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16 pages, 6044 KiB  
Article
The Modifying Effects of Lifestyle Behaviors on the Association Between Drinking Water Micronutrients and BMI Status Among Children and Adolescents Aged 7~17: A Population-Based Regional Surveillance in 2022
by Manman Chen, Xiuhong Zhang, Jianuo Jiang, Tian Yang, Li Chen, Jieyu Liu, Xinli Song, Yi Zhang, Ruolin Wang, Yang Qin, Ziqi Dong, Wen Yuan, Tongjun Guo, Zhiying Song, Jun Ma, Yanhui Dong, Yi Song and Yuhan Qin
Nutrients 2024, 16(22), 3931; https://doi.org/10.3390/nu16223931 (registering DOI) - 18 Nov 2024
Abstract
Background: This study aims to investigate the potential modifying effects of lifestyle behavior on the association between drinking water micronutrients and body mass index (BMI) in a large population of children and adolescents. Methods: Data of the present analysis came from a comprehensive [...] Read more.
Background: This study aims to investigate the potential modifying effects of lifestyle behavior on the association between drinking water micronutrients and body mass index (BMI) in a large population of children and adolescents. Methods: Data of the present analysis came from a comprehensive regional large-scale surveillance study in 2022, involving 172,880 children and adolescents (50.71% boys vs. 49.29% girls) aged seven to seventeen. A restricted cubic spline (RCS) analysis was utilized to examine the exposure-response association of regular drinking water indices (including fluoride, nitrate nitrogen, pH, chloride, sulfates, and total dissolved solids (TDS), total hardness (TH), and chemical oxygen demand (COD)) with BMI. Generalized linear model and logistic regression were conducted to relate BMI and quartiles of drinking water micronutrients. Results: Our findings reveal a nonlinear association between nitrate nitrogen (P for nonlinear < 0.001) and pH (P for nonlinear < 0.001) with BMI. High TH and COD levels significantly increase BMI. Notably, fluoride and chloride were associated with BMI Z-scores but not with overweight and obesity (OB). The BMI Z-score showed a more pronounced association with low and high pH levels in girls. For urban participants, increased TH levels were associated with a higher risk of OB. This study also found that adopting healthy lifestyles could mitigate the negative effects of fluoride, chloride, and sulfate on BMI Z-scores. Conclusions: This large surveillance study provides new insights into the complex interplay between drinking water micronutrients and BMI in children and adolescents. The association of various drinking water parameters on BMI varies, necessitating ongoing focus on their effects, particularly among girls and urban individuals. Healthy lifestyle behavior could mitigate the effects of fluoride, chloride, and sulfate on BMI Z-score. Full article
(This article belongs to the Section Pediatric Nutrition)
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16 pages, 6770 KiB  
Article
The Inactivation of Microscopic Fungi in Bakery Products Using Hurdle Technology—A Case Study
by Anna Diowksz, Przemysław Kopeć and Anna Koziróg
Appl. Sci. 2024, 14(22), 10648; https://doi.org/10.3390/app142210648 (registering DOI) - 18 Nov 2024
Abstract
The issue of the microbiological spoilage of bakery products with an extended shelf life declared by the producer was the reason for searching for an effective solution. The aim of the investigation was to find the sources of infection, identify microorganisms causing product [...] Read more.
The issue of the microbiological spoilage of bakery products with an extended shelf life declared by the producer was the reason for searching for an effective solution. The aim of the investigation was to find the sources of infection, identify microorganisms causing product spoilage, and propose ways to eliminate the problem without the use of chemical preservatives in the product. It was found that the dominant contaminating microorganisms are yeasts of the genus Hyphopichia sp., Saccharomyces sp., and Candida spp., as well as molds—Aspergillus spp. and Penicillium spp. The microbiological quality of the production environment was assessed, and as a remedial action, a disinfection process was carried out. The influence of gas composition in MAP (modified atmosphere packaging) and the use of ethanol during packaging on the incidence of yeast or mold occurrence was checked. The effectiveness of using sourdough was also tested. The best results were achieved by using sourdough obtained with selected starter cultures and using a gas mixture for packaging in the proportion of 70% carbon dioxide and 30% nitrogen, without the addition of ethanol. These conditions ensured the expected shelf life of bakery products while maintaining their quality. Full article
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19 pages, 9359 KiB  
Article
Transforming Irrigated Agriculture in Semi-Arid and Dry Subhumid Mediterranean Conditions: A Case of Protected Cucumber Cultivation
by Talal Darwish, Amin Shaban, Ghaleb Faour, Ihab Jomaa, Peter Moubarak and Roula Khadra
Sustainability 2024, 16(22), 10050; https://doi.org/10.3390/su162210050 (registering DOI) - 18 Nov 2024
Abstract
Pressure from population growth and climate change stress the limited water resources in the Mediterranean region and threaten food security and social stability. Enhancing food production requires the transformation of irrigation systems and enhancement of local capacity for sustainable water and soil management [...] Read more.
Pressure from population growth and climate change stress the limited water resources in the Mediterranean region and threaten food security and social stability. Enhancing food production requires the transformation of irrigation systems and enhancement of local capacity for sustainable water and soil management in irrigated agriculture. The aim of this work is the conversion of traditional irrigation practices, by introducing the practice of optimal irrigation scheduling based on local ET estimation and soil moisture monitoring, and the use of continuous feeding by fertigation to enhance both water and nutrient use efficiency. For this, two trials were established between August and November 2023 in two different pedoclimatic zones (Serein and Sultan Yacoub) of the inner Bekaa Plain of Lebanon, characterized by semi-arid and dry subhumid conditions and different soil types. Greenhouse cucumber was tested to compare the prevailing traditional farmers’ practices with the advanced, technology-based, methods of water management. Results showed a significantly higher amount of water applied by the farmers to the protected cucumber, with a potential for average saving of 105 mm of water applied in each season by improved practices. Water input in the traditional practices revealed potential stress to plants. With more than 20% increase in cucumber yield by the transformed practices, a general trend was observed in the fertilization approach and amounts, resulting in lower nutrient recovery in the farmer’s plots. The science-based practices of water and nutrient management showed higher application and agronomic water use efficiency of full fertigation, exceeding 60%, associated with double and triple higher nitrogen use efficiency, compared to those results obtained by the traditional water and fertilizer application methods. The monitored factors can contribute to severe economic and environmental consequences from nutrient buildup or leaching in the soil–groundwater system in the Mediterranean region. Full article
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15 pages, 4869 KiB  
Article
Biodiversity and Abundance of Angiosperms and Environmental Resilience in the Tidal Range of Yuanjiang Dry–Hot Valley, Southwestern China
by Fengchun Yang, Qiong He, Huaping Huang, Yanmei Cui, Jianyong Gou, Chaya Sarathchandra, Kritana Prueksakorn, Kiyota Hashimoto and Li Liu
Diversity 2024, 16(11), 703; https://doi.org/10.3390/d16110703 (registering DOI) - 18 Nov 2024
Abstract
Yuanjiang dry–hot valley is located in the southwest of mainland China. It is a sparsely vegetated area with a fragile arid ecosystem. Although the valley previously had forest cover, it has become a tropical montane savannah in recent decades. Mechanisms controlling plant species [...] Read more.
Yuanjiang dry–hot valley is located in the southwest of mainland China. It is a sparsely vegetated area with a fragile arid ecosystem. Although the valley previously had forest cover, it has become a tropical montane savannah in recent decades. Mechanisms controlling plant species distribution in such dry–hot valleys are unclear. Clarifying this will be beneficial to sustainable ecosystem management in dry–hot valleys. This study explored the relationship between diversity patterns of plant species and their environments in the lowland of this dry–hot valley. To achieve this, transects and plots were arranged along the river channel. Alpha and beta diversity indices were calculated to quantify biodiversity changes between species and environments. Estimated species, rarity, and abundance indices were also utilized to examine the correlation among species, their population size, and their environment: Species_estimated (expected number of species in t pooled plots), Singletons (the number of species with only one individual in t pooled plots), Uniques (the number of species living in one plot in t pooled plots), ACE (species richness estimator with coverage-based abundance), ICE (species richness estimator with coverage-based incidence), and Chao2 (species richness estimator extrapolated from Singletons). Fifty years of meteorological records, including temperature and precipitation, were utilized as climate variables. The results indicated the following findings: (1) alpha diversity was higher closer to the river, whereas the beta diversity was higher towards the lower sections of the river (Bray–Curtis < 0.5), but this trend was reversed in the perpendicular transects; (2) total phosphorous (TP) and total potassium (TK) were higher on flatter ground, tending to be associated with raised nitrogen (TN) and organic matter (OM); (3) soil nutrients were higher towards the lower sections of the river, corresponding to an increased number of species; (4) water supply determined plant distribution, with soil condition determining water retention; (5) the estimated species and their rarity and abundance indices were associated with proximity to the river, indicating heterogeneity of habitats and soil condition; and (6) fern species could be used as indicators representing the xeric environment of Yuanjiang dry–hot valley. Plant cover was reduced at low altitudes, with high temperatures and a low water supply. These results draw attention to the need for specific policy formation to protect the microhabitats and manage the environment of the Yuanjiang valley. Full article
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20 pages, 9058 KiB  
Article
Response of Yields, Soil Physiochemical Characteristics, and the Rhizosphere Microbiome to the Occurrence of Root Rot Caused by Fusarium solani in Ligusticum chuanxiong Hort.
by Xiaofang Sun, Yong Liu, Lian He, Zaiyin Kuang, Shundong Dai, Lixia Hua, Qiuping Jiang, Taiyang Wei, Pengsheng Ye and Hualan Zeng
Microorganisms 2024, 12(11), 2350; https://doi.org/10.3390/microorganisms12112350 (registering DOI) - 18 Nov 2024
Abstract
Ligusticum chuanxiong Hort. is considered an important medicinal herb with extremely high economic value and medicinal value due to its various effects, including anti-oxidation, sedative action, hepatoprotection, and invigorating blood circulation. However, L. chuanxiong cultivation is hampered by various plant diseases, especially the [...] Read more.
Ligusticum chuanxiong Hort. is considered an important medicinal herb with extremely high economic value and medicinal value due to its various effects, including anti-oxidation, sedative action, hepatoprotection, and invigorating blood circulation. However, L. chuanxiong cultivation is hampered by various plant diseases, especially the root rot caused by Fusarium solani, hindering the sustainable development of the L. chuanxiong industry. The occurrence of soil-borne diseases is closely linked to imbalances in the microbial community structure. Here, we studied the yields, rhizosphere microbiota, and soil physiochemical characteristics of healthy and diseased L. chuanxiong plants affected by root rot with high-throughput sequencing and microbial network analysis, aiming to explore the relationships between soil environmental factors, microbiomes, and plant health of L. chuanxiong. According to the results, L. chuanxiong root rot significantly decreased the yields, altered microbial community diversity and composition, enriched more pathogenic fungi, recruited some beneficial bacteria, and reduced microbial interaction network stability. The Mantel test showed that soil organic matter and pH were the major environmental factors modulating plant microbiome assembly. The root rot severity was significantly affected by soil physiochemical properties, including organic matter, cation exchange capacity, available nitrogen, phosphorus, potassium, and pH. Furthermore, two differential microbes that have great potential in the biocontrol of L. chuanxiong root rot were dug out in the obtained results, which were the genera Trichoderma and Bacillus. This study provided a theoretical basis for further studies revealing the microecological mechanism of L. chuanxiong root rot and the ecological prevention and control of L. chuanxiong root rot from a microbial ecology perspective. Full article
(This article belongs to the Section Plant Microbe Interactions)
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21 pages, 6374 KiB  
Article
Habitat Assessment of Bocachico (Prochilodus magdalenae) in Ciénaga de Betancí, Colombia, Using a Habitat Suitability Index Model
by Karol Vellojín-Muñoz, José Lorduy-González, Franklin Torres-Bejarano, Gabriel Campo-Daza and Ana Carolina Torregroza-Espinosa
Water 2024, 16(22), 3312; https://doi.org/10.3390/w16223312 (registering DOI) - 18 Nov 2024
Abstract
This study evaluates the habitat of the Bocachico fish (Prochilodus magdalenae) in the Ciénaga de Betancí, Colombia, using a habitat suitability index (HSI) model. Wetlands like the Ciénaga de Betancí are under significant pressure from anthropogenic activities, affecting biodiversity and ecosystem [...] Read more.
This study evaluates the habitat of the Bocachico fish (Prochilodus magdalenae) in the Ciénaga de Betancí, Colombia, using a habitat suitability index (HSI) model. Wetlands like the Ciénaga de Betancí are under significant pressure from anthropogenic activities, affecting biodiversity and ecosystem health. The Bocachico, a species of immense cultural and economic importance, faces habitat degradation and fragmentation. Using hydrodynamic and water quality data, a numerical model (EFDC+ Explorer 11.5), and field data collected from multiple sampling campaigns, we assessed habitat suitability based on five key parameters: water temperature, dissolved oxygen, ammonia nitrogen, velocity, and depth. The model results indicated that environmental conditions in the wetland remained relatively stable during the dry season, with an average HSI score of 0.67, where 9% of the wetland area displayed acceptable conditions, and the remaining 91% displayed medium conditions. The wet season, on the other hand, had an average HSI score of 0.64, with 7.2% of the area in the acceptable suitability range, and the remaining 92.8% in the medium category. Variations in HSI were primarily driven by ammonia nitrogen levels, water velocity, and depth. Despite limited fluctuations in the HSI, areas of low suitability were identified, particularly in regions impacted by human activities. These findings have practical implications for conservation strategies, providing valuable insights for the sustainable management and conservation of the Ciénaga de Betancí, informing strategies for improving habitat conditions for the Bocachico, and supporting wetland restoration efforts. Full article
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12 pages, 1823 KiB  
Article
The Study of Nitrogen and Phosphorus Removal Efficiency in Urbanized River Systems Using Artificial Wetland Systems with Different Substrates
by Ran Chi, Zhongqing Wei, Longcong Gong, Guosheng Zhang, Duo Wen and Weiying Li
Water 2024, 16(22), 3309; https://doi.org/10.3390/w16223309 (registering DOI) - 18 Nov 2024
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Abstract
This study evaluated the effectiveness of five commercial substrates (zeolite, volcanic rock, gravel, magic rack, and ceramic pellets) in removing nitrogen (N) and phosphorus (P) from urban river systems using constructed wetlands. By employing X-ray CT and NGS technologies, we analyzed the physical [...] Read more.
This study evaluated the effectiveness of five commercial substrates (zeolite, volcanic rock, gravel, magic rack, and ceramic pellets) in removing nitrogen (N) and phosphorus (P) from urban river systems using constructed wetlands. By employing X-ray CT and NGS technologies, we analyzed the physical structure of the substrates and the microbial communities they harbor. The results indicated that volcanic rock and ceramic pellets, due to their high porosity and specific surface area, performed exceptionally well in nitrogen and phosphorus removal. Specifically, the microbial systems with these two substrates achieved ammonia nitrogen removal rates of 89.86% and 88.45%, total nitrogen removal rates of 78.78% and 74.97%, and total phosphorus removal rates of 92.67% and 80.82%, respectively, within a 7-day period. Furthermore, the microbial communities on volcanic rock and ceramic pellets were more diverse, which correlated with their high pollutant removal efficiency. The study further elucidated the synergistic role of substrate characteristics and microbial community structure and function in nitrogen and phosphorus removal, enhancing the understanding of the purification mechanisms in constructed wetlands. These findings provide a scientific basis for the ecological restoration of urban rivers and are significant for improving the quality of urban water environments. Full article
(This article belongs to the Section Water Quality and Contamination)
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16 pages, 1395 KiB  
Article
Effects of Rubber Plantation Restoration in National Parks on Plant Diversity and Soil Chemical Properties
by Chunyan Du, Donghai Li, Weifeng Wang, Xiaobo Yang, Zhixiang Wu, Chuan Yang, Yingying Zhang, Qingmao Fu and Dongling Qi
Diversity 2024, 16(11), 701; https://doi.org/10.3390/d16110701 (registering DOI) - 18 Nov 2024
Viewed by 106
Abstract
Plantations left for natural succession play a significant role in Tropical Rainforest National Parks. Studying the succession and restoration of plantations is crucial for achieving a park’s authenticity and integrity, as well as for maximizing its ecological functions. However, the changes in vegetation [...] Read more.
Plantations left for natural succession play a significant role in Tropical Rainforest National Parks. Studying the succession and restoration of plantations is crucial for achieving a park’s authenticity and integrity, as well as for maximizing its ecological functions. However, the changes in vegetation and soil properties during the natural succession of these decommissioned plantations remain unclear. In this study, we examined rubber [(Hevea brasiliensis (Willd. Ex A. Juss.) Muell. Arg] plantations in the Yinggeling area of the National Park of Hainan Tropical Rainforest. We used community surveys, field sampling, and soil property analyses to investigate the species richness, diversity, and species composition of the aboveground plant communities during three succession periods of rubber plantations left for natural succession, including 0 years (ZY), 3 years (TY), and 7 years (SY). The soil pH, total organic carbon, total nitrogen, total phosphorus, available phosphorus, nitrate nitrogen, ammonium nitrogen, and total potassium contents in the three succession periods were analyzed. These results showed that there were 92 species of understory plants in the decommissioned rubber plantations, belonging to 72 genera in 39 families. The highest number of understory plant species was found in the plantations with 3 years of natural succession, totaling 66 species from 49 genera in 29 families. The number of families, genera, and species followed the pattern TY > SY > ZY. The Margalef richness index (F), Simpson index (D), and Shannon–Wiener index (H) of understory plants in the 0-year succession plantations were significantly lower than those in the 3-year and 7-year succession plantations. However, there was no significant difference in the Pielou (EH) index among the succession gradients. The soil pH, nitrate nitrogen (NO3--N), and available phosphorus (AP) in the 0-year succession plantations were significantly higher than those in the 3-year and 7-year succession plantations. There were no significant differences in soil total nitrogen (TN), total phosphorus (TP), total organic carbon (TOC), and ammonium nitrogen (NH4+-N) across the three succession gradients. The soil total potassium (TK) in the 3-year succession plantations was significantly higher than that in the 0-year and 7-year succession plantations. Soil available phosphorus and total phosphorus (TP) were positively correlated with the Margalef index, Simpson index, Shannon–Wiener index, and Pielou index. The recovery rate of understory vegetation in decommissioned rubber plantations was faster than that of the soil. This indicates that the construction of the National Park of Hainan Tropical Rainforest has significantly promoted the recovery of the number of plant species and plant species diversity that have been left from rubber plantation operations. These findings not only deepen our understanding of soil property changes during the vegetation succession of artificial forests, particularly rubber plantations, but they also hold significant implications for guiding tropical forest management and sustainable development. Full article
(This article belongs to the Special Issue Biodiversity Conservation Planning and Assessment)
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20 pages, 4069 KiB  
Article
Microalgae-Assisted Treatment of Wastewater Originating from Varied Sources, Particularly in the Context of Heavy Metals and Antibiotic-Resistant Bacteria
by Rabia Rehman, Syeda Fazoon Kazmi, Muhammad Irshad, Muhammad Bilal, Farhan Hafeez, Jamil Ahmed, Shabina Shaheedi and Rashid Nazir
Water 2024, 16(22), 3305; https://doi.org/10.3390/w16223305 (registering DOI) - 18 Nov 2024
Viewed by 200
Abstract
The increasing prevalence of heavy metals and antibiotic-resistant bacteria in wastewater (WW) raises serious environmental and public health concerns. This study investigates the efficiency of the microalgal strain Chlorella vulgaris EV-465 in treating wastewater and evaluates the antibiotic resistance profile of bacterial strains [...] Read more.
The increasing prevalence of heavy metals and antibiotic-resistant bacteria in wastewater (WW) raises serious environmental and public health concerns. This study investigates the efficiency of the microalgal strain Chlorella vulgaris EV-465 in treating wastewater and evaluates the antibiotic resistance profile of bacterial strains obtained from WW samples. Chlorella vulgaris EV-465 was used to treat four types of wastewater—domestic, municipal, hospital, and industrial wastewater—through 21 days of incubation. The findings demonstrated pH stabilization and significant decreases in nutrients (total nitrogen—TN, total phosphorus—TP), biological oxygen demand (BOD), chemical oxygen demand (COD), heavy metal (HM) concentrations, and bacterial count. Copper (Cu) showed the highest reduction, decreasing by 80% in industrial wastewater within 14 days, while lead (Pb) proved more resistant to removal, with only a 50% decrease by day 21. Additionally, the algae decreased bacterial counts, lowering colony-forming units (Log CFU/mL) from 9.04 to 4.65 in municipal wastewater over the 21-day period. Antibiotic susceptibility tests for isolated bacterial strains revealed high levels of resistance, with seven out of nine bacterial strains exhibiting multidrug resistance. Notably, Enterococcus faecium (PBI08), Acinetobacter baumannii (YBH19), and Pseudomonas aeruginosa (NBH16) displayed resistance to all nine antibiotics tested. Among the tested antibiotics, Ciprofloxacin showed the highest efficacy, with 66% susceptibility of tested bacterial strains. Cluster and phylogenetic analyses showed that the majority of the isolated bacterial strains belonged to the genera Pseudomonas and Escherichia, highlighting their genetic diversity and varied resistance mechanisms. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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15 pages, 11526 KiB  
Article
Visualization and Simulation of Foam-Assisted Gas Drive Mechanism in Surface Karst Slit-Hole Type Reservoirs
by Zhengbang Chen, Lei Wang, Juan Luo and Jianpeng Zhang
Processes 2024, 12(11), 2579; https://doi.org/10.3390/pr12112579 (registering DOI) - 17 Nov 2024
Viewed by 380
Abstract
Nitrogen injection technology has become an important production technology after water injection development in the karst fracture-vuggy reservoir in Tahe Oilfield. However, due to the influence of reservoir heterogeneity and the high mobility of gas fluid, nitrogen easily forms a dominant channel and [...] Read more.
Nitrogen injection technology has become an important production technology after water injection development in the karst fracture-vuggy reservoir in Tahe Oilfield. However, due to the influence of reservoir heterogeneity and the high mobility of gas fluid, nitrogen easily forms a dominant channel and gas channeling occurs, and the recovery effect time is short. Based on this, a visual surface karst model is designed and created to study nitrogen foam-assisted gas drive. The results show that after gas channeling occurs in the dominant channel of nitrogen flooding, foam injection-assisted gas flooding can improve oil recovery. In the longitudinal direction, foam-assisted gas drive mainly displaces the remaining oil because of gravity differentiation and the reduction of oil–water interfacial tension. In the horizontal direction, foam-assisted gas drive is mainly used to block the large pore cracks and dominant channels, promote the gas to turn into large tortuous and small cracks, and expand the swept efficiency of the gas. After forming the dominant channel, injecting 0.3 pv salt-sensitive foam with a gas–liquid ratio of 2:1 in the middle of the gas channel can improve the recovery rate of the model from 4% to about 25%, and the recovery rate can be increased by about 20%, which improves the effect of gas flushing and improves the development efficiency of the oil field at the same time. Full article
(This article belongs to the Section Energy Systems)
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19 pages, 14171 KiB  
Article
Mechanical, Tribological, and Corrosion Resistance Properties of (TiAlxCrNbY)Ny High-Entropy Coatings Synthesized Through Hybrid Reactive Magnetron Sputtering
by Nicolae C. Zoita, Mihaela Dinu, Anca C. Parau, Iulian Pana and Adrian E. Kiss
Crystals 2024, 14(11), 993; https://doi.org/10.3390/cryst14110993 (registering DOI) - 17 Nov 2024
Viewed by 270
Abstract
This study investigates the effects of aluminum and nitrogen content on the microstructure, mechanical properties, and tribological performance of high-entropy coatings based on (TiCrAlxNbY)Ny systems. Using a hybrid magnetron sputtering technique, both metallic and nitride coatings were synthesized and evaluated. [...] Read more.
This study investigates the effects of aluminum and nitrogen content on the microstructure, mechanical properties, and tribological performance of high-entropy coatings based on (TiCrAlxNbY)Ny systems. Using a hybrid magnetron sputtering technique, both metallic and nitride coatings were synthesized and evaluated. Increasing the aluminum concentration led to a transition from a crystalline to a nanocrystalline and nearly amorphous (NC/A) structure, with the TiAl0.5CrNbY sample (11.8% Al) exhibiting the best balance of hardness (6.8 GPa), elastic modulus (87.1 GPa), and coefficient of friction (0.64). The addition of nitrogen further enhanced these properties, transitioning the coatings to a denser fine-grained FCC structure. The HN2 sample (45.8% nitrogen) displayed the highest hardness (21.8 GPa) but increased brittleness, while the HN1 sample (32.9% nitrogen) provided an optimal balance of hardness (14.3 GPa), elastic modulus (127.5 GPa), coefficient of friction (0.60), and wear resistance (21.2 × 10−6 mm3/Nm). Electrochemical impedance spectroscopy revealed improved corrosion resistance for the HN1 sample due to its dense microstructure. Overall, the (TiAl0.5CrNbY)N0.5 coating achieved the best performance for friction applications, such as break and clutch systems, requiring high coefficients of friction, high wear resistance, and durability. Full article
(This article belongs to the Special Issue Advances of High Entropy Alloys)
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16 pages, 3427 KiB  
Systematic Review
Slow-Release Fertilisers Control N Losses but Negatively Impact on Agronomic Performances of Pasture: Evidence from a Meta-Analysis
by Gunaratnam Abhiram
Nitrogen 2024, 5(4), 1058-1073; https://doi.org/10.3390/nitrogen5040068 (registering DOI) - 17 Nov 2024
Viewed by 276
Abstract
High nitrogen (N) losses and low nitrogen utilisation efficiency (NUE) of conventional-nitrogen fertilisers (CNFs) are due to a mismatch between N-delivery and plant demand; thus, slow-release N fertilisers (SRNFs) are designed to improve the match. A quantitative synthesis is lacking to provide the [...] Read more.
High nitrogen (N) losses and low nitrogen utilisation efficiency (NUE) of conventional-nitrogen fertilisers (CNFs) are due to a mismatch between N-delivery and plant demand; thus, slow-release N fertilisers (SRNFs) are designed to improve the match. A quantitative synthesis is lacking to provide the overall assessment of SRNFs on pasture. This meta-analysis analyses application rate and type of SRNFs on N losses and agronomic performances with 65 data points from 14 studies in seven countries. Standardized mean difference of SRNFs for nitrate leaching losses and N2O emission were −0.87 and −0.69, respectively, indicating their effectiveness in controlling losses. Undesirably, SRNFs had a more negative impact on dry matter (DM) yield and NUE than CNFs. Subgroup analysis showed that SRNF type and application rate had an impact on all tested parameters. The biodegradable coating-type of SRNF outperformed other types in controlling N losses and improving agronomic performances. High application rates (>100 kg N ha−1) of SRNFs are more effective in controlling N losses. In conclusion, SRNFs are more conducive to controlling N losses, but they showed a negative impact on yield and NUE in pasture. Further studies are recommended to assess the efficacy of SRNFs developed using advanced technologies to understand their impact on pastoral agriculture. Full article
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19 pages, 10067 KiB  
Article
Slow-Release Nitrogen Fertilizer Promotes the Bacterial Diversity to Drive Soil Multifunctionality
by Tiantian Meng, Jingjing Shi, Xiangqian Zhang, Guolong Ge, Yuchen Cheng, Meiren Rong, Liyu Chen, Xiaoyu Zhao, Xiaoxiang Wang and Zhanyuan Lu
Agronomy 2024, 14(11), 2712; https://doi.org/10.3390/agronomy14112712 (registering DOI) - 17 Nov 2024
Viewed by 264
Abstract
The application of slow-release nitrogen fertilizer not only economizes labor input, but also decreases the frequency of use of mechanical intakes, with significant implications in advancing modern intensive agricultural production. Whether slow-release nitrogen fertilizer application can influence the association between microbial diversity and [...] Read more.
The application of slow-release nitrogen fertilizer not only economizes labor input, but also decreases the frequency of use of mechanical intakes, with significant implications in advancing modern intensive agricultural production. Whether slow-release nitrogen fertilizer application can influence the association between microbial diversity and soil multifunctionality remains controversial. This study analyzed the spatial variances of soil environmental factors, soil multifunctionality, and their correlations with bacterial and fungal communities under five nitrogen application rates. The key factors influencing the dominant microbial species and community structures at different spatial locations were determined by the slow-release nitrogen fertilizer application rate, and the driving factors and dominant species of soil multifunctionality were identified. In contrast to the control group, moderate slow-release nitrogen fertilizer application enhanced soil multifunctionality and ameliorated the resilience of microbial diversity loss at diverse spatial locations resulting from irrational nitrogen fertilizer application. The resilience of the fungal community to disturbances caused by fertilization was lower than that of the bacterial community. Bacterial diversity exhibited a significant correlation with soil multifunctionality, and the soil multifunctionality intensity under 240 kg ha−1 treatment increased by 159.01% compared to the CK. The main dominant bacterial communities and the dominant fungal community Ascomycota affected soil multifunctionality through slow-release nitrogen fertilizer application. Structural equation modeling and random forest analysis demonstrated that bacterial community diversity, particularly in bulk soil and the rhizosphere, community composition, and soil nitrogen form are the primary driving factors of soil multifunctionality. Results indicated that the microbial niche alterations induced by slow-release nitrogen fertilizer application positively affect soil multifunctionality. Full article
(This article belongs to the Section Soil and Plant Nutrition)
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13 pages, 3469 KiB  
Article
Design of Composite N-Doped Carbon Nanofiber/TiO2/Diatomite Separator for Lithium–Sulfur Batteries
by Wenjie Xiao, Xiaoyu Wu, Yang Shu, Yitao Zha and Sainan Liu
Materials 2024, 17(22), 5615; https://doi.org/10.3390/ma17225615 (registering DOI) - 17 Nov 2024
Viewed by 264
Abstract
Lithium–sulfur batteries (LSBs) exhibit high theoretical specific capacities, abundant resource reserves, and low costs, making them promising candidates for next-generation lithium-ion batteries (LIBs). However, significant challenges, such as the shuttle effect and volume expansion, hinder their practical applications. To address these issues, this [...] Read more.
Lithium–sulfur batteries (LSBs) exhibit high theoretical specific capacities, abundant resource reserves, and low costs, making them promising candidates for next-generation lithium-ion batteries (LIBs). However, significant challenges, such as the shuttle effect and volume expansion, hinder their practical applications. To address these issues, this study introduces a unique intermediate layer comprising N-doped carbon nanofiber/TiO2/diatomite (NCNF/TiO2/DE) from the perspective of membrane modification. The intermediate layer comprises nitrogen-doped titanium dioxide/carbon nanofiber (NCNF/TiO2) materials, with diatomite filling the fiber gaps. This forms a three-dimensional (3D) conductive network that provides ample space for sulfur volume expansion and numerous adsorption active sites, thereby accelerating electrolyte penetration and lithium-ion diffusion. These features collectively contribute to the outstanding electrochemical performance of the battery. At 0.1 C, the NCNF/TiO2/DE-800-coated separator battery achieved a first-cycle discharge specific capacity of 1311.1 mAh g−1, significantly higher than the uncoated lithium–sulfur battery (919.6 mAh g−1). Under varying current densities, the NCNF/TiO2/DE-800 material demonstrates good electrochemical reversibility and exhibits high lithium-ion diffusion rates and low charge-transfer resistance. Therefore, this study provides an advanced intermediate layer material that enhances the electrochemical performance of lithium–sulfur batteries. Full article
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15 pages, 2396 KiB  
Article
Isolation and Characterization of Biosurfactant-Producing Bacteria for Enhancing Oil Recovery
by Meiyu Jiang, Hongyi Wang, Jiahui Liu, Xuan Hou, Yuanyuan Zhang, Xiaolin Liu, Shiping Wei and Qingfeng Cui
Processes 2024, 12(11), 2575; https://doi.org/10.3390/pr12112575 (registering DOI) - 17 Nov 2024
Viewed by 239
Abstract
Biosurfactants produced by bacteria possess remarkable emulsification properties for crude oil, significantly enhancing oil mobility and recovery rates. This study aimed to isolate and screen biosurfactant-producing bacteria for oil enhancing recovery. A total of 93 bacterial strains were isolated from marine sediments, with [...] Read more.
Biosurfactants produced by bacteria possess remarkable emulsification properties for crude oil, significantly enhancing oil mobility and recovery rates. This study aimed to isolate and screen biosurfactant-producing bacteria for oil enhancing recovery. A total of 93 bacterial strains were isolated from marine sediments, with three high-yield biosurfactant-producing strains identified: Pseudomonas aeruginosa N33, Bacillus paralicheniformis Nian2, and Stenotrophomonas nematodicola T10. The fermentation conditions, such as pH, carbon source, nitrogen source, and C/N ratio, were optimized to maximize the yield and activity of biosurfactants. Further evaluations were performed to assess the stability of the bio-surfactant activity and its emulsification properties. The results indicated that all three strains produced biosurfactants that retained their oil displacement activity in the presence of Na+ and Mg2+, but showed a significant reduction in their activities in the presence of Ca2+. The biosurfactants maintained their original activity after treatment at 120 °C for 3 h. Additionally, the biosurfactants produced by all three strains demonstrated excellent oil emulsification capabilities. Static oil-washing and dynamic displacement experiments revealed static oil recovery rates of 28.1%, 23.4%, and 7.1%, respectively, for N33, Nian2, and T10, and dynamic oil displacement recovery rates of 95.0%, 74.1%, and 69.0%, respectively. This research provides valuable microbial resources for enhancing oil recovery via microorganisms and lays a foundation for practical application. Full article
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