Search Results (143)

Incorporating insect meals into poultry diets has emerged as a sustainable alternative to conventional feed sources, offering nutritional, welfare benefits, and environmental advantages. This study aims to monitor and compare volatile compounds emitted from raw poultry carcasses and subsequently from cooked chicken pieces from animals fed with different diets, including the utilization of insect-based feed ingredients. Alongside the use of traditional analytical techniques, like solid-phase microextraction combined with gas chromatography-mass spectrometry (SPME-GC-MS), to explore the changes in VOC emissions, we investigate the potential of S3+ technology. This small device, which uses an array of six metal oxide semiconductor gas sensors (MOXs), can differentiate poultry products based on their volatile profiles. By testing MOX sensors in this context, we can develop a portable, cheap, rapid, non-invasive, and non-destructive method for assessing food quality and safety. Indeed, understanding changes in volatile compounds is crucial to assessing control measures in poultry production along the entire supply chain, from the field to the fork. Linear discriminant analysis (LDA) was applied using MOX sensor readings as predictor variables and different gas classes as target variables, successfully discriminating the various samples based on their total volatile profiles. By optimizing feed composition and monitoring volatile compounds, poultry producers can enhance both the sustainability and safety of poultry production systems, contributing to a more efficient and environmentally friendly poultry industry. Full article

Noxious gases such as sulfur-containing compounds can inflict several different adverse effects on human health even when present at extremely low concentrations. The accurate detection of these gases at sub-parts per million levels is imperative, particularly in fields where maintaining optimal air quality is crucial. In this study, we harnessed the capabilities of nanostructured metal-oxide semiconducting materials to detect sulfur dioxide, since they have been extensively explored starting from the last decades for their effectiveness in monitoring toxic gases. We systematically characterized the sensing performance of seven chemoresistive devices. As a result, the SnO₂:Au sensor demonstrated to be the most promising candidate for sulfur dioxide detection, owing to its highly sensitivity (0.5–10 ppm), humidity-independent behavior (30 RH% onwards), and selectivity vs. different gases at an operating temperature of 400 °C. This comprehensive investigation facilitates a detailed performance comparison to other devices explored for the SO₂ sensing, supporting advancements in gas detection technology for enhanced workplace and environmental safety. Full article

New process developments linked to Power to X (energy storage or energy conversion to another form of energy) require tools to perform process monitoring. The main gases involved in these types of processes are H₂, CO, CH₄, and CO₂. Because of the non-selectivity of the sensors, a multi-sensor matrix has been built in this work based on commercial sensors having very different transduction principles, and, therefore, providing richer information. To treat the data provided by the sensor array and extract gas mixture composition (nature and concentration), linear (Multi Linear Regression—Ordinary Least Square “MLR-OLS” and Multi Linear Regression—Partial Least Square “MLR-PLS”) and non-linear (Artificial Neural Network “ANN”) models have been built. The MLR-OLS model was disqualified during the training phase since it did not show good results even in the training phase, which could not lead to effective predictions during the validation phase. Then, the performances of MLR-PLS and ANN were evaluated with validation data. Good concentration predictions were obtained in both cases for all the involved analytes. However, in the case of methane, better prediction performances were obtained with ANN, which is consistent with the fact that the MOX sensor’s response to CH₄ is logarithmic, whereas only linear sensor responses were obtained for the other analytes. Finally, prediction tests performed on one-year aged sensor platforms revealed that PLS model predictions on aged platforms mainly suffered from concentration offsets and that ANN predictions mainly suffered from a drop of sensitivity. Full article

Light and active mobility, as well as multimodal mobility, could significantly contribute to decarbonization. Air quality is a key parameter to monitor the environment in terms of health and leisure benefits. In a possible scenario, wearables and recharge stations could supply information about a distributed monitoring system of air quality. The availability of low-power, smart, low-cost, compact embedded systems, such as Arduino Nicla Sense ME, based on BME688 by Bosch, Reutlingen, Germany, and powered by suitable software tools, can provide the hardware to be easily integrated into wearables as well as in solar-powered EVSE (Electric Vehicle Supply Equipment) for scooters and e-bikes. In this way, each e-vehicle, bike, or EVSE can contribute to a distributed monitoring network providing real-time information about micro-climate and pollution. This work experimentally investigates the capability of the BME688 environmental sensor to provide useful and detailed information about air quality. Initial experimental results from measurements in non-controlled and controlled environments show that BME688 is suited to detect the human-perceived air quality. CO₂ readout can also be significant for other gas (e.g., CO), while IAQ (Index for Air Quality, from 0 to 500) is heavily affected by relative humidity, and its significance below 250 is quite low for an outdoor uncontrolled environment. Full article

Certain biomarkers in exhaled breath are indicators of diseases in the human body. The non-invasive detection of such biomarkers in human breath increases the demand for simple and cost-effective gas sensors to replace state-of-the-art gas chromatography (GC) machines. The use of metal oxide (MOX) gas sensors based on thin-film structures solves the current limitations of breath detectors. However, the response at high humidity levels, i.e., in the case of exhaled human breath, significantly decreases the sensitivity of MOX sensors, making it difficult to detect small traces of biomarkers. We have introduced, in previous work, the concept of a hybrid gas sensor, in which thin-film-based MOX gas sensors are combined with an ultra-thin (20–30 nm) polymer top layer deposited by solvent-free initiated chemical vapor deposition (iCVD). The hydrophobic top layer enables sensor measurement in high-humidity conditions as well as the precise tuning of selectivity and sensitivity. In this paper, we present a way to increase the hydrogen (H₂) sensitivity of hybrid sensors through chemical modification of the polymer top layer. A poly(1,3,5,7-tetramethyl-tetravinylcyclotetrasiloxane) (PV4D4) thin film, already applied in one of our previous studies, is transformed into a silsesquioxane-containing top layer by a simple heating step. The transformation results in a significant increase in the gas response for H₂ ~709% at an operating temperature of 350 °C, which we investigate based on the underlying sensing mechanism. These results reveal new pathways in the biomedical application field for the analysis of exhaled breath, where H₂ indicates gastrointestinal diseases. Full article

Two-dimensional Layered Amorphous Metal Oxide Sensors (LAMOS) represent a new class of 2D amorphous oxide (a-MOx) interfaces with unveiled properties in gas sensing applications. Herein, we report the humidity and gas sensing response of p- and n-type chemoresistive few-layered (2D) amorphous a-SnO₂, a-In₂O₃, and a-Cr₂O₃, discussing their reaction mechanisms using DFT modelling and electrical tests. LAMOS interfaces can be easily prepared by controlled oxidation in air of a large class of exfoliated 2D TMDs, MCs, and TMTH (Transition Metal Dichalcogenides, Chalcogenides, and Trihalides) like WS₂, MoS₂, SnSe₂, In₂Se₃, NiCl₂, and CrCl₃, yielding 2D amorphous a-MOx interfaces. LAMOS platforms preserving all the surface-to-volume advantages of their 2D precursors show excellent gas sensing properties representing a new class of material for gas sensing applications. Full article

This research paper presents a case study on the application of Metal Oxide Semiconductor (MOX)-based VOC/TVOC sensors for indoor air quality (IAQ) monitoring. This study focuses on the ease of use and the practical benefits of these sensors, drawing insights from measurements conducted in a university laboratory setting. The investigation showcases the straightforward integration of MOX-based sensors into existing IAQ monitoring systems, highlighting their user-friendly features and the ability to provide precise and real-time information on volatile organic compound concentrations. Emphasizing ease of installation, minimal maintenance, and immediate data accessibility, this paper demonstrates the practicality of incorporating MOX-based sensors for efficient IAQ management. The findings contribute to the broader understanding of MOX sensor capabilities, providing valuable insights for those seeking straightforward and effective solutions for indoor air quality monitoring. This case study outlines the feasibility and benefits of utilizing MOX-based sensors in various environments, offering a promising avenue for the widespread adoption of user-friendly technologies in IAQ management. Full article

Chemiresistive gas sensors based on metal oxide (MOX) semiconductors are attractive devices used to detect gaseous compounds in many applications. In fluid power systems, they could be exploited to monitor the odor changes of the hydraulic fluid that occur with aging. In this work, an extensive investigation has been performed for many kinds of hydraulic fluids aged in different conditions with the aim to develop a portable device to be installed in every system for performing predictive maintenance increasing system efficiency, reliability, and sustainability. Full article

We developed a new approach to the fabrication of MEMS (Microelectromechanical system) substrates for gas sensors. This full screen-printing approach consists in the application of sacrificial material, which is solid at the near-room temperature of printing and becomes powder after firing of the elements of the sensor and, therefore, can be removed from under the suspended elements of the MEMS structure in an ultrasonic bath. The glass–ceramic MEMS is a cantilever structure equipped with a Pt-based microheater on the end edge with the sensing layer. Screen-printing provides cheap fabrication, robustness, and low power (~120 mW at 450 °C) for the sensing element. Full article

This study was focused on the analysis of the emission of volatile compounds as an indicator of changes in the quality degradation of corn groats with 14% and 17% moisture content (wet basis) using an electronic nose (Agrinose) at changing vertical pressure values. The corn groats were used in this study in an unconsolidated state of 0 kPa (the upper free layer of bulk material in the silo) and under a consolidation pressure of 40 kPa (approximately 3 m from the upper layer towards the bottom of the silo) and 80 kPa (approximately 6 m from the upper layer towards the bottom of the silo). The consolidation pressures corresponded to the vertical pressures acting on the layers of the bulk material bed in medium-slender and low silos. Chromatographic determinations of volatile organic compounds were performed as reference tests. The investigations confirmed the correlation of the electronic nose response with the quality degradation of the groats as a function of storage time. An important conclusion supported by the research results is that, based on the determined levels of intensity of volatile compound emission, the electronic nose is able to distinguish the individual layers of the bulk material bed undergoing different degrees of quality degradation. Full article

This study assesses the agreement in terms of linearity errors between simulated and experimental data from MOX sensors operated in dielectric excitation mode. Both simulated and experimental reactance spectra exhibit high linearity with respect to gas concentration in the high-frequency shoulder of the relaxation peak. The results demonstrate strong agreement between simulated and experimental 95% CI of absolute linearity errors as a function of frequency. As expected, the empirical errors are slightly bigger compared to the simulation prediction, since the latter only considers the linearity errors. The good correspondence between simulations and empirical results supports the use of simulation to optimize the tuning capacitor and the selection of the optimal operating frequency. Full article

Gas sensors based on metal oxide (MOX) semiconductors doped with oxygen vacancies (VO) have many advantages over stoichiometric MOX, such as higher surface reactivity and lower operating temperature. However, preparing reduced MOX is challenging, and the impact of different VO types and concentration on sensing performance is still unclear. In this work, we developed a tailored reducing thermal treatment for creating controlled VO in MOX. The effect of the length and temperature of the treatment was investigated using several characterization methods. Finally, measurements were performed to evaluate the impact of VO type and concentration on reduced MOX sensing performance. Full article

Pseudohexagonal Nb₂O₅ microcolumns spanning a size range of 50 to 610 nm were synthesized utilizing a cost-effective hydrothermal process (maintained at 180 °C for 30 min), followed by a subsequent calcination step at 500 °C for 3 h. Raman spectroscopy analysis unveiled three distinct reflection peaks at 220.04 cm⁻¹, 602.01 cm⁻¹, and 735.3 cm⁻¹, indicative of the pseudohexagonal crystal lattice of Nb₂O₅. The HRTEM characterization confirmed the inter-lattice distance of 1.8 Å for the 110 plain and 3.17 Å for the 100 plain. The conductometry sensors were fabricated by drop-casting a dispersion of Nb₂O₅ microcolumns, in ethanol, on Pt electrodes. The fabricated sensors exhibited excellent selectivity in detecting C₂H₅OH (ΔG/G = 2.51 for 10 ppm C₂H₅OH) when compared to a variety of tested gases, including CO, CO₂, NO₂, H₂, H₂S, and C₃H₆O. The optimal operating temperature for this selective detection was determined to be 500 °C in a dry air environment. Moreover, the sensors demonstrated exceptional repeatability over the course of three testing cycles and displayed strong humidity resistance, even when exposed to 90% relative humidity. This excellent humidity resistance gas sensing property can be attributed to their nanoporous nature and elevated operating temperature. Full article

Background: Total ankle arthroplasty (TAA) has grown in popularity and indications, with encouraging results over time. Today, preoperative and postoperative evaluations are mainly performed using clinical test and diagnostic imaging, but there is a deficiency in objectively evaluating the biomechanics of the foot and ankle, which serve as the functional markers for monitoring the effectiveness and outcomes of surgery. Inertial measurement units associated with plantar pressure measurements may provide an accurate and reliable method of evaluating function through the analysis of gait and ankle joint mobility. The aim of this study was to introduce an innovative technology, to assess its accuracy and feasibility compared to standard clinical assessment methods and to objectify kinematic outcomes in patients with end-stage ankle OA before and after TAA surgery. Methods: A consecutive series of eight patients with symptomatic end-stage osteoarthritis and treated with TAA was prospectively evaluated using clinical scores (AOFAS, MOxFQ, VAS, SF-36, 17-IFFI), physical tests (FPI, ALT), plantar pressure measurements with FLEX EPS/R2 Letsense^® baropodometric platform, gait analysis and wearable sensors-based ankle motion and kinematic outcomes using Wiva Science inertial sensors by Letsense^®. Data were collected preoperatively and 4 months after surgery. Results: All PROMs exhibited statistical significance in improvement from pre- to postoperative periods, except for one. Physical examinations showed no significant changes of the foot shape and alignment. Plantar pressure analyses revealed no significant changes in static and dynamic evaluations, but a more uniform distribution of plantar pressure was observed between the two periods. Inertial sensor parameters demonstrated no significant differences, except for a significant reduction in stride length and step length for the operated foot after surgery. Conclusions: Gait analysis using inertial sensors and plantar pressure measurements offer ease of handling, cost effectiveness, portability and swift data reading, making them highly appealing for widespread clinical use. Integrating these tools into the routine assessments of patients with TAA holds promise for advancing precision of treating this condition and our depth of its understanding, contributing to more comprehensive and insightful patient care. Full article

ZnO thin films with a thickness of 300 nm were deposited on Si and Al₂O₃ substrates using an electron beam evaporation technique with the aim of testing them as low cost and low power consumption gas sensors for ozone (O₃). Scanning electron microscopy and atomic force microscopy were used to characterize the film surface morphology and quantify the roughness and grain size, recognized as the primary parameters influencing the gas sensitivity due to their direct impact on the effective sensing area. The crystalline structure and elemental composition were studied through Raman spectroscopy and X-ray photoelectron spectroscopy. Gas tests were conducted at room temperature and zero-bias voltage to assess the sensitivity and response as a function of time of the films to O₃ pollutant. The results indicate that the films deposited on Al₂O₃ exhibit promising characteristics, such as high sensitivity and a very short response time (<2 s) to the gas concentration. Additionally, it was observed that the films display pronounced degradation effects after a significant exposure to O₃. Full article