Research on the Influence of a Magnesium-Based Carbon Dioxide Battery System on CO2 Storage Performance
Abstract
:1. Introduction
2. Materials and Methods
2.1. The Reaction Mechanism of the Mg-CO2 Battery
2.2. Preparation of CO2 Battery Materials
- (1)
- CeO2 carrier preparation
- (2)
- Pd/CeO2 catalyst preparation
- (3)
- Pd/CeO2 cathode coating
2.3. Characterization
3. Results and Discussion
3.1. The Effect of the Catalytic Electrode on the Conversion Efficiency of Mg-CO2 Batteries with Molecules
3.2. The Effect of the Electrolyte Concentration on the Conversion Efficiency of the CO2 Molecules
3.3. The Effect of CO2 Flow Change on the Conversion Efficiency of CO2 Molecules
3.4. CO2 Battery System Performance Analysis
3.5. Characterization of Catalyst Structure
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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No. | Item | Chemistry | Specifications | Manufacturer |
---|---|---|---|---|
1 | Palladium nitrate | Pd(NO3)2·2H2O | 17.27 wt% | Guyan chem., Kunming, China |
2 | Cerium(III) nitrate | Ce(NO3)3·6H2O | AR | Macklin, Shanghai, China |
3 | Potassium hydroxide | KOH | 95% | Macklin, Shanghai, China |
4 | Sodium hydroxide | NaOH | 95% | Macklin, Shanghai, China |
5 | Carbon dioxide | CO2 | 99.999% | Peric, Handan, China |
6 | Nafion perfluorinated resin solution | - | 5 wt% | Macklin, Shanghai, China |
7 | Ethanol | CH3CH2OH | 99.5% | Macklin, Shanghai, China |
8 | Porous carbon nanotube | C | 97.5% | Macklin, Shanghai, China |
9 | VulcanXC-72 Carbon Black | C | 99.5% | CABOT, Boston, MA, USA |
10 | Magnesium flake | Mg | - | Huabei Metal, Wuxi, China |
11 | Nickel Foam Sheet | Ni | - | Suzhou Metal, Suzhou, China |
12 | Polyvinylpyrrolidone | PVP | AR | Macklin, Shanghai, China |
13 | Trisodium phosphate | Na3PO4 | 96% | Macklin, Shanghai, China |
NaOH Concentration (mol/L) | CO2 Flow Rate (L/h) | Complete Reaction Generation NaHCO3 Time (min) |
---|---|---|
0.5 | 1 | 107.52 |
0.1 | 21.50 | |
0.05 | 10.75 |
CO2 Traffic (L/h) | NaOH Potency (mol/L) | Complete Reaction Time to Generate NaHCO3 (min) |
---|---|---|
0.5 | 0.05 | 21.5 |
1 | 10.75 | |
1.5 | 7.17 |
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Yang, H.; Wei, M.; Wang, B.; Wang, L.; Chen, Q.; Su, C.; Feng, Y.; Wang, X.; Li, K. Research on the Influence of a Magnesium-Based Carbon Dioxide Battery System on CO2 Storage Performance. Processes 2024, 12, 1896. https://doi.org/10.3390/pr12091896
Yang H, Wei M, Wang B, Wang L, Chen Q, Su C, Feng Y, Wang X, Li K. Research on the Influence of a Magnesium-Based Carbon Dioxide Battery System on CO2 Storage Performance. Processes. 2024; 12(9):1896. https://doi.org/10.3390/pr12091896
Chicago/Turabian StyleYang, Haoran, Mian Wei, Baodong Wang, Leqi Wang, Qiuyan Chen, Chang Su, Yongcheng Feng, Xing Wang, and Ke Li. 2024. "Research on the Influence of a Magnesium-Based Carbon Dioxide Battery System on CO2 Storage Performance" Processes 12, no. 9: 1896. https://doi.org/10.3390/pr12091896