Search Results (341)

The rapid formation of secondary nitrate (NO₃⁻) contributes significantly to the nocturnal increase of PM_2.5 and has been shown to be a critical factor for aerosol pollution in the North China Plain (NCP) region in summer. To explore the nocturnal NO₃⁻ formation pathways and the influence of ozone (O₃) on NO₃⁻ production, the WRF-CMAQ model was utilized to simulate O₃ and PM_2.5 co-pollution events in the NCP region. The simulation results demonstrated that heterogeneous hydrolysis of dinitrogen pentoxide (N₂O₅) accounts for 60% to 67% of NO₃⁻ production at night (22:00 to 05:00) and is the main source of nocturnal NO₃⁻. O₃ enhances the formation of NO₃ radicals, thereby further promoting nocturnal N₂O₅ production. In the evening (20:00 to 21:00), O₃ sustains the formation of hydroxyl (OH) radicals, resulting in the reaction between OH radicals and nitrogen dioxide (NO₂), which accounts for 48% to 64% of NO₃⁻ formation. Our results suggest that effective control of O₃ pollution in NCP can also reduce NO₃⁻ formation at night. Full article

Surface ozone (O₃) pollution has adverse impacts on the yield of winter wheat. The North China Plain (NCP), one of the globally significant primary regions for winter wheat production, has been frequently plagued by severe O₃ pollution in recent years. In this study, the effects of O₃ pollution on winter wheat yield and economic impact were evaluated in the NCP during the 2015–2018 seasons using the regional atmospheric chemical transport model (WRF-Chem), O₃ metrics including the phytotoxic surface O₃ dose above 12 nmol m⁻² s⁻¹ (POD₁₂), and the accumulated daytime O₃ above 40 ppb (AOT40). Results showed that the modeled O₃, exposure-based AOT40, and flux-based POD₁₂ increased during the winter wheat growing season from 2015 to 2018. The annual average daytime O₃, exposure-based AOT40, and flux-based POD₁₂ were 44 ppb, 5.32 ppm h, and 1.78 mmol m⁻², respectively. During 2015–2018, winter wheat relative production loss averaged 10.9% with AOT40 and 14.6% with POD₁₂. This resulted in an average annual production loss of 12.4 million metric tons, valued at approximately USD 4.5 billion. This study enhances our understanding of the spatial sensitivity of winter wheat to O₃ impacts, and suggests that controlling O₃ pollution during the key growth stages of winter wheat or improving its O₃ tolerance will enhance food security. Full article

The uneven soil fertility made it difficult to implement the recommended nitrogen (N) management practices in the North China Plain (NCP). In order to clarify the effect of N managements in high-fertility soil with a perennial wheat yield of 10,500 kg ha⁻¹ on photosynthetic characteristics, grain yield, N agronomic efficiency (NAE), and water use efficiency (WUE), a trial was conducted from 2022 to 2024. Main plots were N rates of 0 (N1), 150 (N2), 210 (N3), and 270 (N4) kg N ha⁻¹; The sub-plots adopted fertigation (F) and traditional fertilization method (T). The results showed that, compared with T, F increased the intercept rate of photosynthetic effective radiation of canopy, net photosynthetic rate, stomatal conductance, and transpiration rate of flag leaves, as well as the activity of phosphate sucrose synthase and sucrose content. It enhanced dry matter transport and contribution to grain. Under N2, the time required to reach the maximum grain filling rate, duration of grain filling and active grain-filling period of F were improved. Grain yield of N2 was increased by 27.81% and 6.75% compared to N1 and N3, respectively. NAE was improved by 48.63% and 51.47%, and WUE was improved by 20.71% and 9.85%. Therefore, the best effect was achieved by using fertigation and the N rate of 210 kg ha⁻¹ in high-fertility soil. Full article

Exploring the coordination of agricultural water resources (W), cultivated land (L), and the ecoenvironment (E) system is crucial for sustainable agriculture in the North China Plain (NCP). However, the synergistic effects of this composite system remain unclear. Coupling coordination degrees (CCDs) of 53 cities in the NCP for the years 2011, 2015, and 2020 were evaluated using the TOPSIS model, and the coupling coordination model, combined with the analytic hierarchy process and entropy weight method. The evaluation results were further analyzed to identify obstacle factors. The findings reveal the following: (1) The comprehensive development level showed a fluctuating upward trend, with closeness values ranging from 0.418 to 0.574 in 2020, indicating an improvement of 14.6–52.3% compared to 2011. The coefficient of variation (CV) for each province rose from 12.65% in 2011 to 13.64% and subsequently declined to 9.12% by 2020. (2) Between 2011 and 2020, CCDs of the W–L–E composite system exhibited a consistent upward trend. In 2020, regions with intermediate or better coordination accounted for 34.0%, and were primarily located in Jiangsu Province, the southern part of Anhui Province, the northwestern part of Shandong Province, and the municipalities of Beijing and Tianjin. (3) In 2011 and 2015, significant obstacle factors included the water quality compliance rate and the per capita disposable income of rural residents, although these were not primary obstacles in 2020. The water supply modulus and multiple cropping index were major obstacle factors in 2011, 2015, and 2020. Developing water-appropriate cropping patterns based on regional water resource endowment is the essential path for the sustainable and coordinated development of water, land, and ecology in the NCP. Full article

Background: The use of durable left ventricular assist devices (LVADs) for advanced heart failure is increasing and a growing number of patients will require anesthesia for non-cardiac procedures (NCPs). The goal of this study was to describe our experience with NCPs for LVAD patients. Methods: All anesthetic procedures performed in LVAD patients at a single center were reviewed from 2014 to 2023. Perioperative management data and complications were assessed. Results: In total, 16 patients had an LVAD implanted and 9 (56.3%) patients underwent anesthesia for a total of 22 NCPs. Most of the procedures took place outside of the operating room, mainly in the endoscopy unit, as gastrointestinal endoscopy was the most common procedure (13, 59.2%). Sedation was provided in 17 procedures (77.3%). Standard monitoring was used in all cases, and invasive monitoring was applied just in cases of major surgeries. There were no intraoperative complications reported. Postoperative complications were recorded after eight (36.4%) of the procedures, consisting mainly of lower gastrointestinal bleeding after lower endoscopy, which increased the length of hospital stay. All procedures were performed by non-cardiac anesthesiologists. Conclusions: Our data suggest that, in most cases, adherence to standard anesthesia practices can be suitable for NCPs in LVAD patients. Full article

This paper investigates the effectiveness of Neural Circuit Policies (NCPs) compared to Long Short-Term Memory (LSTM) networks in forecasting time series data for energy production and consumption in the context of predictive maintenance. Utilizing a dataset generated from the energy production and consumption data of a Tuscan company specialized in food refrigeration, we simulate a scenario where the company employs a 60 kWh storage system and calculate the battery charge and discharge policies to assess potential cost reductions and increased self-consumption of produced energy. Our findings demonstrate that NCPs outperform LSTM networks by leveraging underlying physical models, offering superior predictive maintenance solutions for energy consumption and production. Full article

The shortage of water resources seriously limits sustainable production in agriculture, and the ridge–furrow planting pattern is an effective water-saving cultivation pattern. However, the mechanism of the ridge–furrow planting pattern that drives the efficient utilization of field water resources in the North China Plain (NCP) is still unclear. A two-year field experiment was conducted in the NCP from 2021 to 2023. The ridge–furrow planting patterns followed a randomized block design as follows: ridge–furrow ratios of 50 cm:50 cm (M2), 75 cm:50 cm (M3), and 100 cm:50 cm (M4). A traditional planting pattern was used as the control (M1). These were used to investigate the effects of different treatments on water use and roots. The results showed that M3 reduced the amount of irrigation, improved water distribution after irrigation, increased water use efficiency (WUE), and promoted root growth. Compared with other treatments, M3 increased soil water consumption at a 0–100 cm soil depth by 6.76–21.34% (average values over two years), root length density by 8.46–20.77%, and root surface area density by 7.87–22.13%. On average, M3 increased grain yields by 3.96–9.80%, biomass yields by 5.32–10.94%, and WUE by 4.5–9.87%. In conclusion, M3 is an effective planting pattern for improving the yield and WUE of wheat in the NCP. Full article

Quantification of soil water-physical properties and their spatial variation is important to better predict soil structure and functioning, as well as associated spatial patterns in the vegetation. The provision of site-specific soil data further facilitates the implementation of enhanced land use and management practices. Using geostatistical methods, this study quantified the spatial distribution of soil bulk density (SBD), soil moisture (SM), capillary water-holding capacity (CWHC), capillary porosity (CP), non-capillary porosity (NCP), and total porosity (TP) in southern subtropical forests located at the Tropical Forest Research Center in Pingxiang City, China. A topographic map (scale = 1:10,000) was used to create a grid of l km squares across the study area. At the intersections of the grid squares, the described soil water-physical properties were measured. By calculating the coefficient of variation for each soil water-physical property, all measured soil water-physical properties were found to show moderate spatial heterogeneity. Exponential, gaussian, spherical, and linear models were used to fit the semivariograms of the measured soil water-physical properties. Across all soil water-physical properties, the range A₀ variable (i.e., the separation distance between the semivariance and the sill value) measured between 3419 m and 14,156 m. The nugget-to-sill ratio ranged from 9 to 41%, indicating variations in the level of spatial autocorrelation among the soil water-physical properties. Many of the soil water-physical properties were strongly correlated (as assessed using Pearson correlation coefficients). Spatial distribution maps of the soil water-physical properties created via ordinary kriging (OK) showed that most water-physical properties had clumped (aggregated) distributions. SBD showed the opposite spatial pattern to SM and CWHC. Meanwhile, CP and TP showed similar distributions. Full article

To investigate the effects and mechanism of prolonged inorganic nitrogen (N) fertilization on the N-use efficiency of spring wheat (Triticum aestivum L.), a long-term study initiated in 2003 was conducted. The study analyzed how N fertilization affects dry matter translocation, N translocation, soil NO₃-N, and N-use efficiency. Five different N-fertilizer rate treatments were tested: N0, N52.5, N105, N157.5, and N210, corresponding to annual N fertilizer doses of 0, 52.5, 105.0, 157.5, and 210.0 kg N ha⁻¹, respectively. Results showed that increasing N-fertilizer rates significantly enhanced the two-year average dry matter accumulation amount (DMA) at maturity by 22.97–56.25% and pre-flowering crop growth rate (CGR) by 17.11–92.85%, with no significant increase beyond 105 kg N ha⁻¹. However, no significant correlation was observed between the dry matter translocation efficiency (DTE) and wheat grain yield. Both insufficient and excessive N applications resulted in an imbalanced N distribution favoring vegetative growth over reproductive growth, thus negatively impacting N-use efficiency. At maturity, the N-fertilized treatments significantly increased the two-year average N accumulation amount (NAA) by 52.04–129.98%, with no further increase beyond 105 kg N ha⁻¹. N fertilization also improved the two-year average N translocation efficiency (NTE) by 56.89–63.80% and the N contribution proportion (NCP) of wheat vegetative organs by 27.79–57.83%, peaking in the lower-N treatment (N52.5). However, high-N treatment (N210) led to an increase in NO₃-N accumulation in the 0–100 cm soil layer, with an increase of 26.27% in 2018 and 122.44% in 2019. This higher soil NO₃-N accumulation in the 0–100 cm layer decreased NHI, NUE, NAE, NPFP, and NMB. Additionally, N fertilization significantly reduced the two-year average N harvest index (NHI) by 9.89–12.85% and N utilization efficiency (NUE) by 11.14–20.79%, both decreasing with higher N application rates. The NAA followed the trend of anthesis > maturity > jointing. At the 105 kg N ha⁻¹ rate, the highest N agronomic efficiency (NAE) (9.31 kg kg⁻¹), N recovery efficiency (NRE) (38.32%), and N marginal benefit (NMB) (10.67 kg kg⁻¹) were observed. Higher dry matter translocation amount (DTA) and N translocation amount (NTA) reduced NHI and NUE, whereas higher NTE improved NHI, NUE, and N partial factor productivity (NPFP). Overall, N fertilization enhanced N-use efficiency in spring wheat by improving N translocation rather than dry matter translocation. Full article

Long-term excessive use of fertilizers and intensive cultivation not only decreases soil organic carbon (SOC) and productivity, but also increases greenhouse gas emissions, which is detrimental to sustainable agricultural development. The purpose of this paper is to identify organic amendments suitable for winter wheat growth in the North China Plain by studying the effects of organic amendments on the economic benefits, carbon emissions, and carbon sequestration for winter wheat fields and to provide a theoretical basis for the wide application of organic amendments in agricultural fields. The two nitrogen rates were N0 (0 kg ha⁻¹) and N240 (240 kg ha⁻¹), and the four organic amendments were straw, manure, mushroom residue (M R), and biochar. The results showed that, compared to N0, N240 significantly increased the yield by 244.1–318.4% and the organic carbon storage by 16.7–30.5%, respectively, but increased the carbon emissions by 29.3–45.5%. In addition, soil carbon stocks increased with all three types of organic amendments compared to the straw amendment, with the biochar treatment being the largest, increasing carbon storage by 13.3–33.6%. In terms of yield and economic benefits, compared to the straw amendment, the manure and biochar amendments increased winter wheat yields by 0.0–1.5% and 4.0–13.3%, respectively, and M R slightly decreased wheat yield; only the economic benefit of the M R amendment was greater than that of the straw amendment, with an increase in economic benefit of 1.3% and 8.2% in the 2021–2022 and 2022–2023 seasons, respectively. Furthermore, according to the net ecosystem productivity (NEP), N0 was the source of CO₂, while N240 was a sink of CO₂. The TOPSIS results showed that N240 with a mushroom residue amendment could be recommended for increasing soil carbon stocks and economic benefits for winter wheat in the NCP and similar regions. Low-cost M R can increase farmer motivation and improve soil organic carbon, making a big step forward in the spread of organic materials on farmland. Full article

The dry–hot–windy climate frequently occurs during the grain-filling stage of winter wheat on the North China Plain (NCP) and thus negatively influences wheat yield. Sprinkler irrigation can improve field temperature and humidity and can be used to mitigate dry–hot–windy climate disasters. A two-season field experiment was carried out on the NCP to test how sprinkler irrigation influences the microclimate, canopy temperature and photosynthetic traits, as well as the grain-filling process and final grain yield, when spraying 1.5–2 mm of water on dry–hot–windy days. Field experiments revealed that, compared with the no-spraying treatment, spraying with 2 mm of water each time caused the air and canopy temperatures to decrease by 2.3–7.6 °C and 4.3–9.9 °C, respectively, during and just after spraying stopped, and the temperatures returned to their previous levels approximately one hour after spraying. The air humidity increased by up to 10% during and after spraying. The photosynthesis and transpiration rates and the stomatal conductivity after spraying increased by 34–235%, 15–55% and 24–79%, respectively. The linear relationships between photosynthesis rates and transpiration rates with respect to stomatal conductivity suggest that increases in both photosynthesis and transpiration rates are the main contributors to the increase in stomatal conductivity, which is due mainly to the improved canopy temperature and humidity conditions caused by spraying practices. The grain-filling process was improved by spraying, which ultimately increased the unit grain mass by approximately 5%. One spraying event on a dry–hot–windy day influenced the field microclimate and canopy photosynthetic traits for 90 min (30 min in spraying time + 60 min after spraying). When the intensity of the dry–hot–windy climate is strong, two spraying events can be applied. Spraying 2–2.5 mm of water each time was sufficient when the leaf area index was 4–5 during the grain-filling stage of winter wheat. Spray events can have a slight effect on grain yield when a dry–hot–windy climate occurs within the last five days before harvest. Full article

The lack of vertical observation of reactive nitrogen oxides in agricultural areas has posed a significant challenge in fully understanding their sources and impacts on atmospheric oxidation. Ground-based multi-axis differential optical absorption spectroscopy (MAX-DOAS) observations were conducted in the agricultural regions of the North China Plain (NCP) during the summer of 2019 to measure the vertical distributions of aerosols, nitrogen dioxide (NO₂), and nitrous acid (HONO). This study aimed at revealing the spatiotemporal distribution, sources, and environmental effects of reactive nitrogen oxides in the NCP agricultural areas. Our findings indicated that the vertical profiles of aerosols and NO₂ exhibited a near-Gaussian distribution, with distinct peak times occurring between 8:00–10:00 and 16:00–18:00. HONO reached its maximum concentration near the surface around 8:00 in the morning and decreased exponentially with altitude. After sunrise, the concentration of HONO rapidly decreased due to photolysis. Additionally, the potential source contribution function (PSCF) was used to evaluate the potential sources of air pollutants. The results indicated that the main potential pollution sources of aerosols were located in the southern part of the Hebei, Shanxi, Shandong, and Jiangsu provinces, while the potential pollution sources of NO₂ were concentrated in the Beijing–Tianjin–Hebei region. At altitudes exceeding 500 m, the heterogeneous reactions of NO₂ on aerosol surfaces were identified as one of the important contributors to the formation of HONO. Furthermore, we discussed the production rate of hydroxyl radicals (OH) from HONO photolysis. It was found that the production rate of OH from HONO photolysis decreased with altitude, with peaks occurring in the morning and late afternoon. This pattern was consistent with the variations in HONO concentration, indicating that HONO was the main contributor to OH production in the agricultural regions of the NCP. This study provides a new perspective on the sources of active nitrogen in agricultural regions and their contribution to atmospheric oxidation capacity from a vertical perspective. Full article

The Antarctic region harbors abundant natural resources that constitute a common heritage site for humankind. However, given climate change and global resource scarcity, natural resource management has emerged as a pivotal issue in Antarctic governance. Assessing the value of natural resources is fundamental and crucial for ensuring their sustainable utilization and conservation. This study attempted to promote decision-makers’ understanding of the Antarctic using nature’s contribution to people (NCP) and provide an evaluation of the value of natural resources in the Antarctic, thereby contributing to sustainable global development. It developed a conceptual framework for evaluating natural resource values in the NCP, which includes scope delimitation, type identification, and value assessment. Economic value assessments were conducted for key NCPs in Antarctica. Based on existing biological, physical, and economic data, our initial estimates indicate that the economic value of the realized NCP is approximately 2.46 trillion CNY, with regulating NCP accounting for roughly 70% of the total value. If the potential NCP in the Antarctic were realized at foreseeable scientific and technological levels, the total economic value would reach approximately 105.62 trillion CNY. Regulating NCP accounted for most of the total value, but material NCP accounted for more than 20%. Overall, the development of natural resources and environmental protection are two sides of the same coin in the Antarctic, and there may be trade-offs between different NCPs. With increasing human activity, many NCP may be lost in the Antarctic region. This study develops a new perspective on the valuation of nature’s contributions to the Antarctic. The evaluation results can provide scientific evidence for decision-making and management of the development and utilization of natural resources in the Antarctic. Full article

The North China Plain (NCP) serves as the main grain production land in China, functioning as a critical region for ensuring China’s food security. To address the multifaceted challenges confronting food security in the NCP, the study embarked on a comprehensive analysis of the synergistic interactions between agricultural water usage, carbon emissions, and ecosystem health. By proposing footprint family indicators and using the bottom-up IPCC coefficient approach, this study quantitatively evaluates the spatial–temporal changes of water–carbon–ecological footprints in NCP from 2003 to 2020. Furthermore, a coupling coordination degree model that focuses on the coordination of water–carbon–ecological footprints is established. The findings are as follows: (1) The total water footprint in the NCP showed a striking increasing trend with an increase of 1.52 × 10¹¹ m³, and the carbon footprint increased by 1.27 × 10⁹ t, with significant ecological impacts. (2) The NCP’s ecological footprint exhibited an “M”-shaped trend. The land structure maintained stable with negligible changes in the proportion of ecological footprints. (3) The coupling degree between the footprints of water, carbon, and ecology in the NCP is high, revealing a noteworthy interaction effect. This research can provide data support for effective resources allocation and sustainable social–economic development, offering reasonable insights for China to formulate more scientific policies of green transition in land use and ecological civilization construction. Full article

With the recent ban on the production and use of long-chain perfluorinated compounds, the development of alternative approaches to prepare liquid-repellent surfaces that avoids the use of such compounds has become an urgent issue. We have succeeded in the development of fish-mimicking hydrophilic transparent hydrogel-based films with long-lasting anti-oil adhesion properties. Such films could be prepared by simply mixing poly(vinylpyrrolidone) (PVP), nanoclay particles (NCPs), and a waterborne aminosilane (AOS) using an integral blend (IB) method. When submerged in water, these films displayed underwater superoleophobicity (advancing and receding contact angles (CAs) of diiodomethane were ~171°/~163°) with low CA hysteresis (less than 8°), because the hydrophilic nature of the films promoted the formation of a thin layer of adsorbed water on the topmost film surfaces, similar to fish scales. Furthermore, when our films were coated onto the inside of poly(ethylene terephthalate) (PET) bottles and pre-wetted using 80 °C hot water vapors, these film surfaces could effectively repel various oils and were able to maintain their oil-repellent properties for more than 5 weeks. These water-driven, non-perfluorinated transparent hydrogel-based films are expected to increase recycling of PET bottles for oils that are generally incinerated or landfilled. Full article