Search Results (14,373)

Duplex stainless-steel grade 2205 (2205 DSS) is the most widely used of the current duplex materials. The duplex steel alloy is characterized by high strength and high corrosion resistance through enhancing nitrogen and molybdenum contents. The activated tungsten inert gas (ATIG) welding technique uses the same equipment as tungsten inert gas (TIG), but prior to the welding operation, a thin layer of flux is deposited. Activation fluxes are known to influence the shape and energy characteristics of the arc. They promote the change in shapes and dimensions of the welds, namely, increasing the depth and narrowing the weld width. This work is dedicated to investigate the influence of the thermophysical properties of individual metal oxide fluxes on 2205 DSS welding morphology. It helps also to identify the recommended flux properties in order to perform full penetrated ATIG welds. Thirteen kinds of oxides (SiO₂, TiO₂, Fe₂O₃, Cr₂O₃, ZnO, Mn₂O₃, V₂O₅, MoO₃, Co₃O₄, SrO, ZrO₂, CaO, and MgO) have been tested and three current intensity levels (120, 150 and 180 A) have been considered. The results showed that the main input factors affecting the weld depth (D) were the welding current intensity with a contribution of up to 53.36%, followed by the oxides enthalpy energy with 15.05% and then by the difference between the oxides and the base metal of 2205 DSS (BM 2205 DSS) melting points with a contribution of 9.71% of the data variance. The conditions on individual oxides’ thermophysical properties to achieve full penetrated weld beads have been also revealed. Full article

The hydrodynamic processes of landfill leachate migration in the base of a solid waste landfill can have a critical impact on the natural environment. In the case of improper operation of municipal solid waste placement facilities, highly contaminated leachate may penetrate into groundwater and subsequently into surface water. This work addresses fundamental issues of multicomponent fluid propagation in a multilayer porous medium, taking into account temperature inhomogeneities caused by waste decomposition with heat release. The regimes of diffusion and convection of leachate water penetrating into soil layers in the base of municipal solid waste facilities are numerically studied. Archival data from a set of field and laboratory measurements in the area of the operating landfill are used to model the features of pollutant propagation and determine migration parameters. The process of pollutant propagation and migration is described by quantitative values of dry residue content in leachate. Factors that have a significant impact on the migration of leachate are considered. The main ones are convective transfer, diffusion, and properties of the geological composition of the landfill base, which are taken into account in the mathematical formulation of the problem. The calculations show that leachate self-heating can substantially intensify leachate filtration and has to be taken into account in the assessment of leachate migration rate. Full article

Photodynamic therapy (PDT) has emerged as a promising therapeutic approach owing to its non-invasive nature and minimal toxicity. PDT involves the administration of a photosensitizing agent (PS), which, upon light activation, induces a photodynamic reaction (PDR), leading to targeted cell destruction. However, developing resistance to PDT poses a significant challenge to its effectiveness. Various factors, including properties and administration of PSs, mediate this resistance. Despite the widespread use of substances like 5-aminolevulinic acid (5-ALA) and protoporphyrin, their efficacy is limited due to restricted tumor penetration and a lack of tumor targeting. To address these limitations, nano-delivery techniques and newer PSs like Aza-BODIPY and its derivatives, which offer enhanced tissue penetration, are being explored. In this paper, we provide an overview of resistance mechanisms in PDT and discuss novel methods, substances, and technologies to overcome resistance to improve clinical outcomes in tumor treatment. Full article

This study investigated the influence of sea–land breezes on nocturnal spatial and temporal distribution of ozone (O₃) and its potential effects on particulate nitrate formation in Qingdao, a coastal city in northern China. Observation campaigns were conducted to measure surface air pollutants and meteorological factors during a typical sea–land breezes event from 22 to 23 July 2022. A coherent Doppler lidar (CDL) system was employed to continuously detect three-dimensional wind fields. The results revealed that nocturnal ozone levels were enhanced by a conversion of sea–land breezes. Initially, the prevailing northerly land breeze transported high concentrations of O₃ and other air pollutants from downtown to the Yellow Sea. As the sea breeze developed in the afternoon, the sea breeze front advanced northward, resulting in a flow of high O₃ concentrations back into inland areas. This penetration of the sea breeze front led to a notable spike in O₃ concentrations between 16:00 on 22 July and 02:00 on 23 July across downtown areas, with an average increase of over 70 μg/m³ within 10 min. Notably, a time lag in peak O₃ concentration was observed with southern downtown areas peaking before northern rural areas. During this period, combined pollution of O₃ and PM_2.5 was also observed. These findings indicated that the nighttime increase in O₃ concentrations, coupled with enhanced atmospheric oxidation, would likely promote the secondary conversion of gaseous precursors into PM_2.5. Full article

A popular belief for why polar bears have black skin is to increase solar heat gain from solar radiation that penetrates through a translucent fur layer made of unpigmented hollow hair. To examine the relative importance of skin color on solar heat gain, we measured thermal gradients, heat flux, and solar transmittance through a polar bear pelt under solar irradiation while thermally anchored to a temperature-controlled plate set to 33 °C. We found that for 60–70% of the dorsal region of the pelt where the fur layer is thickest, solar energy cannot reach the skin through the fur (solar transmittance ≤ 3.5 ± 0.2%) and therefore skin color does not meaningfully contribute to solar heat gain. In contrast, skin pigmentation was important in the remaining areas of the pelt that were covered with thinner fur. This information was used to select commercially available materials according to their solar optical properties to build biomimetic outdoor apparel with enhanced solar heat gain by a factor of 3 compared to standard outerwear constructions. Full article

Background/Objectives: The search for novel ways of providing treatment also targets the development of formulations used in drug delivery. Among the important characteristics of pharmaceutical gels are their ability to penetrate membranes, their capability to offer rapid response, and their capacity to avoid the hepatic metabolization route followed by many drugs. Bigels combine the advantages of both hydrogels and oleogels, creating a biphasic system that might improve the solubility of amiodarone in water, which is otherwise poorly soluble. This study aimed to succeed in formulating stable amiodarone hydrochloride bigels (coded from ABG1-ABG6) destined for atrial application and evaluating them from a pharmacotechnical perspective. Methods: Three of the six initial formulations presented stability and underwent studies of spreadability, rheology, drug content, textural properties, and microbiological activity. A statistical analysis was performed on penetrometry and drug assay data. Results: The spreadability varied from 1734.07 mm² (ABG1) to 2163.85 mm² (ABG6), while the drug concentration ranged between 1.35 and 1.49% (w/w). The textural profile analysis highlighted superior hardness, cohesiveness, and resilience for ABG6 and higher adhesion for ABG2. Both presented pseudoplastic thixotropic behavior, while a plastic thixotropic flow was registered in the case of ABG1. Conclusions: All three bigels are suitable for amiodarone incorporation; however, the influence of the type of ingredients chosen on the texture and properties of the formulations was reflected in the data gathered upon evaluation. Full article

Mitragynine is an “atypic opioid” analgesic with an alternative mechanism of action and a favorable side-effect profile. Our aim was to optimize the alkaloid extraction procedure from kratom leaves and to determine and isolate the most relevant compounds capable of penetrating the central nervous system. The PAMPA-BBB study revealed that mitragynine and its coalkaloids, speciociliatine, speciogynine, and paynantheine, possess excellent in vitro BBB permeability. An optimized sequence of CPC, flash chromatography, and preparative HPLC methods was used to isolate the four identified BBB+ alkaloids. To improve the bioavailability of the isolated alkaloids, their cyclodextrin (CD) complexation behavior was investigated via affinity capillary electrophoresis using almost 40 CD derivatives. The apparent alkaloid–CD complex stability constants were determined and compared, and the most relevant CDs phase-solubility studies were also performed. Both the neutral and negatively charged derivatives were able to form complexes with all four kratom alkaloids. It was found that cavity size, substituent type, and degree of substitution also influenced complex formation. The negatively charged Sugammadex, Subetadex, and the sufoalkylated-beta-CD analogs were able to form the most stable complexes, exceeding 1000 M⁻¹. These results serve as a good basis for further solubility and stability enhancement studies of kratom alkaloids. Full article

The future charging requirements of electric trucks will lead to new demands on the power grid. In order not to slow the expansion of the charging infrastructure for electric trucks, the power grid must be strengthened for this purpose. However, due to the limited penetration of electric trucks in fleets to date, grid planners lack information on their time- and location-dependent charging demand. The question arises as to how the charging demand of electric trucks can be realistically taken into account in power grid simulations. This paper therefore presents a methodology that makes it possible to quantify the charging demand of electric trucks at typical charging locations and derives initial parameters for power system planning with electric trucks. For location-based charging demand modeling, the arrival and departure behavior of trucks at representative logistics centers is combined with mobility data and vehicle parameters. This allows the determination of time series-based charging demand. A charging demand analysis at five different logistics center types shows that that energy demand, peak load, and temporal behavior vary greatly depending on the center type. It is therefore advisable to take these different charging location types into account when designing the electricity grids. Full article

The snow melting and runoff process in the black soil area of Northeast China has led to soil quality degradation in farmland, posing a threat to sustainable agricultural development. To investigate the regulatory effect of tillage layer construction on the infiltration characteristics of snowmelt water, a typical black soil in Northeast China was selected as the research object. Based on field experiments, four protective tillage treatments (CK: control treatment; SB: sub-soiling treatment; BC: biochar regulation treatment; SB + BC: sub-soiling tillage and biochar composite treatment) were set up, and the evolution of soil physical structure, soil thawing rate, snow melting infiltration characteristics, and the feedback effect of frozen layer evolution on snowmelt infiltration were analyzed. The research results indicate that sub-soiling and the application of biochar effectively regulate soil aggregate particle size and increase soil total porosity. Among them, at the 0–10 cm soil layer, the soil mean weight diameter (MWD) values under SB, BC, and SB + BC treatment conditions increased by 6.25%, 16.67%, and 19.35%, respectively, compared to the CK treatment. Sub-soiling increases the frequency of energy exchange between the soil and the environment, while biochar enhances soil heat storage performance and accelerates the melting rate of frozen soil layers. Therefore, under the SB + BC treatment conditions, the maximum soil freezing rate increased by 21.92%, 5.67%, and 25.12% compared to the CK, SB, and BC treatments, respectively. In addition, sub-soiling and biochar treatment effectively improved the penetration performance of snowmelt water into frozen soil layers, significantly enhancing the soil’s ability to store snowmelt water. Overall, it can be concluded that biochar regulation has a good improvement effect on the infiltration capacity of surface soil snowmelt water. Sub-soiling can enhance the overall snowmelt water holding capacity, and the synergistic effect of biochar and deep tillage is the best. These research results have important guiding significance for the rational construction of a protective tillage system model and the improvement of the utilization efficiency of snowmelt water resources in black soil areas. Full article

This research aims at systematically evaluating the properties of SMA-13 asphalt mixture reinforced by several fiber additives including flocculent lignin fiber (FLF), granular lignin fiber (GLF), chopped basalt fiber (CBF), and flocculent basalt fiber (FBF). Firstly, the thermal stability, moisture absorption, and oil absorption property of these fiber additives were analyzed. Secondly, the property of SMA-13 reinforced using four types of single fibers and two kinds of composite fibers (FLF + CBF and FLF + FBF) was comprehensively analyzed. Specifically, the high-temperature performance was evaluated using the uniaxial penetration test and the rutting test, the medium-temperature anticracking property was evaluated using the IDEAL-CT test, the low-temperature property was analyzed using the beam bending test, and the water stability was studied by the freeze–thaw splitting test. Thirdly, the dynamic mechanical response of different-fibers-modified SMA-13 was evaluated using the uniaxial compression dynamic modulus test. Finally, correlation analysis between the results of dynamic modulus and the high-, medium-, and low-temperature mechanical performance was carried out. The research results reveal that the stability of CBF and FBF under thermal action is better than that of GLF and FLF, and FBF shows the best thermal stability. The oil absorption property of FLF is better than that of GLF, followed by FBF and CBF. The comprehensive mechanical properties of CBF- and FBF-reinforced SMA-13 are better than those of FLF- and GLF-modified SMA-13. CBF can better reinforce the mechanical property of SMA-13 under low and medium temperature, while FBF can better reinforce the performance of SMA-13 at high temperature. FLF/CBF- and FLF/FBF-composite-modified SMA-13 show better high-temperature mechanical performance than that of the single-fiber-reinforced mixture, and FLF has some negative impact on the properties of FLF/FBF-composite-modified SMA-13 at low temperature. Fibers have no significant influence on the water stability of the mixtures. Meanwhile, the linear correlation between the mechanical performance of all the fiber-reinforced SMA-13 and the dynamic modulus result is good. Full article

Increasing penetration of distributed energy resources is manifesting as voltage regulation challenges in many LV networks. Appropriate regulation of supply voltage magnitude is essential to ensure efficacy and efficiency in the operation of electricity supply networks and consumer equipment. While the theoretical impacts of supply voltage magnitude on the performance of consumer equipment, which include additional energy consumption and decreased equipment lifespan as voltage magnitude increases, are relatively well known, this has not been translated into quantitative impacts. This paper applies the outcomes of previous impact of supply voltage magnitude studies by the authors, in conjunction with domestic load models, to develop algorithms to estimate the quantitative impacts of supply voltage magnitude on consumers. The paper then applies these algorithms to calculate quantitative economic impacts that can be associated with the magnitude of the supply voltage. The outcomes of this research suggest that the per-annum impact of supply voltage magnitude on consumer equipment loss of life is potentially an order of magnitude greater than the resultant increased energy consumption based on case studies using Australian data. Full article

In order to clearly determine the carbon emission distribution of regions, lines or nodes in the power grid, this paper applies cloud theory to the evaluation of the distribution of carbon emissions in the power grid. Based on the theory of carbon emission flow in the whole life cycle, five indicators that can reflect the spatial and temporal distribution of carbon emissions are constructed from the two dimensions of space and time. Cloud theory is used to establish the standard cloud of the carbon emission distribution level to quantify the randomness and fuzziness of the data to be evaluated. The bilateral constraint cloud theory and data-driven cloud transformation are combined to construct five comprehensive standard clouds of excellent, good, medium, poor and inferior, which are used as the evaluation interval of the evaluation index of carbon emission distribution. The reverse cloud is used to convert multiple sets of data into cloud droplets. Through the similarity measurement algorithm based on cloud model overlap, the comprehensive evaluation level of carbon emission distribution state in the time dimension is determined. Taking the IEEE 39 system as the research object, the spatial and temporal distribution of carbon emissions is evaluated, and the rationality and effectiveness of the proposed model are verified. Finally, the influence of the new energy penetration rate and power supply structure on the carbon emission distribution of the power grid is discussed by using cloud computing. Based on this, the targeted carbon reduction strategies for different types of nodes and the method of measuring the optimal new energy penetration rate are proposed and can provide a decision-making reference for optimizing the carbon emissions of the power grid. Full article

Photoresist polymers containing cycloaliphatic acrylic monomers have been synthesized for use in the microcircuits of semiconductors. Although cycloaliphatic acrylic monomers exhibit a high etch resistance and excellent thermal properties, their large size increases the distance between the main chains of the resulting polymers. This increased distance facilitates the penetration of a developer between the main chains, which leads to swelling and thus pattern collapse, distortion, and delamination, thereby complicating the fabrication of microcircuits. To solve this problem, various large developers were used in previous studies to reduce the swelling effect. However, these developers could not easily dissolve the unexposed regions of the resist. To overcome this issue, we designed photoresist polymers with smaller functional groups to decrease the degree of swelling. Specifically, ArF photoresist polymers were synthesized from monomers with various sizes of functional groups. We confirmed that the polymer synthesized using cyclohexyl methacrylate (CHMA), which had the smallest functional group, exhibited the shortest distance between the main chains. Consequently, this polymer showed the least swelling, with a swelling ratio of 109%. In contrast, the polymers synthesized using isobornyl acrylate (IBOA) and dicyclopentanyl methacrylate (TCDMA), which have large functional groups, exhibited greater distances between the main chains, resulting in swelling ratios of 114% and 112%, respectively. The polymer with a swelling ratio of 109% showed excellent patterning properties, while those with swelling ratios of 114% and 112% were delaminated by the developer. Our work introduces a novel approach to help reduce the swelling effect and achieve high-quality patterns in negative photoresists. Full article

The integration of ground-penetrating radar (GPR) with unmanned aerial vehicles (UAVs) enables efficient non-contact detection, performing exceptionally well in complex terrains and extreme environments. However, challenges in data processing and interpretation remain significant obstacles to fully utilizing this technology. To mitigate the effects of numerical dispersion, this paper develops a high-order finite-difference time-domain (FDTD(2,4)) three-dimensional code suitable for airborne GPR numerical simulations. The simulation results are compared with traditional FDTD methods, validating the accuracy of the proposed approach. Additionally, a Kirchhoff migration algorithm that considers the influence of the air layer is developed for airborne GPR. Different processing strategies are applied to flat and undulating terrain models, significantly improving the identification of shallowly buried targets. Particularly under undulating terrain conditions, the energy ratio method is introduced, effectively suppressing the interference of surface reflections caused by terrain variations. This innovative approach offers a new technical pathway for efficient GPR data processing in complex terrains. The study provides new insights and methods for the practical application of airborne GPR. Full article

Multi-component ultra-high-temperature ceramics (MC-UHTCs) are promising for high-temperature applications due to exceptional thermo-mechanical properties, yet their wear characteristics remain unexplored. Herein, the wear behavior of binary (Ta, Nb)C, ternary (Ta, Nb, Hf)C, and quaternary (Ta, Nb, Hf, Ti)C UHTCs synthesized via spark plasma sintering (SPS) is investigated. Gradual addition of equimolar UHTC components improves the wear resistance of MC-UHTCs, respectively, by ~29% in ternary UHTCs and ~49% in quaternary UHTCs when compared to binary UHTCs. Similarly, the penetration depth decreased from 115.14 mm in binary UHTCs to 73.48 mm in ternary UHTCs and 44.41 mm in quaternary UHTCs. This has been attributed to the complete solid solutioning, near-full densification and higher hardness (~up to 30%) in quaternary UHTCs. Analysis of the worn-out surface suggests pull-out, radial, and edge micro-cracking and delamination as the dominant wear mechanisms in binary and ternary UHTCs. However, grain deformation and minor delamination are the dominant wear mechanisms in quaternary UHTCs. This study underscores the potential of MC-UHTCs for tribological applications where material experiences removal and inelastic deformation under high mechanical loading. Full article