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19 pages, 2595 KiB  
Article
Ancient Text Translation Model Optimized with GujiBERT and Entropy-SkipBERT
by Fuxing Yu, Rui Han, Yanchao Zhang and Yang Han
Electronics 2024, 13(22), 4492; https://doi.org/10.3390/electronics13224492 - 15 Nov 2024
Viewed by 258
Abstract
To cope with the challenges posed by the complex linguistic structure and lexical polysemy in ancient texts, this study proposes a two-stage translation model. First, we combine GujiBERT, GCN, and LSTM to categorize ancient texts into historical and non-historical categories. This categorization lays [...] Read more.
To cope with the challenges posed by the complex linguistic structure and lexical polysemy in ancient texts, this study proposes a two-stage translation model. First, we combine GujiBERT, GCN, and LSTM to categorize ancient texts into historical and non-historical categories. This categorization lays the foundation for the subsequent translation task. To improve the efficiency of word vector generation and reduce the limitations of the traditional Word2Vec model, we integrated the entropy weight method in the hopping lattice training process and spliced the word vectors with GujiBERT. This improved method improves the efficiency of word vector generation and enhances the model’s ability to accurately represent lexical polysemy and grammatical structure in ancient documents through dependency weighting. In training the translation model, we used a different dataset for each text category, significantly improving the translation accuracy. Experimental results show that our categorization model improves the accuracy by 5% compared to GujiBERT. In contrast, the Entropy-SkipBERT improves the BLEU scores by 0.7 and 0.4 on historical and non-historical datasets. Ultimately, the proposed two-stage model improves the BLEU scores by 2.7 over the baseline model. Full article
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17 pages, 3991 KiB  
Article
Intelligent Wireless Charging Path Optimization for Critical Nodes in Internet of Things-Integrated Renewable Sensor Networks
by Nelofar Aslam, Hongyu Wang, Muhammad Farhan Aslam, Muhammad Aamir and Muhammad Usman Hadi
Sensors 2024, 24(22), 7294; https://doi.org/10.3390/s24227294 - 15 Nov 2024
Viewed by 471
Abstract
Wireless sensor networks (WSNs) play a crucial role in the Internet of Things (IoT) for ubiquitous data acquisition and tracking. However, the limited battery life of sensor nodes poses significant challenges to the long-term scalability and sustainability of these networks. Wireless power transfer [...] Read more.
Wireless sensor networks (WSNs) play a crucial role in the Internet of Things (IoT) for ubiquitous data acquisition and tracking. However, the limited battery life of sensor nodes poses significant challenges to the long-term scalability and sustainability of these networks. Wireless power transfer technology offers a promising solution by enabling the recharging of energy-depleted nodes through a wireless portable charging device (WPCD). While this approach can extend node lifespan, it also introduces the challenge of bottleneck nodes—nodes whose remaining energy falls below a critical value of the threshold. The paper addresses this issue by formulating an optimization problem that aims to identify the optimal traveling path for the WPCD based on ant colony optimization (WPCD-ACO), with a focus on minimizing energy consumption and enhancing network stability. To achieve it, we propose an objective function by incorporating a time-varying z phase that is managed through linear programming to efficiently address the bottleneck nodes. Additionally, a gateway node continually updates the remaining energy levels of all nodes and relays this information to the IoT cloud. Our findings indicate that the outage-optimal distance achieved by WPCD-ACO is 6092 m, compared to 7225 m for the shortest path and 6142 m for Dijkstra’s algorithm. Furthermore, the WPCD-ACO minimizes energy consumption to 1.543 KJ, significantly outperforming other methods: single-hop at 4.8643 KJ, GR-Protocol at 3.165 KJ, grid clustering at 2.4839 KJ, and C-SARSA at 2.5869 KJ, respectively. Monte Carlo simulations validate that WPCD-ACO is outshining the existing methods in terms of the network lifetime, stability, survival rate of sensor nodes, and energy consumption. Full article
(This article belongs to the Section Intelligent Sensors)
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25 pages, 23966 KiB  
Article
Online Service Function Chain Planning for Satellite–Ground Integrated Networks to Minimize End-to-End (E2E) Delay
by Soohyeong Kim, Joohan Park, Jiseung Youn, Seyoung Ahn and Sunghyun Cho
Sensors 2024, 24(22), 7286; https://doi.org/10.3390/s24227286 - 14 Nov 2024
Viewed by 272
Abstract
The combination of software-defined networking (SDN) and satellite–ground integrated networks (SGINs) is gaining attention as a key infrastructure for meeting the granular quality-of-service (QoS) demands of next-generation mobile communications. However, due to the unpredictable nature of end-user requests and the limited resource capacity [...] Read more.
The combination of software-defined networking (SDN) and satellite–ground integrated networks (SGINs) is gaining attention as a key infrastructure for meeting the granular quality-of-service (QoS) demands of next-generation mobile communications. However, due to the unpredictable nature of end-user requests and the limited resource capacity of low Earth orbit (LEO) satellites, improper Virtual Network Function (VNF) deployment can lead to significant increases in end-to-end (E2E) delay. To address this challenge, we propose an online algorithm that jointly deploys VNFs and forms routing paths in an event-driven manner in response to end-user requests. The proposed algorithm selectively deploys only the essential VNFs required for each Service Function Chain (SFC), focusing on minimizing E2E delay—a critical QoS parameter. By defining a minimum-hop region (MHR) based on the geographic coordinates of the routing endpoints, we reduce the search space for candidate base stations, thereby designing paths that minimize propagation delays. VNFs are then deployed along these paths to further reduce E2E delay. Simulations demonstrate that the proposed algorithm closely approximates the global optimum, achieving up to 97% similarity in both E2E delay and CPU power consumption, with an average similarity of approximately 90%. Full article
(This article belongs to the Section Communications)
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16 pages, 2870 KiB  
Article
A Construction Method for the Random Factor-Based G Function
by Yongxin Feng, Jiankai Su and Bo Qian
Appl. Sci. 2024, 14(22), 10478; https://doi.org/10.3390/app142210478 - 14 Nov 2024
Viewed by 222
Abstract
In consideration of the prevailing methodology for constructing G functions, there are certain limitations such as fixed change rules and restricted flexibility when producing frequency-hopping sequences. This paper introduces a novel construction method for the Random Factor-based G function (RFGF). This approach incorporates [...] Read more.
In consideration of the prevailing methodology for constructing G functions, there are certain limitations such as fixed change rules and restricted flexibility when producing frequency-hopping sequences. This paper introduces a novel construction method for the Random Factor-based G function (RFGF). This approach incorporates random factors to dynamically divide the frequency set into equal intervals and randomly selects the frequency hopping frequency within each subset. This effectively reduces the correlation between adjacent frequency-hopping frequencies, enhancing the randomness of the sequence and the system’s anti-interference performance. Furthermore, this method utilizes chaotic sequences to scramble data information, further strengthening the security of the information. The experimental results demonstrate that the frequency-hopping sequence generated by this proposed G function construction method outperforms the sequence generated by the time-varying iterative decomposition in terms of randomness, uniformity, and two-dimensional continuity. Specifically, under the same parameter conditions, the two-dimensional continuity is improved by 36.87%. Full article
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34 pages, 1718 KiB  
Article
Lyrical Code-Switching, Multimodal Intertextuality, and Identity in Popular Music
by Michael D. Picone
Languages 2024, 9(11), 349; https://doi.org/10.3390/languages9110349 - 14 Nov 2024
Viewed by 507
Abstract
Augmenting the author’s prior research on lyrical code-switching, as presented in Picone, “Artistic Codemixing”, published in 2002, various conceptual frameworks are made explicit, namely the enlistment of multimodal and intertextual approaches for their methodological usefulness in analyzing and interpreting message-making that incorporates lyrical [...] Read more.
Augmenting the author’s prior research on lyrical code-switching, as presented in Picone, “Artistic Codemixing”, published in 2002, various conceptual frameworks are made explicit, namely the enlistment of multimodal and intertextual approaches for their methodological usefulness in analyzing and interpreting message-making that incorporates lyrical code-switching as one of its components. Conceived as a bipolarity, the rooted (or local) and the transcendent (or global), each having advantages in the negotiation of identity, is also applied to the analysis. New departures include the introduction of the notion of “curated lyrical code-switching” for the purpose of analyzing songs in which multiple performers are assigned lyrics in different languages, as a function of their respective proficiencies, as curated by the person or persons having authorial agency and taking stock of the social semiotics relevant to the anticipated audience. Moving beyond the negotiation of the identity of the code-switching composer or performer, in another new departure, attention is paid to the musical identity of the listener. As a reflection of the breadth of lyrical code-switching, a rich assortment of examples draws from the musical art of Beyoncé, Jon Batiste, Stromae, Shakira, BTS, NewJeans, Indigenous songsmiths, Cajun songsmiths, Latin Pop and Hip-Hop artists, songs composed for international sports events, and other sources. Full article
(This article belongs to the Special Issue Interface between Sociolinguistics and Music)
13 pages, 16555 KiB  
Article
Miodynamic and Radiographic Evaluation in Recreative Athletes with Patellofemoral Pain
by Abiel Eugenio Garza-Borjón, Mirna González-González, José Fernando de la Garza-Salazar, Mario Simental-Mendía and Carlos Acosta-Olivo
Medicina 2024, 60(11), 1860; https://doi.org/10.3390/medicina60111860 - 13 Nov 2024
Viewed by 290
Abstract
Background and Objectives: Patellofemoral pain (PFP) is frequent in the young and active population. The effect of muscle strength in the lower extremities after aerobic activity in patients with this condition has yet to be detailed. Our objective was to determine if patients [...] Read more.
Background and Objectives: Patellofemoral pain (PFP) is frequent in the young and active population. The effect of muscle strength in the lower extremities after aerobic activity in patients with this condition has yet to be detailed. Our objective was to determine if patients with PFP show alterations in lower extremity muscle strength measurements after performing a session of ten minutes of aerobic activity on a treadmill compared to people without patellofemoral pain. Materials and Methods: We conducted a prospective experimental study with a stratified, non-randomized, and non-blinded population sample with group matching, including an experimental group with PFP and a control group with no pain. Subjects completed self-reported functional questionnaires (IKDC, Kujala, KOOS, SF-12), underwent radiographic studies, and were evaluated by measuring the strength of hip and knee muscles and the Single-Leg Triple-Hop (SLTH) test before and after ten minutes of exercise on a treadmill. Results: Seventeen subjects diagnosed with PFP and seventeen control subjects were evaluated. Both groups were homogeneous and had no significant differences in the demographic variables. A wider sulcus angle at 30° (136.8 ± 3.8° vs. 132.5 ± 5.6°, p = 0.0140), a decrease strength post-exercise in the hip abductor (37.9 ± 7.1 N⋅m vs. 45.6 ± 7.7 N⋅m, p < 0.05) and knee extensor (36.0 ± 9.1 N⋅m vs. 47.7 ± 14.0 N⋅m, p < 0.05), and a shorter distance in the SLTH test (337.9 ± 74.9 cm vs. 438.6 ± 65.8 cm, p < 0.01) was recorded in subjects with patellofemoral pain. Conclusions: Subjects with PFP had an overall lower strength of hip and knee muscles, showing significant differences in the hip abductors and knee extensors between people with PFP and healthy matched controls after aerobic exercise. Full article
(This article belongs to the Section Sports Medicine and Sports Traumatology)
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11 pages, 5675 KiB  
Communication
780 nm Narrow Linewidth External Cavity Diode Laser for Quantum Sensing
by Junzhu Ye, Chenggang Guan, Puchu Lv, Weiqi Wang, Xuan Chen, Ziyi Wang, Yifan Xiao, Linfeng Zhan, Jiaoli Gong and Yucheng Yao
Sensors 2024, 24(22), 7237; https://doi.org/10.3390/s24227237 - 13 Nov 2024
Viewed by 341
Abstract
To meet the demands of laser communication, quantum precision measurement, cold atom technology, and other fields for narrow linewidth and low-noise light sources, an external cavity diode laser (ECDL) operating in the wavelength range around 780 nm was set up with a Fabry–Pérot [...] Read more.
To meet the demands of laser communication, quantum precision measurement, cold atom technology, and other fields for narrow linewidth and low-noise light sources, an external cavity diode laser (ECDL) operating in the wavelength range around 780 nm was set up with a Fabry–Pérot etalon (F–P) and an interference filter (IF) in the experiment. The interference filter type ECDL (IF–ECDL) with butterfly-style packaging configuration has continuous wavelength tuning within a specified range through precise temperature and current control and has excellent single-mode characteristics. Experimental results indicate that the output power of the IF–ECDL is 14 mW, with a side-mode suppression ratio (SMSR) of 54 dB, a temperature-controlled mode-hop-free tuning range of 527 GHz (1.068 nm), and an output linewidth of 570 Hz. Compared to traditional lasers operating at 780 nm, the IF–ECDL exhibits narrower linewidth, lower noise, and higher spectral purity, and its dimensions are merely 25 × 15 × 8.5 mm3 weighing only 19.8 g, showcasing remarkable miniaturization and lightweight advantages over similar products in current research fields. Full article
(This article belongs to the Section Optical Sensors)
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15 pages, 3616 KiB  
Article
Polarizing Magnetic Field Effect on Some Electrical Properties of a Ferrofluid in Microwave Field
by Catalin N. Marin, Paul C. Fannin and Iosif Malaescu
Magnetochemistry 2024, 10(11), 88; https://doi.org/10.3390/magnetochemistry10110088 - 9 Nov 2024
Viewed by 505
Abstract
The complex dielectric permittivity, ε (f, H) = ε′ (f, H) − i ε″ (f, H), in the microwave frequency range f, of (0.1–3) GHz and polarizing field values H, [...] Read more.
The complex dielectric permittivity, ε (f, H) = ε′ (f, H) − i ε″ (f, H), in the microwave frequency range f, of (0.1–3) GHz and polarizing field values H, in the range of (0–135) kA/m, was measured for a kerosene-based ferrofluid with magnetite particles. A relaxation process attributed to interfacial type relaxation was highlighted, determining for the first time in the microwave field, the activation energy of the dielectric relaxation process in the presence of the magnetic field, EA(H), in relation to the activation energy in zero field, EA(H = 0). Based on the complex permittivity measurements and the Claussius–Mossotti equation, the dependencies on frequency (f), and magnetic field (H), of the polarizability (α) and electrical conductivity (σ), were determined. From the dependence of α(f,H), the electric dipolar moment, p, of the particles in the ferrofluid, was determined. The conductivity spectrum, σ(f,H), was found to be in agreement with Jonscher’s universal law and the electrical conduction mechanism in the ferrofluid was explained using both Mott’s VRH (variable range hopping) model and CBH (correlated barrier hopping) model. Based on these models and conductivity measurements, the hopping distance, Rh, of the charge carriers and the maximum barrier height, Wm, for the investigated ferrofluid was determined for the first time in the microwave field. Knowledge of these electrical properties of the ferrofluid in the microwave field is useful for explaining the mechanisms of polarization and control of electrical conductivity with an external magnetic field, in order to use ferrofluids in various technological applications in microwave field. Full article
(This article belongs to the Section Magnetic Materials)
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33 pages, 1638 KiB  
Article
Enhancing Communication Security in Drones Using QRNG in Frequency Hopping Spread Spectrum
by J. de Curtò, I. de Zarzà, Juan-Carlos Cano and Carlos T. Calafate
Future Internet 2024, 16(11), 412; https://doi.org/10.3390/fi16110412 - 8 Nov 2024
Viewed by 847
Abstract
This paper presents a novel approach to enhancing the security and reliability of drone communications through the integration of Quantum Random Number Generators (QRNG) in Frequency Hopping Spread Spectrum (FHSS) systems. We propose a multi-drone framework that leverages QRNG technology to generate truly [...] Read more.
This paper presents a novel approach to enhancing the security and reliability of drone communications through the integration of Quantum Random Number Generators (QRNG) in Frequency Hopping Spread Spectrum (FHSS) systems. We propose a multi-drone framework that leverages QRNG technology to generate truly random frequency hopping sequences, significantly improving resistance against jamming and interception attempts. Our method introduces a concurrent access protocol for multiple drones to share a QRNG device efficiently, incorporating robust error handling and a shared memory system for random number distribution. The implementation includes secure communication protocols, ensuring data integrity and confidentiality through encryption and Hash-based Message Authentication Code (HMAC) verification. We demonstrate the system’s effectiveness through comprehensive simulations and statistical analyses, including spectral density, frequency distribution, and autocorrelation studies of the generated frequency sequences. The results show a significant enhancement in the unpredictability and uniformity of frequency distributions compared to traditional pseudo-random number generator-based approaches. Specifically, the frequency distributions of the drones exhibited a relatively uniform spread across the available spectrum, with minimal discernible patterns in the frequency sequences, indicating high unpredictability. Autocorrelation analyses revealed a sharp peak at zero lag and linear decrease to zero values for other lags, confirming a general absence of periodicity or predictability in the sequences, which enhances resistance to predictive attacks. Spectral analysis confirmed a relatively flat power spectral density across frequencies, characteristic of truly random sequences, thereby minimizing vulnerabilities to spectral-based jamming. Statistical tests, including Chi-squared and Kolmogorov-Smirnov, further confirm the unpredictability of the frequency sequences generated by QRNG, supporting enhanced security measures against predictive attacks. While some short-term correlations were observed, suggesting areas for improvement in QRNG technology, the overall findings confirm the potential of QRNG-based FHSS systems in significantly improving the security and reliability of drone communications. This work contributes to the growing field of quantum-enhanced wireless communications, offering substantial advancements in security and reliability for drone operations. The proposed system has potential applications in military, emergency response, and secure commercial drone operations, where enhanced communication security is paramount. Full article
(This article belongs to the Section Internet of Things)
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15 pages, 3866 KiB  
Article
Distributed Passive Positioning and Sorting Method for Multi-Network Frequency-Hopping Time Division Multiple Access Signals
by Jiaqi Mao, Feng Luo and Xiaoquan Hu
Sensors 2024, 24(22), 7168; https://doi.org/10.3390/s24227168 - 8 Nov 2024
Viewed by 327
Abstract
When there are time division multiple access (TDMA) signals with large bandwidth, waveform aliasing, and fast frequency-hopping in space, current methods have difficulty achieving the accurate localization of radiation sources and signal-sorting from multiple network stations. To solve the above problems, a distributed [...] Read more.
When there are time division multiple access (TDMA) signals with large bandwidth, waveform aliasing, and fast frequency-hopping in space, current methods have difficulty achieving the accurate localization of radiation sources and signal-sorting from multiple network stations. To solve the above problems, a distributed passive positioning and network stations sorting method for broadband frequency-hopping signals based on two-level parameter estimation and joint clustering is proposed in this paper. Firstly, a two-stage filtering structure is designed to achieve control filtering for each frequency point. After narrowing down the parameter estimation range through adaptive threshold detection, the time difference of arrival (TDOA) and the velocity difference of arrival (VDOA) can be obtained via coherent accumulating based on the cross ambiguity function (CAF). Then, a multi-station positioning method based on the TDOA/VDOA is used to estimate the position of the target. Finally, the distributed joint eigenvectors of the multi-stations are constructed, and the signals belonging to different network stations are effectively classified using the improved K-means method. Numerical simulations indicate that the proposed method has a better positioning and sorting effect in low signal-to-noise (SNR) and low snapshot conditions compared with current methods. Full article
(This article belongs to the Section Communications)
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19 pages, 6745 KiB  
Article
Frequency-Hopping Binary Offset Carrier Modulation with Independent Frequency-Hopping Patterns in Lower and Upper Sidebands
by Yikang Yang, Jiangang Ma, Lingyu Deng and Hengnian Li
Remote Sens. 2024, 16(22), 4151; https://doi.org/10.3390/rs16224151 - 7 Nov 2024
Viewed by 571
Abstract
To enhance the anti-interference capabilities and increase flexibility in frequency allocation between the lower and upper sidebands of the navigation signal, we introduce frequency-hopping binary offset carrier modulation with independent frequency-hopping patterns in lower and upper sidebands (IFH-BOC). This novel modulation is classified [...] Read more.
To enhance the anti-interference capabilities and increase flexibility in frequency allocation between the lower and upper sidebands of the navigation signal, we introduce frequency-hopping binary offset carrier modulation with independent frequency-hopping patterns in lower and upper sidebands (IFH-BOC). This novel modulation is classified as a constant-envelope multiplexing (CEM) method, with independent frequency-hopping patterns for the lower and upper sidebands, in contrast with frequency-hopping binary offset carrier (FH-BOC) and binary offset carrier (BOC) modulations, which share the same patterns. IFH-BOC represents a generalized modulation that incorporates FH-BOC and BOC, thus retaining their advantages while introducing new characteristics, such as independent frequency-hopping pattern design and flexible spectral splitting. The results indicate that IFH-BOC maintains the same time–frequency characteristics and measurement accuracy as FH-BOC when using identical modulation parameters, yet it demonstrates superior anti-interference performance due to its varied frequency-hopping patterns. Furthermore, IFH-BOC provides enhanced flexibility in spectral splitting compared with BOC modulation, potentially allowing for increased availability of L-band frequencies for satellite navigation. With these benefits, IFH-BOC is poised to be a promising modulation for the signal design of next-generation global navigation satellite systems. Full article
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22 pages, 1556 KiB  
Article
Mobility-Based Multi-Hop Content Precaching Scheme in Content-Centric Vehicular Networks
by Hyunseok Choi, Youngju Nam, Gayeong Kim and Euisin Lee
Electronics 2024, 13(22), 4367; https://doi.org/10.3390/electronics13224367 - 7 Nov 2024
Viewed by 307
Abstract
Due to the rapid development of smart vehicles, such as self-driving cars, the demand for mobile data traffic by vehicle users has increased so much that base stations cannot handle it, causing delays in content provision. The burden on the base station can [...] Read more.
Due to the rapid development of smart vehicles, such as self-driving cars, the demand for mobile data traffic by vehicle users has increased so much that base stations cannot handle it, causing delays in content provision. The burden on the base station can be alleviated through roadside units (RSUs) to distribute the demand. However, outage zones, which fall outside the communication range of RSUs, still exist due to their high deployment cost. Existing schemes for covering outage zones have only considered single-hop precaching vehicles to provide precached content, which is insufficient to reduce outage zones effectively. Therefore, we propose a scheme to reduce outage zones by maximizing the amount of precached content using multi-hop precaching vehicles. The proposed scheme optimally selects precaching vehicles through a numerical model that calculates the amount of precached content. It enhances the process of multi-hop precaching by comparing the connection time of vehicles with the dark area time in the outage zone. To prevent excessive overheads due to frequent precaching vehicle handovers, the proposed scheme limits the selection to vehicles with a longer communication time, based on a precaching restriction indicator in the multi-hop precaching vehicle selection process. The simulation results show that our scheme outperforms representative schemes based on single-hop precaching. Full article
(This article belongs to the Special Issue Advances in Wireless Communication Performance Analysis)
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10 pages, 593 KiB  
Review
A Novel Look at Mechanisms and Applications of Xanthohumol (XN) in Dermatology and Cosmetology
by Anna Kołodziejczak, Marta Dziedzic, Barbara Algiert-Zielińska, Paulina Mucha and Helena Rotsztejn
Int. J. Mol. Sci. 2024, 25(22), 11938; https://doi.org/10.3390/ijms252211938 - 6 Nov 2024
Viewed by 431
Abstract
Xanthohumol (XN), representing the group of chalcones, is a hydroxyl and superoxide free radical scavenger. It also has antimicrobial properties, showing antibacterial activity against Staphylococcus aureus, Staphylococcus pyogenes, Staphylococcus epidermidis and Propionibacterium acnes. XN exerts an inhibitory effect on tyrosinase (it hinders the [...] Read more.
Xanthohumol (XN), representing the group of chalcones, is a hydroxyl and superoxide free radical scavenger. It also has antimicrobial properties, showing antibacterial activity against Staphylococcus aureus, Staphylococcus pyogenes, Staphylococcus epidermidis and Propionibacterium acnes. XN exerts an inhibitory effect on tyrosinase (it hinders the oxidation of l-tyrosine and l-DOPA). However, it also affects the transport of pigment (through a reduction in the number and length of dendrites) and its degradation (through damage to melanosomes). Additionally, it has been shown to inhibit the different activation pathways of the premeditated response in macrophages and reduce the secretion of pro-inflammatory cytokines TNF-α, IL-6 and IL-1β. Xanthohumol also improves skin elasticity by reducing the activity of elastase and MMP 1, 2 and 9, and it increases the expression of type I, III and V collagen, as well as elastin and fibrillins in skin fibroblasts. It acts against the main factors contributing to the pathogenesis of acne by inhibiting pro-inflammatory mediators (e.g., COX-2, PGE2, IL-1β and TNF-α). Moreover, it shows antibacterial activity against P. acnes and S. aureus, as well as seboregulatory and antioxidant properties. It has also been recognized that XN intake could affect diabetic wound healing. XN shows antitumoral activity, e.g., in the case of skin melanoma, which is associated with the antioxidant, pro-apoptotic, anti-angiogenic and immunostimulating effects of this compound. Full article
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13 pages, 326 KiB  
Article
New Families of Frequency-Hopping Sequence Sets with a Low-Hit-Zone
by Limengnan Zhou and Hanzhou Wu
Entropy 2024, 26(11), 948; https://doi.org/10.3390/e26110948 - 5 Nov 2024
Viewed by 341
Abstract
As a means of spread spectrum communication, frequency-hopping technology has good performance in anti-jamming, multiple-access, security, covert communications, and so on. In order to meet the needs of different frequency-hopping multiple-access (FHMA) communication scenarios, the research on frequency-hopping sequence (FHS) sets with a [...] Read more.
As a means of spread spectrum communication, frequency-hopping technology has good performance in anti-jamming, multiple-access, security, covert communications, and so on. In order to meet the needs of different frequency-hopping multiple-access (FHMA) communication scenarios, the research on frequency-hopping sequence (FHS) sets with a low-hit-zone (LHZ) is now becoming more and more crucial. In this paper, a general construction to obtain new families of LHZ-FHS sets is achieved via interleaving technique. Subsequently, based on two different shift sequences, two classes of LHZ-FHS sets with new flexible parameters not covered in the related literature are presented. The requirements for our new LHZ-FHS sets to obtain optimality or near-optimality with respect to the Peng–Fan–Lee bound are also introduced. Furthermore, as long as the base FHS set is fixed, the performances of new LHZ-FHS sets can be analyzed, such that the parameters of all appropriate shift sequences to obtain desired LHZ-FHS sets are also fixed. Full article
(This article belongs to the Special Issue Advances in Information and Coding Theory III)
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18 pages, 2697 KiB  
Article
Non-Adiabatic Excited-State Time-Dependent GW (TDGW) Molecular Dynamics Simulation of Nickel-Atom Aided Photolysis of Methane to Produce a Hydrogen Molecule
by Aaditya Manjanath, Ryoji Sahara, Yoshiyuki Kawazoe and Kaoru Ohno
Nanomaterials 2024, 14(22), 1775; https://doi.org/10.3390/nano14221775 - 5 Nov 2024
Viewed by 582
Abstract
Methane photolysis is a very important initiation reaction from the perspective of hydrogen production for alternative energy applications. In our recent work, we demonstrated using our recently developed novel method, non-adiabatic excited-state time-dependent GW (TDGW) molecular dynamics (MD), how [...] Read more.
Methane photolysis is a very important initiation reaction from the perspective of hydrogen production for alternative energy applications. In our recent work, we demonstrated using our recently developed novel method, non-adiabatic excited-state time-dependent GW (TDGW) molecular dynamics (MD), how the decomposition reaction of methane into a methyl radical and a hydrogen atom was captured accurately via the time-tracing of all quasiparticle levels. However, this process requires a large amount of photoabsorption energy (PAE ∼10.2 eV). Moreover, only one hydrogen atom is produced via a single photon absorption. Transition metal atoms can be used as agents for photochemical reactions, to reduce this optical gap and facilitate an easier pathway for hydrogen production. Here, we explore the photolysis of methane in the presence of a Ni atom by employing TDGW-MD. We show two possibilities for hydrogen-atom ejection with respect to the location of the Ni atom, towards the Ni side or away from it. We demonstrate that only the H ejection away from the Ni side facilitates the formation of a hydrogen molecule with the quasiparticle level corresponding to it having an energy close to the negative ionization potential of an isolated H2 molecule. This is achieved at a PAE of 8.4 eV which is lower compared to that of pristine methane. The results obtained in this work are an encouraging step towards transition metal-mediated hydrogen production via photolysis of hydrocarbons. Full article
(This article belongs to the Special Issue Modeling, Simulation and Optimization of Nanomaterials)
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