Jump to content

Potassium iodate: Difference between revisions

From Wikipedia, the free encyclopedia
Content deleted Content added
Monkbot (talk | contribs)
m Radiation protection: Task 16: replaced (3×) / removed (0×) deprecated |dead-url= and |deadurl= with |url-status=;
Radiation protection: change link to ireland the country not the island
Tags: Mobile edit Mobile web edit Advanced mobile edit
 
(26 intermediate revisions by 16 users not shown)
Line 10: Line 10:
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 22856
| ChemSpiderID = 22856
| DrugBank = DB15923
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = I139E44NHL
| UNII = I139E44NHL
Line 31: Line 32:
| Odor = odorless
| Odor = odorless
| Density = 3.89 g/cm<sup>3</sup>
| Density = 3.89 g/cm<sup>3</sup>
| Solubility = 4.74 g/100 mL (0 °C) <br> 9.16 g/100 mL (25 °C) <br> 32.3 g/100 mL (100 °C)
| Solubility = 4.74 g/100 mL (0 °C) <br /> 9.16 g/100 mL (25 °C) <br /> 32.3 g/100 mL (100 °C)
| SolubleOther = soluble in [[potassium iodide|KI]] solution <br> insoluble in [[ethanol|alcohol]], liquid [[ammonia]], [[nitric acid]]
| SolubleOther = soluble in [[potassium iodide|KI]] solution <br /> insoluble in [[ethanol|alcohol]], liquid [[ammonia]], [[nitric acid]]
| MeltingPtC = 560
| MeltingPtC = 560
| MeltingPt_notes = (decomposes)
| MeltingPt_notes = (decomposes)
Line 39: Line 40:
|Section7={{Chembox Hazards
|Section7={{Chembox Hazards
| ExternalSDS =
| ExternalSDS =
| RPhrases = {{R9}}, {{R22}}, {{R36}}, {{R37}}, {{R38}}
| GHSPictograms = {{GHS03}} {{GHS05}} {{GHS07}}
| SPhrases = {{S35}}
| HPhrases = {{H-phrases|272|302|318}}
| PPhrases = {{P-phrases|210|280|301+312+330|305+351+338+310}}
| NFPA-H = 2
| NFPA-H = 2
| NFPA-F = 0
| NFPA-F = 0
Line 48: Line 50:
}}
}}
|Section8={{Chembox Related
|Section8={{Chembox Related
| OtherAnions = [[Potassium chlorate]]<br/>[[Potassium bromate]]
| OtherAnions = [[Potassium chlorate]]<br />[[Potassium bromate]]
| OtherCations = [[Sodium iodate]]
| OtherCations = [[Sodium iodate]]
| OtherCompounds = [[Potassium iodide]]<br/>[[Potassium periodate]]
| OtherCompounds = [[Potassium iodide]]<br />[[Potassium periodate]]
}}
}}
}}
}}
'''Potassium iodate''' ([[Potassium|K]][[Iodine|I]][[Oxygen|O<sub>3</sub>]]) is a [[chemical compound]]. It is [[Ionic compound|ionic]], made up of K<sup>+</sup> ions and IO<sub>3</sub><sup>−</sup> ions in a 1:1 ratio.
'''Potassium iodate''' ([[Potassium|K]][[Iodine|I]][[Oxygen|O<sub>3</sub>]]) is an [[ionic compound|ionic]] [[inorganic compound]] with the formula {{chem2|KIO3}}. It is a white salt that is soluble in water.<ref name=":0"/>


==Preparation and properties==
==Preparation and properties==
It can be prepared by reacting a potassium-containing base such as [[potassium hydroxide]] with [[iodic acid]], for example:<ref name=":0">{{Cite encyclopedia |title=Iodine and Iodine Compounds |encyclopedia=Ullmann's Encyclopedia of Industrial Chemistry |publisher=Wiley-VCH |location=Weinheim |last1=Lyday |first1=Phyllis&nbsp;A. |editor-last=Ley |editor-first=Claudia |publication-date=26 November 2015 |edition=7th |page=9 |doi=10.1002/14356007.a14_381.pub2 |last2=Kaiho Tatsuo|isbn=9783527306732 }}</ref>
Potassium iodate is an [[oxidizing agent]] and as such it can cause fires if in contact with combustible materials or [[reducing agents]]. It can be prepared by reacting a potassium-containing base such as [[potassium hydroxide]] with [[iodic acid]], for example:


:{{math|[[Iodic acid|HIO<sub>3</sub>]] + [[Potassium hydroxide|KOH]] → KIO<sub>3</sub> + [[Water|H<sub>2</sub>O]]}}
:[[Iodic acid|HIO<sub>3</sub>]] + [[Potassium hydroxide|KOH]] → KIO<sub>3</sub> + [[Water|H<sub>2</sub>O]]


It can also be prepared by adding [[iodine]] to a hot, concentrated solution of potassium hydroxide.
It can also be prepared by adding [[iodine]] to a hot, concentrated solution of potassium hydroxide:<ref name=":0" />


:{{math|3 [[iodine|I<sub>2</sub>]] + 6 [[Potassium hydroxide|KOH]] → KIO<sub>3</sub> + 5 [[potassium iodide|KI]] + 3 [[water|H<sub>2</sub>O]]}}
:3 [[iodine|I<sub>2</sub>]] + 6 [[Potassium hydroxide|KOH]] → KIO<sub>3</sub> + 5 [[potassium iodide|KI]] + 3 [[water|H<sub>2</sub>O]]


Or by fusing potassium iodide with [[potassium chlorate]], [[potassium bromate|bromate]] or [[potassium perchlorate|perchlorate]], the melt is extracted with water and potassium iodate is isolated from the solution by crystallization:<ref>Pradyot Patnaik. ''Handbook of Inorganic Chemicals''. McGraw-Hill, 2002, {{ISBN|0-07-049439-8}}</ref>
Or by fusing potassium iodide with [[potassium chlorate]], [[potassium bromate|bromate]] or [[potassium perchlorate|perchlorate]], the melt is extracted with water and potassium iodate is isolated from the solution by crystallization:<ref>Pradyot Patnaik. ''Handbook of Inorganic Chemicals''. McGraw-Hill, 2002, {{ISBN|0-07-049439-8}}</ref>
:{{math|KI + KClO<sub>3</sub> → KIO<sub>3</sub> + KCl}}
:KI + KClO<sub>3</sub> → KIO<sub>3</sub> + KCl


The analogous reaction with [[potassium hypochlorite]] is also possible:<ref>{{Cite journal |last=Andrews |first=Launcelot&nbsp;W. |date=July 1903 |title=Titrations with potassium iodide |url=https://babel.hathitrust.org/cgi/pt?id=uc1.%24b811386&seq=113 |journal=[[Journal of the American Chemical Society]] |location=[[Easton, Pennsylvania]] |publisher=[[US Postal Service]] |volume=25 |issue=7 |page=756 |doi=10.1021/ja02009a012 |via=[[HathiTrust]]}}</ref><blockquote>KI + 3KOCl → 3KCl + KIO<sub>3</sub></blockquote>Conditions/substances to avoid include: [[heat]], [[Shock (mechanics)|shock]], [[friction]],<ref name=":1">{{Cite web |last=Regulatory Affairs |date=23 March 2023 |title=Safety Data Sheet |url=https://www.fishersci.com/store/msds?partNumber=AC418245000&productDescription=POTASSIUM+IODATE%2C+REAGEN+500GR&vendorId=VN00033901&countryCode=US&language=en |url-status=live |archive-url=https://web.archive.org/web/20230922143106/https://www.fishersci.com/store/msds?partNumber=AC418245000&productDescription=POTASSIUM+IODATE%2C+REAGEN+500GR&vendorId=VN00033901&countryCode=US&language=en |archive-date=22 September 2023 |access-date=22 September 2023 |publisher=[[Thermo Fisher Scientific]] |type=Potassium iodate MSDS |publication-place=[[Fair Lawn, NJ]] |edition=5}}</ref> combustible materials,<ref name=":0" /> reducing materials, [[aluminium]],<ref name=":1" /> [[organic compounds]],<ref name=":0" /> [[carbon]], [[hydrogen peroxide]] and [[sulfide]]s.<ref name=":1" />
Conditions/substances to avoid include: [[heat]], [[Shock (mechanics)|shock]], [[friction]], combustible materials, reducing materials, [[aluminium]], [[organic compounds]], [[carbon]], [[hydrogen peroxide]] and [[sulfide]]s.


==Applications==
==Applications==
Potassium iodate is sometimes used for iodination of table salt to prevent [[iodine deficiency]]. In the US, [[Iodised salt|iodized salt]] contains [[antioxidant]]s, because [[atmospheric oxygen]] can oxidize [[Aqueous solution|wet]] iodide to iodine; other countries simply use potassium iodate instead.<ref>{{Cite journal |last1=Arroyave |first1=Guillermo |last2=Pineda |first2=Oscar |last3=Scrimshaw |first3=Nevin&nbsp;S. |date=1956 |orig-date=May 1955 |title=The stability of potassium iodate in crude table salt |journal=[[Bulletin of the World Health Organization]] |volume=14 |issue=1 |pages=183–185 |pmid=13329845 |pmc=2538103}}</ref> Salt mixed with [[ferrous fumarate]] and potassium iodate, "double fortified salt", are used to address both iron and iodine deficiencies.<ref>{{cite journal |doi=10.1111/mcn.12773 |title=Improving the lives of millions through new double fortification of salt technology |date=2019 |last1=Diosady |first1=Levente L. |last2=Mannar |first2=M.G. Venkatesh |last3=Krishnaswamy |first3=Kiruba |journal=Maternal & Child Nutrition |volume=15 |issue=Suppl 3 |pages=e12773 |pmid=31148400 |pmc=6594086 }}</ref> Potassium iodate is also used to provide iodine in some [[Infant formula|baby formula]].<ref>{{Cite web |last=James |first=Maia |date=2023-04-04 |title=Best Baby Formula Guide |url=https://gimmethegoodstuff.org/safe-product-guides/safe-infant-formula-guide/ |access-date=2023-09-22 |website=Gimme the Good Stuff |language=en-US}}</ref>
Potassium iodate is sometimes used for iodination of table salt to prevent [[iodine deficiency]]. Because iodide can be oxidized to iodine by molecular oxygen under wet conditions, US companies add [[thiosulfate]]s or other [[antioxidant]]s to the potassium iodide. In other countries, potassium iodate is used as a source for dietary iodine. It is also an ingredient in some [[Infant formula|baby formula]] milk.


Like [[potassium bromate]], potassium iodate is occasionally used as a [[Flour treatment agent|maturing agent]] in baking.
Like [[potassium bromate]], potassium iodate is occasionally used as a [[Flour treatment agent|maturing agent]] in baking.<ref>{{Cite encyclopedia |title=Potassium iodate |encyclopedia=BAKERpedia |location=[[Portland, OR]] |url=https://bakerpedia.com/ingredients/potassium-iodate/ |access-date=22 September 2023 |editor-last=Carson |editor-first=Lin}}</ref>


===Radiation protection===
===Radiation protection===
[[Image:Potassium iodate tablets.jpg|thumb|left|An unopened box of potassium [[iodate]] tablets distributed in the early 2000s to [[Republic of Ireland|Irish]] households in case of a terror attack on [[United Kingdom|British]] nuclear facilities.]]
Potassium iodate may be used to protect against accumulation of [[radioiodine|radioactive iodine]] in the [[thyroid]] by saturating the body with a stable source of [[iodine]] prior to exposure.<ref>{{Citation
Potassium iodate may be used to protect against accumulation of [[radioiodine|radioactive iodine]] in the [[thyroid]] by saturating the body with a stable source of [[iodine]] prior to exposure.<ref>{{Citation
| doi = 10.1093/pubmed/21.4.412
| doi = 10.1093/pubmed/21.4.412
Line 85: Line 88:
| pages = 2008–10
| pages = 2008–10
| url = http://jpubhealth.oxfordjournals.org/cgi/reprint/21/4/412
| url = http://jpubhealth.oxfordjournals.org/cgi/reprint/21/4/412
| archive-url = https://web.archive.org/web/20080905170659/http://jpubhealth.oxfordjournals.org/cgi/reprint/21/4/412
| url-status = dead
| archive-date = 2008-09-05
| journal = Journal of Public Health
| journal = Journal of Public Health
| year = 1999
| year = 1999
| pmid = 11469363
| pmid = 11469363
| doi-access = free
}}</ref> Approved by the [[World Health Organization]] for radiation protection, potassium iodate (KIO<sub>3</sub>) is an alternative to [[potassium iodide|potassium iodide (KI)]], which has poor [[shelf life]] in hot and humid [[climate]]s.<ref>{{Citation
}}</ref> Approved by the [[World Health Organization]] for radiation protection, potassium iodate (KIO<sub>3</sub>) is an alternative to [[potassium iodide|potassium iodide (KI)]], which has poor [[shelf life]] in hot and humid [[climate]]s.<ref>{{Citation
| doi = 10.1097/00004032-199311000-00014
| doi = 10.1097/00004032-199311000-00014
| last1 = Pahuja | first1 = D.N.
| last1 = Pahuja | first1 = D.N.
Line 101: Line 108:
| pmid = 8225995
| pmid = 8225995
| journal = Health physics
| journal = Health Physics
}}</ref> The [[UK]], [[Singapore]], [[United Arab Emirates]], and the [[U.S. state]]s [[Idaho]] and [[Utah]] are known{{by whom|date=February 2011}} to stock potassium iodate in [[Tablet (pharmacy)|tablet]] form.{{Citation needed|date=February 2010}} The government of [[Ireland]] also, following the [[September 11 attacks]], issued potassium iodate tablets to all households.<ref>{{cite web |url=http://www.rpii.ie/Site/Media/Press-Releases/Radioactivity-released-from-Wylfa-nuclear-power-pl.aspx |title=Archived copy |accessdate=2013-04-08 |url-status=dead |archiveurl=https://web.archive.org/web/20131017221002/http://www.rpii.ie/Site/Media/Press-Releases/Radioactivity-released-from-Wylfa-nuclear-power-pl.aspx |archivedate=2013-10-17 }}</ref><ref name="dohc">{{cite web |url=http://www.dohc.ie/press/releases/2008/20080403c.html |title=Archived copy |accessdate=2013-05-22 |url-status=dead |archiveurl=https://web.archive.org/web/20131018013248/http://www.dohc.ie/press/releases/2008/20080403c.html |archivedate=2013-10-18 }}</ref> It is not approved by the [[Food and Drug Administration (United States)|U.S. Food and Drug Administration]] (FDA) for use as a [[thyroid blocker]], and the FDA has taken action against US websites that promote this use.<ref>http://www.nukepills.com/potassium-iodate-vs-potassium-iodide.html</ref><ref>http://www.nukepills.com/docs/Potassium%20Iodate%20warning%20letter.pdf</ref>
}}</ref> The [[UK]], [[Singapore]], [[United Arab Emirates]], and the [[U.S. state]]s [[Idaho]] and [[Utah]] all maintain potassium iodate [[Tablet (pharmacy)|tablets]] towards this end.{{Citation needed|date=February 2010}} Following the [[September 11 attacks]], the government of [[Republic of Ireland|Ireland]] issued potassium iodate tablets to all households for a similar purpose.<ref name="dohc">{{cite web |url=http://www.dohc.ie/press/releases/2008/20080403c.html |title=Decision to Discontinue the Future Distribution of Iodine Tablets |access-date=2013-05-22 |url-status=dead |archive-url=https://web.archive.org/web/20131018013248/http://www.dohc.ie/press/releases/2008/20080403c.html |archive-date=2013-10-18 }}</ref>


{| class="wikitable" style="margin-left: auto; margin-right: auto; border: none;"
[[Image:Potassium iodate tablets.jpg|thumb|left|An unopened box of potassium [[iodate]] tablets, distributed to every household in [[Ireland]] in case of a terror attack on reprocessing plants such as [[Sellafield]] and [[nuclear power station]]s such as [[Wylfa]] in the [[United Kingdom]].
A scenario that upon later expert Irish examination in 2007, was found to not have justified their distribution.<ref>{{cite web |url=http://www.rpii.ie/Site/Media/Press-Releases/Radioactivity-released-from-Wylfa-nuclear-power-pl.aspx |title=Archived copy |accessdate=2013-04-08 |url-status=dead |archiveurl=https://web.archive.org/web/20131017221002/http://www.rpii.ie/Site/Media/Press-Releases/Radioactivity-released-from-Wylfa-nuclear-power-pl.aspx |archivedate=2013-10-17 }}</ref><ref name="dohc" /> The Irish government now upon realizing their error suggests that the tablets be disposed of with municipal waste.<ref name="dohc" />]]

{| class="wikitable"
|+ Recommended Dosage for Radiological Emergencies involving radioactive iodine<ref>{{Citation
|+ Recommended Dosage for Radiological Emergencies involving radioactive iodine<ref>{{Citation
| publication-date = 1999
| date = 1999
| title = Guidelines for Iodine Prophylaxis following Nuclear Accidents
| title = Guidelines for Iodine Prophylaxis following Nuclear Accidents
| publication-place =
| place = Geneva
| place = Geneva
| publisher = [[World Health Organization]]
| publisher = [[World Health Organization]]
| url = http://www.who.int/ionizing_radiation/pub_meet/Iodine_Prophylaxis_guide.pdf
| url =https://www.who.int/ionizing_radiation/pub_meet/Iodine_Prophylaxis_guide.pdf
}}</ref>
}}</ref>
! Age
! Age
Line 136: Line 139:
| 21
| 21
|}
|}

Potassium iodate is not approved by the [[Food and Drug Administration (United States)|U.S. Food and Drug Administration]] (FDA) for use as a [[thyroid blocker]], and the FDA has taken action against US websites that promote this use.<ref>{{Cite web|url=http://www.nukepills.com/potassium-iodate-vs-potassium-iodide.html|title=Potassium iodide vs potassium iodate. Which one works?}}</ref><ref>{{cite web|url=http://www.nukepills.com/docs/Potassium%20Iodate%20warning%20letter.pdf|title=Potassium Iodate Warning Letter|author=W. Charles Becoat|publisher=Food and Drug Administration|date=29 May 2003}}</ref>

==Safety==
Potassium iodate is an [[oxidizing agent]] and as such it can form explosive mixtures when combined with organic compounds.<ref name=":0"/>
{{clear}}


==References==
==References==
{{refimprove|date=January 2009}}
{{reflist}}
{{reflist}}


{{Potassium compounds}}
{{Potassium compounds}}
{{Iodates}}


[[Category:Iodates]]
[[Category:Iodates]]

Latest revision as of 10:30, 18 April 2024

Potassium iodate
Names
IUPAC name
Potassium iodate
Other names
Iodic acid, potassium salt
Identifiers
3D model (JSmol)
ChemSpider
DrugBank
ECHA InfoCard 100.028.938 Edit this at Wikidata
EC Number
  • 231-831-9
E number E917 (glazing agents, ...)
RTECS number
  • NN1350000
UNII
  • InChI=1S/HIO3.K/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1 checkY
    Key: JLKDVMWYMMLWTI-UHFFFAOYSA-M checkY
  • InChI=1/HIO3.K/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1
    Key: JLKDVMWYMMLWTI-REWHXWOFAL
  • [K+].[O-]I(=O)=O
Properties
KIO3
Molar mass 214.001 g/mol
Appearance white crystalline powder
Odor odorless
Density 3.89 g/cm3
Melting point 560 °C (1,040 °F; 833 K) (decomposes)
4.74 g/100 mL (0 °C)
9.16 g/100 mL (25 °C)
32.3 g/100 mL (100 °C)
Solubility soluble in KI solution
insoluble in alcohol, liquid ammonia, nitric acid
−63.1·10−6 cm3/mol
Hazards
GHS labelling:
GHS03: Oxidizing GHS05: Corrosive GHS07: Exclamation mark
H272, H302, H318
P210, P280, P301+P312+P330, P305+P351+P338+P310
NFPA 704 (fire diamond)
Flash point Non-flammable
Related compounds
Other anions
Potassium chlorate
Potassium bromate
Other cations
Sodium iodate
Related compounds
Potassium iodide
Potassium periodate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Potassium iodate (KIO3) is an ionic inorganic compound with the formula KIO3. It is a white salt that is soluble in water.[1]

Preparation and properties

[edit]

It can be prepared by reacting a potassium-containing base such as potassium hydroxide with iodic acid, for example:[1]

HIO3 + KOH → KIO3 + H2O

It can also be prepared by adding iodine to a hot, concentrated solution of potassium hydroxide:[1]

3 I2 + 6 KOH → KIO3 + 5 KI + 3 H2O

Or by fusing potassium iodide with potassium chlorate, bromate or perchlorate, the melt is extracted with water and potassium iodate is isolated from the solution by crystallization:[2]

KI + KClO3 → KIO3 + KCl

The analogous reaction with potassium hypochlorite is also possible:[3]

KI + 3KOCl → 3KCl + KIO3

Conditions/substances to avoid include: heat, shock, friction,[4] combustible materials,[1] reducing materials, aluminium,[4] organic compounds,[1] carbon, hydrogen peroxide and sulfides.[4]

Applications

[edit]

Potassium iodate is sometimes used for iodination of table salt to prevent iodine deficiency. In the US, iodized salt contains antioxidants, because atmospheric oxygen can oxidize wet iodide to iodine; other countries simply use potassium iodate instead.[5] Salt mixed with ferrous fumarate and potassium iodate, "double fortified salt", are used to address both iron and iodine deficiencies.[6] Potassium iodate is also used to provide iodine in some baby formula.[7]

Like potassium bromate, potassium iodate is occasionally used as a maturing agent in baking.[8]

Radiation protection

[edit]
An unopened box of potassium iodate tablets distributed in the early 2000s to Irish households in case of a terror attack on British nuclear facilities.

Potassium iodate may be used to protect against accumulation of radioactive iodine in the thyroid by saturating the body with a stable source of iodine prior to exposure.[9] Approved by the World Health Organization for radiation protection, potassium iodate (KIO3) is an alternative to potassium iodide (KI), which has poor shelf life in hot and humid climates.[10] The UK, Singapore, United Arab Emirates, and the U.S. states Idaho and Utah all maintain potassium iodate tablets towards this end.[citation needed] Following the September 11 attacks, the government of Ireland issued potassium iodate tablets to all households for a similar purpose.[11]

Recommended Dosage for Radiological Emergencies involving radioactive iodine[12]
Age KI in mg KIO3 in mg
Over 12 years old 130 170
3 – 12 years old 65 85
1 – 36 months old 32 42
< 1 month old 16 21

Potassium iodate is not approved by the U.S. Food and Drug Administration (FDA) for use as a thyroid blocker, and the FDA has taken action against US websites that promote this use.[13][14]

Safety

[edit]

Potassium iodate is an oxidizing agent and as such it can form explosive mixtures when combined with organic compounds.[1]

References

[edit]
  1. ^ a b c d e f Lyday, Phyllis A.; Kaiho Tatsuo (26 November 2015). "Iodine and Iodine Compounds". In Ley, Claudia (ed.). Ullmann's Encyclopedia of Industrial Chemistry (7th ed.). Weinheim: Wiley-VCH. p. 9. doi:10.1002/14356007.a14_381.pub2. ISBN 9783527306732.
  2. ^ Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN 0-07-049439-8
  3. ^ Andrews, Launcelot W. (July 1903). "Titrations with potassium iodide". Journal of the American Chemical Society. 25 (7). Easton, Pennsylvania: US Postal Service: 756. doi:10.1021/ja02009a012 – via HathiTrust.
  4. ^ a b c Regulatory Affairs (23 March 2023). "Safety Data Sheet" (Potassium iodate MSDS) (5 ed.). Fair Lawn, NJ: Thermo Fisher Scientific. Archived from the original on 22 September 2023. Retrieved 22 September 2023.
  5. ^ Arroyave, Guillermo; Pineda, Oscar; Scrimshaw, Nevin S. (1956) [May 1955]. "The stability of potassium iodate in crude table salt". Bulletin of the World Health Organization. 14 (1): 183–185. PMC 2538103. PMID 13329845.
  6. ^ Diosady, Levente L.; Mannar, M.G. Venkatesh; Krishnaswamy, Kiruba (2019). "Improving the lives of millions through new double fortification of salt technology". Maternal & Child Nutrition. 15 (Suppl 3): e12773. doi:10.1111/mcn.12773. PMC 6594086. PMID 31148400.
  7. ^ James, Maia (2023-04-04). "Best Baby Formula Guide". Gimme the Good Stuff. Retrieved 2023-09-22.
  8. ^ Carson, Lin (ed.). "Potassium iodate". BAKERpedia. Portland, OR. Retrieved 22 September 2023.
  9. ^ Astbury, John; Horsley, Stephen; Gent, Nick (1999), "Evaluation of a scheme for the pre-distribution of stable iodine (potassium iodate) to the civilian population residing within the immediate countermeasures zone of a nuclear submarine construction facility", Journal of Public Health, 21 (4): 2008–10, doi:10.1093/pubmed/21.4.412, PMID 11469363, archived from the original on 2008-09-05
  10. ^ Pahuja, D.N.; Rajan, M.G.; Borkar, A.V.; Samuel, A.M. (Nov 2008), "Potassium iodate and its comparison to potassium iodide as a blocker of 131I uptake by the thyroid in rats", Health Physics, 65 (5): 545–9, doi:10.1097/00004032-199311000-00014, PMID 8225995
  11. ^ "Decision to Discontinue the Future Distribution of Iodine Tablets". Archived from the original on 2013-10-18. Retrieved 2013-05-22.
  12. ^ Guidelines for Iodine Prophylaxis following Nuclear Accidents (PDF), Geneva: World Health Organization, 1999
  13. ^ "Potassium iodide vs potassium iodate. Which one works?".
  14. ^ W. Charles Becoat (29 May 2003). "Potassium Iodate Warning Letter" (PDF). Food and Drug Administration.