Scribd
Upload
22 views18 pages

Energetics and Equilibrium Lesson 3

Uploaded by

nfawzy
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PPTX, PDF, TXT or read online on Scribd
22 views18 pages

Energetics and Equilibrium Lesson 3

Uploaded by

nfawzy
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PPTX, PDF, TXT or read online on Scribd
You are on page 1/ 18

Energy and

Enthalpy
Agenda

•Define the term


enthalpy
•Calculate the
enthalpy changes for
different processes.
What is Enthalpy?
• Previously, we calculated the
energy of a chemical reaction
using:
Q = m.c.ΔT

• How does this relate to our


previous unit?
Read the following statement
and think of how this relates to
our previous unit?
What do they all have in common?

Enthalpy of reaction ΔHr


Guess the Enthalpy of combustion ΔHc
definitions of Enthalpy of neutralization ΔHn
the following Enthalpy of formation ΔHf
types of Enthalpy of vaporization ΔHv
enthalpies Enthalpy of solution ΔHsol
Two rules to
remember …

Q=mcΔT
N.B .: ΔH =
Divide into
groups
(2-3)

•There are 5 questions,


•You will have 5 minutes to
answer each one.
•You don’t have to work in
order.
•Complete all questions.
•A time will tell you when to
move to the next question.
First Question
Second Question
Third Question
Fourth Question
Fifth Question
Check your
answers

•Reflect on your responses


Practice 1
4.3 g of ammonium nitrate, NH4NO3 was added to 60.0 g of water and
stirred to dissolve the solid completely. The initial temperature dropped
from 22.0 °C to a final temperature of 16.9 °C.

1. Calculate the energy absorbed during this process.

2. Calculate the number of moles of ammonium nitrate.

3. Calculate the enthalpy of solution of ammonium nitrate.


Practice
The enthalpy of combustion of methane, CH4 = -890.4 kJ.mol-1.

1. Calculate the energy released when 2.00 moles of methane completely combust
in excess oxygen.

2. Calculate the energy released when 22.4 g of CH4 completely combust in excess
oxygen.

3. The energy released by the burning of 22.4 g of CH4 is used to heat up 100.0 g of
water, at room temperature.
Calculate the final temperature of water.
Practice
The enthalpy of solution, ΔHsoln , of NaOH is −44.51kJ/mol .
In a certain experiment, 50.0g of NaOH is completely dissolved in 1.000
L of 20.0 °C water in a foam cup calorimeter.
Assuming no heat loss, calculate the final temperature of the water.
1. Calculate the number of moles of sodium hydroxide.

2. Calculate the energy released when 50.0 g of NaOH dissolved.

3. Calculate ΔT.
Practice
If 0.750 grams of magnesium oxide is placed in a coffee-cup calorimeter
and then 100.0 mL of 1.00 M HCl is added, the temperature of the HCl
solution increases from 22.8 °C to 28.7 °C.
Based on this information, calculate the enthalpy of neutralization of
MgO.
The specific heat of the solution is 4.20 J/g°C and the density of the HCl
solution is 1.00 g/mL.
Practice
Using a coffee cup calorimeter, 150 mL of 1.00 mol L-1 hydrochloric
acid are mixed with 150 mL of 1.00 mol L-1 sodium hydroxide solution.
The initial temperature of the solutions was 22.6°C and the
temperature after mixing was 29.5°C.
Calculate the enthalpy of neutralization.

You might also like