in the field of reinforced additively manufactured technologies in the literature of recent years. More specifically, this review discusses the conducted research in the composite fibre coextrusion (CFC) additive manufacturing techniques developed over the past years and the materials that can be used. In addition, this study includes an up-to-date comprehensive review of the evaluation of fibre-reinforced 3D printing along with its benefits in terms of mechanical response, namely tensile, flexural, compression and energy absorption, anisotropy, and dynamic properties. Finally, this review highlights possible research gaps regarding fibre-reinforced AM and proposes future directions, such as deeper investigations into energy absorption and anisotropy, to position fibre-reinforced AM as a preferred fabrication method for ready-to-use parts in cutting-edge industries, including automotive, aerospace, and biomedical sectors. Full article

Incremental sheet forming has emerged as an excellent alternative to other material forming procedures, incrementally deforming flat metal sheets into complex three-dimensional profiles. The main characteristics of this process are its versatility and cost-effectiveness; additionally, it allows for greater formability compared to conventional sheet forming processes. Recently, its application has been extended to polymers and composites. The following review aims to present the current state of the art in the incremental sheet forming of polycarbonate, an outstanding engineering plastic, beginning with initial studies on the feasibility of this process for polymers. Attention is given to the advantages, drawbacks, and main applications of incrementally formed polycarbonate sheets, as well as the influence of process parameters and toolpath strategies on features such as formability, forming forces, deformation and failure mechanisms, geometric accuracy, surface quality, etc. Additionally, new hybrid forming methods for process optimisation are presented. Finally, a discussion is provided on the technical challenges and future research directions for incremental sheet forming of polycarbonate and, more generally, thermoplastics. Thus, this review aims to offer an extensive overview of the incremental forming of polycarbonate sheets, useful to both academic and industrial researchers working on this topic. Full article

Wood–Textile Composites (WTCs) are a new type of composite material based on willow wood strips and polypropylene that combines the properties of classic natural-fiber-reinforced polymers with an innovative textile wood design. While the basic quasi-static properties have already been investigated and described, there is a lack of knowledge about the behavior of the material under dynamic-cyclic and dynamic-impact loading as well as in relation to basic wood construction parameters. The present study is intended to contribute to the later use of the developed material, e.g., in architecture. For this purpose, fatigue tests, dart drop tests (impact and penetration), impact bending tests, and embedment tests were carried out. It was shown that embedding wood fabrics in a thermoplastic matrix leads to a significant increase in resistance to impact loads compared to the neat basic materials. It was also shown that the ratio of the failure stress in the fatigue test to the tensile strength of the WTC corresponds to that of other fiber-reinforced thermoplastics at around 70%. The embedment tests showed that WTC has good values compared to neat wood. Full article