Revision date: 10/24/2022 Revision: 7.

SAFETY DATA SHEET

BELZONA® 5851 (HA-BARRIER)

1. Identification

Product identifier
Product name BELZONA® 5851 (HA-BARRIER)

Product number SN2368

Recommended use of the chemical and restrictions on use

Application Heat activated corrosion resistant coating. For industrial use only.

Uses advised against The product should not be used for purposes other than those recommended in the
appropriate Instructions For Use (IFU) leaflet.

Details of the supplier of the safety data sheet

Supplier Belzona Inc. Belzona Great Lakes
14300 NW 60th Ave. 588 Edward Avenue, Unit 51
Miami Lakes Richmond Hill
FL 33014 Ontario, L4C 9W7
UNITED STATES CANADA
1-305-594-4994 1-905-737-2225
[email protected] [email protected]

Manufacturer Belzona Polymerics Limited

Claro Road, Harrogate
HG1 4DS
United Kingdom
+44 1423 567641
[email protected]

Emergency telephone number

Emergency telephone VelocityEHS: +1 813-248-0585

2. Hazard(s) identification

Classification of the substance or mixture

OSHA Regulatory Status This Product is Hazardous under the OSHA Hazard Communication Standard.

Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2B - H320 Skin Sens. 1 - H317

Reference The full text for all hazard statements is displayed in Section 16.

Label elements

Hazard symbols

Signal word Warning

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Hazard statements H315+H320 Causes skin and eye irritation.

H317 May cause an allergic skin reaction.

Precautionary statements P260 Do not breathe vapors.

P264 Wash contaminated skin thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of the workplace.
P280 Wear protective gloves, protective clothing and eye protection.
P302+P352 If on skin: Wash with plenty of water.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P337+P333+P313 If skin irritation or rash occurs or eye irritation persists: Get medical
attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents/container in accordance with all Federal, State/Provincial and local
regulations.

Contains BISPHENOL F- EPOXY RESIN, BIS[4-(2,3-EPOXYPROPOXY)PHENYL]PROPANE

Other hazards
Not applicable.

Hazards not otherwise Not applicable.

classified (HNOC)

3. Composition/information on ingredients

Mixtures

BISPHENOL F- EPOXY RESIN 10-30%

CAS number: 9003-36-5

BIS[4-(2,3-EPOXYPROPOXY)PHENYL]PROPANE 5-10%
CAS number: 1675-54-3

4. First-aid measures

Description of first aid measures

General information In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything
by mouth to an unconscious person.

Inhalation Remove to fresh air. Keep the patient warm and at rest. Give nothing by mouth.

Ingestion If accidentally swallowed obtain immediate medical attention. Keep at rest. Rinse mouth with
plenty of water. Do NOT induce vomiting.

Skin Contact Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
a proprietary skin cleaner. Do NOT use solvents or thinners. If irritation or inflammation
persists, seek medical attention.

Eye contact Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 15
minutes, holding the eyelids apart, and seek medical advice.

Most important symptoms and effects, both acute and delayed

Skin contact Prolonged or repeated contact with the skin or mucous membrane may result in irritant
symptoms such as redness, blistering or dermatitis. Onset of symptoms may be delayed. May
cause an allergic skin reaction.

Eye contact Irritating to eyes.

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Indication of immediate medical attention and special treatment needed

Notes for the doctor None.

5. Fire-fighting measures

Extinguishing media
Suitable extinguishing media Use: sand, alcohol resistant foam, carbon dioxide, chemical powder, or water fog for larger
fires.
Do NOT use water jet.

Special hazards arising from the substance or mixture

Flammability Class 3.2 Combustible Liquid IIIB

Hazardous combustion In a fire, hazardous decomposition products such as smoke, carbon monoxide and carbon
products dioxide may be produced.

Advice for firefighters

Protective actions during Fire will produce dense black smoke containing hazardous products of combustion. Exposure
firefighting to decomposition products may be a hazard to health. Appropriate positive-pressure self-
contained breathing apparatus (SCBA) and full fire fighting turn-out gear (Bunker gear) should
be worn. Cool closed containers exposed to fire with water spray. Do not allow run-off from
fire fighting to enter drains, sewers, ditches or waterways.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

Personal precautions Exclude non-essential personnel. Do not get on skin or in eyes.

Environmental precautions
Environmental precautions Prevent product entering drains or sewers. In the event of a spill or accidental release, notify
relevant authorities in accordance with all applicable regulations.

Methods and material for containment and cleaning up

Methods for cleaning up Scrape the majority of the product into a suitable labeled container. Clean surfaces down with
a water and detergent mixture. Do not allow to enter drains or watercourses.

Reference to other sections For personal protection, see Section 8. For waste disposal, see section 13. .

7. Handling and storage

Precautions for safe handling

Usage precautions Keep the container tightly closed when not in use. Vapors may collect in the container
headspace during transit or prolonged storage. Do not breathe vapor when opening the
container. Where possible open containers in a well ventilated place away from the
application area. Do not get on skin or in eyes. Smoking, eating and drinking should be
prohibited in areas of storage and use. For personal protection see Section 8. Exclude non-
essential personnel. Minimise the number of employees exposed and the duration of their
exposure. Always keep in containers made of the same material as the supply container.
FIRE/EXPLOSION This product is combustible. Exclude sources of heat, sparks and open
flame. Good housekeeping standards and regular safe removal of waste materials will
minimise the risks of spontaneous combustion and other fire hazards. SPECIAL This product
should not be applied where substrate temperatures exceed 150°C (302°F). Do not breathe
vapors/mists.

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Advice on general Wash at the end of each work shift and before eating, smoking and using the toilet. Ensure
occupational hygiene eye wash facilities (fountain, bottle, vials, etc.) are readily available. Do not put contaminated
articles or equipment e.g. spatulas, applicators, brushes, cloths etc., into pockets. Where
necessary, contaminated work clothing and shoes should be removed to prevent cross
contamination of surfaces and the risk of inadvertent skin contact and ingestion.

Conditions for safe storage, including any incompatibilities

Storage precautions Observe the label precautions. Store cool, preferably refrigerated, between 5°C (41°F) and
20°C (68°F) unless otherwise stated in a dry, well ventilated place away from sources of heat,
ignition and direct sunlight. No smoking. Prevent unauthorized access. Containers that are
opened should be properly resealed and kept upright. Store separately from oxidizing agents
and strongly alkaline and strongly acidic materials. ENVIRONMENTAL STORAGE
PRECAUTIONS Spillage, incorrect storage of chemicals or waste materials or unsuitable
disposal activities can result in pollutants seeping through the soil, causing serious harm to
groundwater- which is a vital source of drinking water. All wastes, especially liquid wastes,
should be securely stored on site in designated areas that are isolated from waterways and
groundwater and diked to contain any spillages.

Specific end uses(s)

Specific end use(s) Application by short bristled brush. Single component material. This product does not require
mixing with another component before use. Please refer to the relevant Belzona® Instructions
For Use for further information.

8. Exposure controls/Personal protection

Control parameters
Occupational exposure limits
No exposure limits known for ingredient(s).

Exposure controls
Appropriate engineering Open containers in a well ventilated area. Use in well ventilated areas or provide adequate
controls mechanical ventilation. Where reasonably practicable adequate ventilation should be
achieved by the use of local exhaust ventilation and good general extraction.

Eye/face protection It is recommended that eye protection, for example safety glasses with side shields or goggles
are worn at all times during the handling and use of this material. .

Hand protection . The breakthrough time of the gloves selected should exceed the expected use period.
Where this is not possible, gloves should be changed in good time, and in any case before the
breakthrough time is exceeded. Where doubt exists, advice should be sought from
manufacturers or vendors of protective gloves in order to determine appropriate types for the
particular circumstances. Barrier creams may help to protect exposed areas of skin but are
not substitutes for full physical protection. They should not be applied once exposure has
occurred. SPECIFIC RECOMMENDATIONS Wear protective gloves made of the following
material: Nitrile rubber. STANDARD APPLICATIONS / EMERGENCY SITUATIONS Medium-
heavy weight gauntlet type gloves that provide wrist protection are suitable.

Other skin and body STANDARD APPLICATIONS Synthetic polyethylene coveralls such as the Tyvek PRO-
protection TECH® or equivalent coveralls manufactured to provide protection against liquid chemicals
should be worn. Grossly contaminated clothing should be removed and the skin washed with
soap and water or a proprietary skin cleaner.

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Respiratory protection Respiratory protection complying with an approved standard should be worn if a risk
assessment indicates inhalation of contaminants is possible. Respirator selection must be
based on exposure levels, the hazards of the product and the safe working limits of the
selected respirator. It is essential that the concentration of the contaminant(s) in the
application environment does not exceed the applicable occupational exposure limit(s)
multiplied by the Assigned Protection Factor (APF) quoted for the respiratory protective
equipment selected. Respirators are not normally required, but may be required when this
product is used in confined spaces or where adequate ventilation cannot be achieved. Where
necessary, it is recommended that an OSHA/NIOSH approved air-purifying full facepiece or
half-face respirator equipped with appropriate vapor cartridge(s) should be worn. Where the
application environment is likely to be contaminated by significant concentrations of dust then
the appropriate particulate prefilter (N-, R- or, P-series) should be worn in combination with
the above. It is essential that the facepiece is correctly fitted and the filter is changed in
accordance with the manufacturer's instructions. In confined or poorly-ventilated spaces, a
supplied-air respirator must be worn.

Immediate danger to life and Where entry into unknown or Immediately Dangerous To Life or Health (IDLH) atmospheres is
health required, an OSHA/NIOSH approved pressure-demand self-contained breathing apparatus
(SCBA) with a full facepiece or a pressure-demand supplied-air respirator (SAR) with a full
facepiece in combination with an auxiliary pressure-demand SCBA respirator should be worn.

9. Physical and chemical properties

Information on basic physical and chemical properties

Appearance Paste.

Color Grey.

Odor Odorless or no characteristic odor.

Odor threshold Not applicable.

pH Not applicable.

Melting point Not available.

Initial boiling point and range >200°C/>392°F @ 760 mm Hg

Flash point Not available.

Evaporation rate Not available.

Flammability (solid, gas) Not applicable.

Upper/lower flammability or Not applicable.

explosive limits

Vapor pressure ~0.08 kPa @ 20°C/68°F

Vapor density >1

Relative density 1.95 - 2.05 @ 20°C/68°F

Solubility(ies) Immiscible with water.

Partition coefficient Not available.

Auto-ignition temperature >180°C/>356°F

Decomposition Temperature >200°C/>392°F

Viscosity Technically not feasible.

Explosive properties Not applicable.

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Oxidizing properties Not applicable.

Other information This section contains typical values for Health, Safety and Environmental guidance only and is
not intended to represent a technical specification for the product.

10. Stability and reactivity

Reactivity There are no known reactivity hazards associated with this product.

Stability Stable under recommended storage and handling conditions (see Section 7).

Possibility of hazardous No hazardous reactions expected when stored and handled as recommended.
reactions

Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

Materials to avoid Keep away from oxidizing agents and strongly alkaline and strongly acidic materials to
prevent the possibility of exothermic reaction.

Hazardous decomposition Does not decompose when used and stored as recommended.
products

11. Toxicological information

Information on toxicological effects

Acute toxicity - oral
Notes (oral LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - dermal

Notes (dermal LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - inhalation

Notes (inhalation LC₅₀) Based on available data the classification criteria are not met.

Skin corrosion/irritation
Animal data Irritating to skin.

Serious eye damage/irritation

Serious eye damage/irritation Irritating to eyes.

Respiratory sensitization
Respiratory sensitization Based on available data the classification criteria are not met.

Skin sensitization
Skin sensitization Based on the properties of the epoxy constituent(s) and considering toxicological data on
similar preparations, this preparation may be a skin sensitizer. Repeated skin contact may
lead to sensitization with possibly cross-sensitization to other epoxies.

Germ cell mutagenicity

Genotoxicity - in vitro Based on available data the classification criteria are not met.

Genotoxicity - in vivo Based on available data the classification criteria are not met.

Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.

IARC carcinogenicity Not listed.

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NTP carcinogenicity Not listed.

OSHA Carcinogenicity Not listed.

Reproductive toxicity
Reproductive toxicity - fertility Based on available data the classification criteria are not met.

Reproductive toxicity - Based on available data the classification criteria are not met.
development

Specific target organ toxicity - single exposure

STOT - single exposure Based on available data the classification criteria are not met.

Specific target organ toxicity - repeated exposure

STOT - repeated exposure Based on available data the classification criteria are not met.

Aspiration hazard
Aspiration hazard Based on available data the classification criteria are not met.

Route of exposure Skin and/or eye contact

Medical considerations Skin contact constitutes a pronounced hazard. Persons with a history of skin sensitization
problems should only be employed in processes in which this product is used under
appropriate medical supervision.

Toxicological information on ingredients.

BIS[4-(2,3-EPOXYPROPOXY)PHENYL]PROPANE

Toxicological effects Repeated skin contact may lead to sensitization with possibly cross-sensitization to
other epoxies. In rare cases, low molecular weight liquid epoxy resins can cause an
allergic respiratory reaction like asthma, based on limited human information. The
evidence available is not however, considered to fall within the classification criteria
as laid out within the OSHA Hazard Communication Standard nor the Controlled
Products Regulations.

12. Ecological information

Ecotoxicity There is no data on the product itself. The following information is provided on the basis of the
individual component data available.

Toxicity Based on the epoxy resin content, this product is expected to have experimental
LC50/EC50/IC50 values between 1 and 10 mg/l in most sensitive species.

Persistence and degradability

Persistence and degradability Based on the epoxy resin content, this product is not expected to be rapidly biodegradable
according to OECD/EC guidelines.

Bioaccumulative potential
Bio-Accumulative Potential Based on the epoxy resin content, this product is expected to bioaccumulate.

Partition coefficient Not available.

Mobility in soil
Mobility There is no data available on the product itself.

Other adverse effects

Other adverse effects None known.

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13. Disposal considerations

Waste treatment methods

Disposal methods Do NOT dump into any sewers, on the ground, or into any body of water. Controlled wastes
include non-hazardous industrial and hazardous chemical wastes. Disposal must be in
compliance with all Federal, State/Provincial and local laws and regulations. Regulations may
vary in different locations. Waste characterizations are the responsibility solely of the waste
generator. . . COMPONENT DISPOSAL TRANSIT PACKAGING: shrink or stretch wrap,
boxes and fittings that have not been contaminated with product should be re-used or
recycled. UNREACTED PRODUCT, uncleaned containers and contaminated packaging may
qualify as hazardous chemical waste as defined in 40 CFR 261.20-24.

Waste class . . Waste class is not relevant. .

14. Transport information

General This product is not regulated for transport by US DOT, and qualifies for exemption (TDG
1.45.1) if shipped on land in Canada. Labeling and packaging requirements may vary with
pack and load size. Please refer to the current transport regulations. Transport within user's
premises: always transport in closed containers that are upright and secure. Ensure that
persons transporting the product know what to do in the event of accident or spillage.

UN Number
UN No. (TDG) 3082

UN No. (IMDG) 3082

UN No. (ICAO) 3082

UN No. (DOT) Not applicable.

UN proper shipping name

Proper shipping name (TDG) Environmentally hazardous substance, liquid, n.o.s. (containing Epoxy resin mixture)

Proper shipping name (IMDG) Environmentally hazardous substance, liquid, n.o.s. (containing Epoxy resin mixture)

Proper shipping name (ICAO) Environmentally hazardous substance, liquid, n.o.s. (containing Epoxy resin mixture)

Proper shipping name (DOT) Not applicable.

Transport hazard class(es)

DOT hazard class Not applicable.

TDG class 9

IMDG Class 9

ICAO class/division 9

Packing group
TDG Packing Group III

IMDG packing group III

ICAO packing group III

DOT packing group Not applicable.

Environmental hazards

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Environmentally Hazardous Substance

Yes. Not a marine pollutant under US DOT.

Special precautions for user

Not applicable.

Transport in bulk according to Not carried in bulk.

Annex II of MARPOL 73/78
and the IBC Code

15. Regulatory information

National regulations
The provisions of the Health and Safety at Work Act and the Control of Substances
Hazardous to Health Regulations with amendments apply to the use of this product at work.

US Federal Regulations
SARA 313 Emission Reporting
SECTION 313: This product does not contain toxic chemical subject to the reporting requirements of Section 313 of Title III
of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR Part 372.

SARA (311/312) Hazard Categories

Acute

US State Regulations
State Regulations Comments U.S California Safe Drinking Water & Toxic Enforcement Act (Proposition 65): WARNING:
This product contains a chemical known to the State of California to cause birth defects or
other reproductive harm.

Inventories
Canada - DSL/NDSL
All the ingredients are listed or exempt.

US - TSCA
All the ingredients are listed or exempt.

16. Other information

General information The information contained within this safety data sheet does not constitute the users own
assessment of workplace risks as may be required by other Local Regulations. As the specific
conditions of use of the product are outside the supplier's control, the user is responsible for
ensuring that the requirements of relevant Local Regulations are complied with. To the best of
our knowledge, the information contained herein is accurate. However, some of the
information presented and conclusions drawn are derived from sources other than direct test
data on the product itself and while Belzona Inc. believes such sources to be reliable, the
information is provided without any warranty regarding its correctness.
Since Belzona Inc. has no control over the conditions under which the product will be used,
liability will not be assumed to exceed replacement or refund of the purchase price of this
product. Except as stated herein, there are no express or implied warranties including implied
warranties of merchantability or fitness for a particular purpose. Belzona Inc. assumes no
liability for injury or incidental or consequential damage arising out of the storage, handling,
use or, disposal of this product.

Key literature references and .......

sources for data

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Training advice For further information please contact your supplier, Belzona consultant or Belzona direct.

Revision comments REVISION. This safety data sheet has been revised in the following Section(s): 1, 2, 3, 5, 6,
7, 8, 11, 12, 15, Please observe the REVISION DATE. Should you be reading a material
safety data sheet that is more than 24 months old or have concerns over its validity, please
contact your local Belzona Distributor or Belzona direct ([email protected]) and the most
current information will be sent to you.

Revision date 10/24/2022

Revision 7.5

SDS No. 10791

SDS status English (North American). Approved.

Hazard statements in full H315 Causes skin irritation.

H317 May cause an allergic skin reaction.
H320 Causes eye irritation.

NFPA - health hazard Irritation, minor residual injury. (1)

NFPA - flammability hazard Burns only if pre-heated. (1)

NFPA - instability hazard Normally stable. (0)

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