Search Results (935)

Background and Objectives: Urine serves as a vital diagnostic fluid, and urine cytology analysis plays a crucial role in identifying urinary system illnesses such as bladder cancer and kidney stones. The Paris System for Reporting Urinary Cytology establishes a uniform method for diagnosing urinary tract cancer. This study aimed to provide valuable insights that can inform diagnostic strategies related to kidney stones and ultimately improve patient outcomes via the early detection of the cellular changes associated with kidney stones and their relation to kidney function tests. Materials and Methods: A comparative study was conducted and comprised two groups: group 1, consisting of 50 patients diagnosed with kidney stones, and group 2, comprising 50 patients diagnosed with other kidney diseases. Renal function tests and urinalysis (via the PAP staining of urine cellular deposits to detect nuclear changes) were performed, and the results were analyzed. Results: There was a statistically significant increase in urinary red blood cells, white blood cells, and nuclear reactive atypical changes in urinary sediments of kidney stone patients compared to the patients without stones, while there was a decrease in the estimated glomerular filtration rate (eGFR). eGFR showed a 96.7% specificity in detecting cases with nuclear reactive atypia. Conclusions: eGFR emerges as a reliable diagnostic marker for the comprehensive assessment of kidney stones, particularly when associated with nuclear atypia. The significant correlation between the indicators of chronic kidney disease, such as decreased eGFR, and the presence of kidney stones emphasizes the urgent need for efficient diagnostic practices. Full article

The valorisation of sludges from aggregate production into construction materials is required for full circularity in mining waste management. This study explores valorisation pathways, relevant regulatory frameworks, and End-of-Waste (EoW) criteria for specific settings in Spain and Norway. The explored valorisation routes involved the production of filler, supplementary cementitious materials (SCMs), and lightweight aggregates (LWAs) for the production of cement-based products, and precursors for 3D printed construction material. The sludge from Norway revealed a non-polluted stream and a stream contaminated with organic phases and clays. Sludge-based filler proved suitable in concrete production with contents of up to 40% of total binder, providing adequate consistency and cohesion. However, clays in the sludge increased the demand for water and superplasticizer. Clay contents were still insufficient for the applications as SCMs, as the calcined sludge demonstrated limited reactivity. The application to produce LWAs was promising, but further microstructure optimization is still required. The clay content was also relevant for the sludge from the site in Spain, as it provided 3D printing mixes with good plasticity. The dosage optimization still required the addition of enzymes, limestone, and natural fibres to improve cohesion, workability, and resistance to the cracking of the 3D printing mix. Full article

Purifying polluted water is becoming a crucial concern to meet quantity and quality demands as well as to ensure the resource’s sustainability. In this study, a new material was prepared from cherry stone powder and sodium alginate, and its capacity to remove methylene blue (MB) from water was determined. The characterization of the resulting product, performed via scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR), revealed that the raw material considered for the synthesis was successfully embedded in the polymeric matrix. The impact of three of the main working parameters (pH 3–9, adsorbent dose 50–150 g/L, contact time 60–180 min) on the retention of MB was evaluated through response surface methodology with a Box–Behnken design. In the optimal settings, a removal efficiency of 80.46% and a maximum sorption capacity of 0.3552 mg/g were recorded. MB retention followed the pseudo-second-order kinetic and was suitably described by Freundlich, Khan, Redlich–Peterson, and Sips isotherm models. The experimental results show that the synthesized composite can be used for at least three successive cycles of MB adsorption. From these findings, it can be concluded that the use of the cherry-stone-based adsorbent is environmentally friendly, and efficacious in the removal of contaminants from the water environment. Full article

The rising demand for açaí berries in Amazonian Brazil and French Guiana generates a significant amount of waste, namely the fruit’s stone, which accounts for 80% of the dry fruit’s mass. Recently, various studies have explored the potential valorization of açaí waste in the civil engineering sector, including the functionalization of the fibers surrounding the stone and the multiphysics testing of composite materials based on açaí fibers and/or stones, treated or untreated. This literature review aims to provide an overview of the technology readiness levels (TRLs) of the existing techniques capable of reducing the environmental impact of both the cultivation and management of naturally occurring açaí. While the research to date is promising, it remains at the prototype stage, and the mass ratio of waste in composites, regardless of their type, limits addressing the underlying ecological problem of açaí waste processing. Further experimental investigations are required to improve the functionalization processes, enabling the use of higher proportions of fibers and/or stones in cementitious composites and their large-scale production. Full article

The deposition of Yellow River sediment in the middle and lower reaches is a significant factor in the siltation of reservoirs and the occurrence of serious flooding along the river. The efficient and valuable utilization of Yellow River sediment has already become a key research topic in this field. In this study, we have employed Yellow River sediment as the primary material, in conjunction with commercially available slag, fly ash, and quicklime as the binder, to develop a novel type of artificial flood-prevention stone. Following a 28-day standard curing procedure, the highest compressive strength of the prepared artificial stone was recorded at 4.29 MPa, with a value exceeding 0.7 MPa under wet conditions. The results demonstrated that the prepared artificial stone met the specifications for artificial flood-prevention stones. The curing mechanism, as evidenced by analyses from SEM and XRD testing, indicated that the alkali excitation process in the binder, which produced C-A-S-H gel, was the key factor in enhancing the compressive strength of the specimens. Notably, an evaluation of the amount of CO₂ emissions and the cost of the artificial stone concluded that the preparation process was both environmentally friendly and cost-effective. Full article

Introduction: Digital workflow and intraoral scanners (IOSs) are used to clinically obtain data for a wide range of applications in restorative dentistry. The study aimed to compare two different IOSs with inexperienced users in the digital workflow of oral split manufacturing. Material and Methods: Anonymous stone models of upper and lower dentate patients were used. Both models were scanned with a desktop 3D scanner 3Shape D2000 to obtain the reference models (STL_R). Ten inexperienced operators scanned each model three times with each IOS system (3Shape TRIOS 3 and Carestream CS 3800). Finally, 20 intraoral scanners were randomly chosen from the obtained dataset (10 per IOS system) to design and manufacture 20 nightguards. All the nightguards were scanned. Trueness and precision were calculated and compared between the two IOS systems. Results: All the mean errors both for trueness and precision were below 40 µm, more than acceptable for the design and manufacturing of intraoral devices such as nightguards. All the mean errors (except one) for trueness between the inner part of the nightguards and the upper control model were below 100 µm, less than a printed layer height. For inexperienced operators, both IOSs are suitable for a digital workflow of manufacturing occlusal splints. Full article

Recycling olive waste, a major by-product of the olive oil industry, presents significant environmental and economic benefits. This study explores the potential of olive waste (OW) by-products, specifically their individual components such as olive stones (OS), olive oily pomace (OS) and olive oil-free pomace (OF), as sustainable alternatives to wood in eco-friendly composite materials, alongside other residues such as miscanthus, spent mushroom substrate and recycled textile waste. Composite panels were produced with densities ranging from 685 to 907 kg/m³ through thermocompression. The manuscript details the production methodology and assesses the panel’s thermal performance, water absorption, and mechanical strength. The aim is to assess the viability of these alternative materials in producing composites that could serve as environmentally friendly substitutes for traditional wood-based products. Oil-free pomace is a promising and effective alternative to wood, suitable for dry environments. Composite panels composed of miscanthus or spent mushroom substrate and oil-free pomace met the EN 312 standards for general-purpose products in dry conditions, highlighting their potential for use in sustainable applications. Full article

The deterioration of dams and levees is an increasing concern for both infrastructure integrity and environmental sustainability. The extensive repercussions, including the displacement of communities, underscore the imperative for sustainable interventions. This study addresses these challenges by investigating the stabilization of dredged material (DM) for diverse applications. Seven mixtures incorporating fly ash, lime, and cement were formulated. The Standard Compaction Test was used to determine optimal density–moisture conditions, which helped with brick fabrication. Bricks were tested for compressive strength over various curing periods, and the durability of the 28-day-cured samples was evaluated by performing water immersion tests following the New Mexico Code specifications. Scanning electron microscopy (SEM) was used to assess microstructural bonding. Results confirm that the inclusion of cementitious stabilizers modifies the material’s microstructure, resulting in enhancements of both strength and water resistance. Notably, the stabilized material demonstrates potential for use in non-fired brick manufacturing and as bridge stones for waterway erosion control. This dual-function application offers a sustainable and economically feasible approach to managing dredged materials. Full article

The erosion phenomena of the natural stone in cultural heritage are induced by various sources. Consequently, the development of multifunctional protective materials that combine two or more useful properties is an effective strategy in addressing the synergistic effects of various erosion mechanisms. A multifunctional coating, consisting of a silane-based precursor and zinc oxide (ZnO) nanoparticles (NPs), is produced and tested for the protection of limestone. The hybrid coating combines the following three properties: superhydrophobicity, including water-repellency, photocatalytic self-cleaning and biocidal activity. The relative concentration of the NPs (0.8% w/w), used for the suggested composite coating, is carefully selected according to wetting studies, colourimetric measurements and durability (tape peeling) tests. The non-wetting state is evidenced on the surface of the composite coating by the large contact angle of water drops (≈153°) and the small contact angle hysteresis (≈5°), which gives rise to a physical self-cleaning scenario (lotus effect). The photocatalytic chemical self-cleaning is shown with the removal of methylene blue, induced by UV-A radiation. Moreover, it is shown that the suggested coating hinders the incubation of E. coli and S. aureus, as the inhibitions are 94.8 and 99.9%, respectively. Finally, preliminary studies reveal the chemical stability of the suggested coating. Full article

Recent scholarship on the late medieval Pays de Vaud has allowed for a better understanding of the Reformation (1536) in this region, revealing it as a period marked not only by ruptures but also by significant adaptations and continuities. This article employs a trans-periodic approach to explore the material culture of the Eucharist, tracing its developments across the late medieval and Reformation periods. Key findings include the transition from stone altars to wooden communion tables, the contested continuity in the substance and shape of chalices, and the gradual shift from unleavened hosts to plain bread. These changes highlight a complex interplay of theological and practical concerns. The study provides a nuanced perspective on the Reformation in the Pays de Vaud, emphasizing the ongoing influence of medieval ecclesiastical reforms and the gradual nature of liturgical transformations. This analysis underscores the importance of material culture in understanding religious and cultural shifts during this pivotal period. Full article

Inefficiency and poor quality are the main problems in polishing natural heterogeneous marbles using sol-gel (SG) diamond pads. A strategy was proposed to address these issues by establishing a natural heterogeneous marble polishing model based on the optimal polishing time. The surface evolution and optimal time for polishing natural heterogeneous marble were systematically investigated. Six different types of marbles were polished by the sol-gel diamond pads. The surface glossiness, roughness, peak–valley value, and surface morphology of the marbles were measured and analyzed after different polishing times. The optimal polishing time for each marble was revealed using sol-gel diamond pads. The experimental results show that the standard deviation of the hardness distribution of marble tile significantly affects the material removal inconsistency and evolution of the surface during polishing, resulting in different optimal polishing times for different kinds of marble. The larger the standard deviation of the hardness of the marble is, the more difficult it is to obtain better surface quality, and the orange peel effect is more likely to occur. Furthermore, the optimal polishing time has a good logarithmic relationship with the standard deviation of the hardness distribution. Finally, a curve model of the optimal polishing time for each marble was established. The determination of the optimal polishing time can effectively optimize the polishing process, simplify the processing flow, improve production efficiency, and reduce production costs. The proposed method and obtained results in this paper can provide a theoretical basis and reference for polishing other types of heterogeneous stone materials. Full article

Since prehistoric times, indigenous residents of southwest British Columbia, Canada, collected water-worn nephrite specimens from the gravel bars along the Fraser River, using the stone for the manufacture of tools that were widely traded with other tribes. Allochthonous nephrite occurs in another geologic setting. Late Pleistocene continental glaciers transported nephrite and many other rock types from western Canada to northwest Washington State, producing extensive sediment deposits that border the Salish Sea coast in Whatcom and Island Counties, Washington. This material was little utilized by indigenous residents, but “black jade” specimens are prized by modern collectors. The depositional history and mineralogy of this material has received little attention. X-ray diffraction and SEM/EDS analyses indicate that the Salish Sea “black jade” is a form of impure nephrite that probably originated from metamorphism of a mafic igneous parent material (metabasite). The texture consists of prismatic amphibole crystals (ferro-actinolite) set in a matrix rich in plagioclase feldspar. Pyrite inclusions are locally present. A second material, sometimes erroneously labelled “muttonfat jade” by amateur collectors, consists of an intermixture of quartz and sillimanite. Full article

This study conducted a big data mining and lexical co-occurrence network analysis on design texts sourced from architectural media over the past decade, systematically evaluating the application trends of materials in architectural design. This approach distinguishes itself from traditional case studies that rely on small samples of material applications in architectural design, thereby significantly enhancing the generalizability of the conclusions. The research reveals a 27.2% increase in the material–project frequency of architectural materials over the past ten years, indicating that the materiality of architecture is gradually making a comeback to counteract the trend toward architectural visualization. Within this context, material properties, material interactions, and material presentation in architectural components emerge as universal concerns in architectural design. Notably, the sustainability and energy efficiency of wood and concrete have emerged as pivotal topics in architectural practice, in addition to their structural functions. Additionally, over the past decade, the material–project frequencies of brick and stone have grown rapidly, with respective increases of 24.3% and 11.8%. Brick and stone primarily respond to the locality and style of architectural design by emphasizing their inherent texture and color, thereby enhancing the spatial perception and experience within the designs. This study lays the groundwork for quantitative research on the influence of building materials on architectural design, and it illuminates current trends and preferences in material application within architectural design, thereby empowering architects to make more informed decisions in their material selection. Full article

External and internal microclimatic conditions, biodeterioration, anthropogenic factors, etc, influence the natural stone support for artifacts and built heritage. Based on this fact, the present study explores the effectiveness of nano-TiO₂ in preserving and enhancing the durability of natural stone used in the façades of heritage buildings, focusing on the Markovits-Mathéser House in Oradea Municipality, Romania. The investigation involved treating rock samples (fossiliferous limestone) with 2% and 5% nano-TiO₂ solutions and subjecting them to simulated extreme climatic conditions for the analyzed area in a controlled climatic chamber for six months. The treated samples demonstrated a significantly higher compressive strength than untreated benchmarks. SEM analyses confirmed that nano-TiO₂ formed a protective layer, filling micro-cracks and pores, thereby enhancing the stone’s resistance to environmental stressors. The study also found that the nanoparticle coating maintained its integrity under extreme temperature and humidity variations, with only a slight decrease in surface coverage. These findings suggest that nano-TiO₂ coatings significantly improve heritage building materials’ mechanical properties and longevity. However, the study highlights the importance of careful application and long-term evaluation to ensure environmental and health safety. Overall, nano-TiO₂ presents a promising solution for the conservation of cultural heritage, offering enhanced durability and protection against climatic and environmental challenges. Further research is recommended to optimize application workflow and formulations for broader and more effective use in heritage conservation. Full article

Plant oils are currently not only an essential element of the healthy eating pyramid, but also a valuable cosmetic material, which, in line with the eco-friendly trends of recent years, is effectively replacing petroleum-derived fatty ingredients. The fatty acids, phenolic compounds, pigments, and vitamins (e.g., A and E) present in plant oils contribute to their health-promoting properties, including antioxidant activity. This study assessed the contents of carotenoids and chlorophylls, as well as the antioxidant properties of 10 selected plant oils. Fenugreek seed oil was shown to have the highest total content of carotenoids, and the most β-carotene. Chokeberry and rosehip oils also contained large amounts of provitamin A, in comparison to the other oils tested. Lycopene was the dominant compound in black currant and rosehip seed oils. Among chlorophyll pigments, elderberry oil had the highest content of chlorophyll a, while black currant oil had large amounts of both chlorophyll a and chlorophyll b. The antioxidant properties of the cold pressed oils obtained from selected seeds and fruit stones, assessed by electron paramagnetic resonance (EPR) spectroscopy as the ability to interact with the DPPH (2,2-diphenyl-1-picrylhydrazyl) free radical, can be ranked as follows: pomegranate > fenugreek > poppy > black currant > chokeberry > rosehip > perilla > elderberry > carrot > fig. The results of this study showed that these plant oils are valuable natural materials with antioxidant properties, which can be an important complement to synthetic antioxidants due to their additional skin care properties. Full article