Search Results (28,313)

This paper takes corporate social responsibility goodwill and consumers’ reference low-carbon level as endogenous variables of joint carbon emission reduction in the “supplier–manufacturer–retailer–consumer” supply chain system. The joint carbon emission reduction strategies of this four-tier system are analyzed from a dynamic perspective by considering random factors that affect the endogenous variables. Three stochastic differential games are proposed to examine the mechanism between each player, namely the cooperative model, Nash non-cooperative model, and Stackelberg master–slave model. Compared to the Nash non-cooperative game, the manufacturer/supplier-led Stackelberg master–slave game leads to Pareto improvement in the profits of the entire supply chain system and each player. The cooperative game demonstrates the highest expected emission reduction and corporate social responsibility goodwill, but also the highest variance. More importantly, the reference low-carbon level embraces consumers’ subjective initiative in the dynamic of carbon emission reduction. This level is an internal benchmark used to compare against the observed low-carbon level. This paper provides a theoretical foundation for strategic decision-making in emission reduction, contributing to sustainable development. By addressing environmental, economic, and social sustainability, it promotes climate action through carbon reduction strategies and offers policy recommendations aligned with the Sustainable Development Goals. Full article

The photochemical and photoelectrochemical reduction of CO₂ is a promising approach for converting carbon dioxide into valuable chemicals (materials) and fuels. A key issue is ensuring the accuracy of experimental results in CO₂ reduction reactions (CO2RRs) because of potential sources of false positives. This paper reports the results of investigations on various factors that may contribute to erroneous attribution of reduced-carbon species, including degradation of carbon species contained in photocatalysts, residual contaminants from synthetic procedures, laboratory glassware, environmental exposure, and the operator. The importance of rigorous experimental protocols, including the use of labeled ¹³CO₂ and blank tests, to identify true CO₂ reduction products (CO2RPs) accurately is highlighted. Our experimental data (eventually complemented with or compared to literature data) underline the possible sources of errors and, whenever possible, quantify the false positives with respect to the effective conversion of CO₂ in clean conditions. This paper clarifies that the incidence of false positives is higher in the preliminary phase of photo-material development when CO2RPs are in the range of a few 10s of μg g_cat⁻¹ h⁻¹, reducing its importance when significant conversions of CO₂ are performed reaching 10s of mol g_cat⁻¹ h⁻¹. This paper suggests procedures for improving the reliability and reproducibility of CO2RR experiments, thus validating such technologies. Full article

Loneliness among young adults is a growing concern worldwide, posing serious health risks. While the human ecological framework explains how various factors such as socio-demographic, social, and built environment characteristics can affect this feeling, still, relatively little is known about the effect of built environment characteristics on the feelings of loneliness that young people experience in their daily life activities. This research investigates the relationship between built environment characteristics and emotional state loneliness in young adults (aged 18–25) during their daily activities. Leveraging the Experience Sampling Method, we collected data from 43 participants for 393 personal experiences during daily activities across different environmental settings. The findings of a mixed-effects regression model reveal that built environment features significantly impact emotional state loneliness. Notably, activity location accessibility, social company during activities, and walking activities all contribute to reducing loneliness. These findings can inform urban planners and municipalities to implement interventions that support youngsters’ activities and positive experiences to enhance well-being and alleviate feelings of loneliness in young adults. Specific recommendations regarding the built environment are (1) to create spaces that are accessible, (2) create spaces that are especially accessible by foot, and (3) provide housing with shared facilities for young adults rather than apartments/studios. Full article

Over the past few decades, synthetic petroleum-based packaging materials have increased, and the production of plastics has surpassed all other man-made materials due to their versatility. However, the excessive usage of synthetic packaging materials has led to severe environmental and health-related issues due to their nonbiodegradability and their accumulation in the environment. Therefore, bio-based packages are considered alternatives to substitute synthetic petroleum-based packaging material. Furthermore, the choice of packing material in the food industry is a perplexing process as it depends on various factors, such as the type of food product, its sustainability, and environmental conditions. Interestingly, due to proven mechanical, gas, and water vapor barrier properties and biological activity, polysaccharide-based bioplastics show the potential to expand the trends in food packaging, including edible films or coatings and intelligent and active food packaging. Various chemical modifications, network designs, and processing techniques have transformed polysaccharide materials into valuable final products, particularly for large-scale or high-value applications. Transitioning from petroleum-based resources to abundant bio-based polysaccharides presents an opportunity to create a sustainable circular economy. The economic viability of polysaccharide-based bioplastics is determined by several factors, including raw material costs, production technologies, market demand, and scalability. Despite their potential advantages over traditional plastics, their economic feasibility is affected by continuous technological advancements and evolving market dynamics and regulations. This review discusses the structure, properties, and recent developments in polysaccharide-based bioplastics as green and sustainable food packaging materials. Full article

Air pollution, greenspace and noise are interrelated environmental factors with the potential to influence human health outcomes. Research has measured these exposures in diverse ways across the globe, but no study has yet performed a country-wide analysis of air pollution, greenspace, and noise in England. This study examined cross-sectional PM_2.5, NO₂, greenness, accessible greenspace, road noise, and rail noise exposure data at all residential postcodes in England (n = 1,227,681). Restricted cubic spline models were fitted between each environmental exposure and a measure of socioeconomic status, the Index of Multiple Deprivation (IMD) rank. Population-weighted exposures by IMD deciles, urbanicity, and region were subsequently estimated. Restricted cubic spline models were also fitted between greenness and each other environmental exposure in the study. The results show some evidence of inequalities in exposure to air pollutants, greenspace, and noise across England. Notably, there is a socioeconomic gradient in greenness, NO₂, PM_2.5, and road noise in London. In addition, NO₂, PM_2.5, and road noise exposure decrease as greenness increases in urban areas. Concerningly, almost all air pollution estimates in our study exceed international health guidelines. Further research is needed to elucidate the socioeconomic patterns and health impacts of air pollution, greenspace, and noise over time. Full article

In addition to the surrounding climatic environment, the intrinsic characteristics of the stones used in construction are a critical factor to understand a building’s conservation state and define the necessary planning and conservation management activities. The use of environmentally susceptible stones, such as carbonate stones, in heritage buildings can be especially problematic. The present investigation presents an overview of past research and contributes to identifying the types of carbonate stones used over time in Coimbra’s Old Cathedral in Portugal, which was classified as a National Monument and integrated into the Coimbra World Heritage site by UNESCO. Our mineralogical and chemical analyses revealed the use of carbonate stones from different quarries (Coimbra region), including Ançã limestone and dolostone (Porta Especiosa portal), Portunhos limestone and Outil limestone (in the perimeter of windows), and marlstones and Outil limestone (side facades). These stones, which were installed at various times during the construction and alteration of the monument, represent a great challenge for conservation planning due to their intrinsic vulnerability to adverse environmental conditions and pollution. Full article

Radiation-induced cataracts (RICs) represent a significant public health challenge, particularly impacting individuals exposed to ionizing radiation (IR) through medical treatments, occupational settings, and environmental factors. Effective therapeutic strategies require a deep understanding of the mechanisms underlying RIC formation (RICF). This study investigates the roles of angiotensin II (Ang II) and oxidative stress in RIC development, with a focus on their combined effects on lens transparency and cellular function. Key mechanisms include the generation of reactive oxygen species (ROS) and oxidative damage to lens proteins and lipids, as well as the impact of Ang II on inflammatory responses and cellular apoptosis. While the generation of ROS from water radiolysis is well established, the impact of Ang II on RICs is less understood. Ang II intensifies oxidative stress by activating type 1 receptors (AT1Rs) on lens epithelial cells, resulting in increased ROS production and inflammatory responses. This oxidative damage leads to protein aggregation, lipid peroxidation, and apoptosis, ultimately compromising lens transparency and contributing to cataract formation. Recent studies highlight Ang II’s dual role in promoting both oxidative stress and inflammation, which accelerates cataract development. RICs pose a substantial public health concern due to their widespread prevalence and impact on quality of life. Targeting Ang II signaling and oxidative stress simultaneously could represent a promising therapeutic approach. Continued research is necessary to validate these strategies and explore their efficacy in preventing or reversing RIC development. Full article

One of the worst natural, economic, and social catastrophes caused by human activity is the Aral Sea crisis in Central Asia. The Aral Sea’s desiccation, which has an impact on the region’s overall sustainable development, human welfare, security, and survival, is what led to the problem. This study assesses the effects of economic expansion, population ageing, life expectancy, internet usage, and greenhouse gas emissions on the fertility rate in the countries that made up the Aral Sea basin between 1990 and 2021. Several econometric techniques were used in this study, including Pooled OLS (Ordinary Least Squares) with the Driscoll–Kraay estimating method, FMOLS (Fully Modified Ordinary Least Square), and DOLS (Dynamic Ordinary Least Square). Additionally, we used the Hurlin and Dumitrescu non-cause tests to verify the causal links between the variables. The empirical findings verify that a decrease in the fertility rate among women in the nations surrounding the Aral Sea occurs when the population of a certain age (women aged 15–64 as a percentage of the total population) grows and life expectancy rises. Greenhouse gas emissions (GHGs) also have an adverse effect on reproductive rates. Conversely, the region’s fertility rate may rise as a result of increased internet usage and economic growth. Furthermore, this study indicates that certain variables—aside from greenhouse gas emissions (GHGs)—have a causal relationship with the fertility rate. Full article

Nitrogen (N) deposition rates have notably increased around the world, especially in high-altitude regions like the Qinghai–Tibetan Plateau (QTP). We conducted a six-year comprehensive experiment to simulate nitrogen deposition in an alpine grassland area near Qinghai Lake. Four levels of nitrogen depositions, i.e., 0 (CK), 8 kg N ha⁻¹year⁻¹ (N1), 40 kg N ha⁻¹year⁻¹ (N2), and 72 kg N ha⁻¹year⁻¹ (N3), with three replicates for each N treatment, were tested annually in early May and early July, with the meticulous collection of plant and soil samples during the peak growth period from 15 July to 15 August. We used the null model to evaluate the impact of environmental filtration and interspecific competition on the dynamics of the plant community was assessed based on the level of discrete species affinities within the plant community by constructing a phylogenetic tree. The results showed that the environmental filter was the predominant driver for the change of community’s genealogical fabric. The N2 and N3 treatments increased the influence of soil factors on the change of plant community structure. Climatic factors played a crucial role on the change of plant community in the CK grassland area, while soil factors were dominant in the N1- and N3-treated grasslands. Full article

In modern medicine, studies devoted to the assessment of the parameters of residential infrastructure and the population’s attitude towards them have become quite large-scale. Objectives: The aim of the study was to establish associations between individually perceived parameters of residential infrastructure and the main modifiable cardiovascular risk factors (hypertension, obesity, lipid and carbohydrate metabolism disorders) in one of the subjects of the Russian Federation. Methods: The epidemiological study “Study of the influence of social factors on chronic non-communicable diseases” started in 2015 and ended in 2023. The sample was formed by using the stratification method based on the assignment to a medical organization. The study included 1598 respondents aged 35 to 70 years (491 rural residents). The study of infrastructure parameters was conducted based on the subjective opinions of respondents using the neighborhood environment walkability scale (NEWS) questionnaire, divided into eight scales. Logistic regression analysis was used to identify associations between infrastructure parameters and cardiovascular risk factors; the odds ratio (OR) and 95% confidence interval were evaluated. Results: Individually perceived infrastructure parameters of the scale B, reflecting the accessibility of infrastructure facilities, were associated with hypertension [OR = 1.33], obesity [OR = 1.40], and abdominal obesity [OR = 1.59]. Elements of the social infrastructure of the scale C, describing the streets in the residential area, increased the likelihood of developing obesity [OR = 1.42] and visceral obesity [OR = 1.43]. The characteristics of the residential area, represented by the scale D that evaluates pedestrian infrastructure, were associated with all major cardiovascular risk factors (hypertension [OR = 1.65], obesity [OR = 1.62] and abdominal obesity [OR = 1.82], and disorders of lipid [OR = 1.41] and carbohydrate metabolism [OR = 1.44]). Conclusion: Social factors represented by various aspects of infrastructure have become important criteria for determining cardiovascular health. Environmental conditions affect cardiovascular risk factors through behavioral patterns that shape the respondent’s lifestyle. Interventions in urban planning—increasing accessibility to infrastructure facilities for the population, developing a pedestrian-friendly urban environment, improving physical activity resources in areas, planning recreation areas, and landscaping—can become the most important concept for the prevention of cardiovascular diseases. Full article

The Hunjiang River, a vital water system in northeastern China, has suffered severe ecological damage due to overexploitation. This study analyzes the basin’s environmental conditions from 2016 to 2020, identifies key restoration factors, and examines practical restoration projects. Investigating five major pollutants (permanganate index, chemical oxygen demand (COD), biochemical oxygen demand, ammonia nitrogen, total phosphorus) in eight sections, the study finds the Xicun section most polluted, mainly from Baishan City’s industrial and domestic discharges. The ammonia nitrogen concentration at the Zian section also shows deterioration. Using a DPSIR (Driving forces, Pressures, State, Impacts, Responses) framework, the study elucidates the relationship between environmental and socio-economic issues. Results indicate that population changes, industrial development, and water resource management have complex ecological impacts. Evaluating the urban water resource carrying capacity with the entropy weight method and correlation coefficient weighting method, the study finds that increasing forest coverage, improving wastewater treatment efficiency, and reducing COD emissions are crucial. Quantitative assessment of integrated protection and restoration projects involving mountains, rivers, forests, farmlands, lakes, and grasslands demonstrates their positive impact. This research reveals the interplay between the ecological environment and social factors, proposes practical restoration measures, and clarifies project effects, providing reliable decision-making schemes for policymakers. Full article

Detecting IgE sensitizations in the serum of allergic dogs is commonly performed using allergen extracts, but these are difficult to standardize. This article details the development and validation of the Pet Allergy Xplorer (PAX; Nextmune, Stockholm, Sweden), the first multiplex macroarray for the detection of IgE sensitization in dogs using allergen extracts and molecular components; the PAX is derived from the Allergy Xplorer (ALEX²; MacroArray Diagnostics, Vienna, Austria). The selection of allergens, cartridge processing, strategy for identifying and blocking IgE directed against cross-reactive carbohydrate determinants (CCDs), and the method used for determining the positivity threshold are described. The validation of the PAX included evaluations of the specificity of its anti-IgE monoclonal antibody, specificity of IgE binding to target allergens, assay precision, and internal consistency. Additionally, the influence of possible confounding factors, such as sample type, the influence of hemolysis, lipemia, bilirubinemia, and elevated CCD-IgE, was tested. Finally, the sensitization rates of 23,858 European dogs to 145 environmental and Hymenoptera venom allergens were summarized. The PAX is accurate and reproducible and has a unique CCD-detection and blocking strategy; its molecular allergens offer a unique window on allergen cross-reactivity. Full article

The consumption of fatty acids offers significant health benefits; however, they are prone to degradation by environmental factors. One method to preserve these fatty acids is the addition of synthetic antioxidants. This study focuses on the determination of peroxide and MDA formation rates at temperatures of 25 °C, 45 °C, and 65 °C. The oxidative stability of cold-pressed avocado oil was evaluated using pure astaxanthin, TBHQ, and H. pluvialis extract at concentrations of 100, 500, and 1000 ppm. Kinetic models and thermodynamic analysis were applied to determine the oxidation rate and compare the antioxidant effects of H. pluvialis extract with astaxanthin and TBHQ. The Arrhenius model was used to estimate activation energy (Ea), enthalpy, entropy, and free energy. Avocado oil with 500 ppm of H. pluvialis extract showed antioxidant effects comparable to TBHQ and pure astaxanthin. The activation energy of plain avocado oil was 40.47 kJ mol⁻¹, while with H. pluvialis extract, it was 54.35 kJ mol⁻¹. These findings suggest that H. pluvialis extract offers effective antioxidant properties and could serve as a natural alternative to synthetic antioxidants in food applications, despite the limitations of unprotected astaxanthin. Full article

This paper proposes the use of Pierre Bourdieu’s sociological concepts of social fields, capital, and habitus to analyze water management in Colombia. By mapping the social dynamics of water management, this study examines the interactions and power relationships among agents, including government agencies, private companies, academic institutions, non-profits, and local communities. The analysis reveals how various forms of capital, such as economic, cultural, social, and symbolic, influence water management practices, policies, and the distribution of power. Integrating agent-based modeling with hydrological simulations provides a more nuanced understanding of how social dynamics influence water management. This interdisciplinary approach helps develop more adaptive and equitable strategies by capturing the complex interactions between human behavior and environmental factors. This study highlights the need to localize the analysis of the social field to capture regional customs and specific social dynamics. This localized approach ensures that water management strategies are more relevant, context sensitive, and sustainable. This paper advocates for the wider adoption of agent-based modeling in water management, proposing a methodology that combines the engineering principles of practical problem solving and adaptive design with an understanding of the social complexities in water management. Full article

Understanding the driving mechanisms behind surface urban heat island (SUHI) effects is essential for mitigating the degradation of urban thermal environments and enhancing urban livability. However, previous studies have primarily concentrated on central urban areas, lacking a comprehensive analysis of the entire metropolitan area over distinct time periods. Additionally, most studies have relied on regression analysis models such as ordinary least squares (OLS) or logistic regression, without adequately analyzing the spatial heterogeneity of factors influencing the surface urban heat island (SUHI) effects. Therefore, this study aims to explore the spatial heterogeneity and driving mechanisms of surface urban heat island (SUHI) effects in the Guangzhou-Foshan metropolitan area across different time periods. The Local Climate Zones (LCZs) method was employed to analyze the landscape characteristics and spatial structure of the Guangzhou-Foshan metropolis for the years 2013, 2018, and 2023. Furthermore, Geographically Weighted Regression (GWR), Multi-scale Geographically Weighted Regression (MGWR), and Geographical Detector (GD) models were utilized to investigate the interactions between influencing factors (land cover factors, urban environmental factors, socio-economic factors) and Surface Urban Heat Island Intensity (SUHII), maximizing the explanation of SUHII across all time periods. Three main findings emerged: First, the Local Climate Zones (LCZs) in the Guangzhou-Foshan metropolitan area exhibited significant spatial heterogeneity, with a non-linear relationship to SUHII. Second, the SUHI effects displayed a distinct core-periphery pattern, with Large lowrise (LCZ 8) and compact lowrise (LCZ 3) areas showing the highest SUHII levels in urban core zones. Third, land cover factors emerged as the most influential factors on SUHI effects in the Guangzhou-Foshan metropolis. These results indicate that SUHI effects exhibit notable spatial heterogeneity, and varying negative influencing factors can be leveraged to mitigate SUHI effects in different metropolitan locations. Such findings offer crucial insights for future urban policy-making. Full article