Matter Wave EM Wave

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MODULE - II

QUANTUM PHYSICS

Dr. C. R. Kesavulu, Associate Professor, Dept. of Physics

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MODULE - II
QUANTUM PHYSICS
TOPICS IN QUANTUM PHYSICS

 Introduction to quantum physics

 Wave Particle Duality-de-Broglie’s hypothesis

 Davisson and Germer experiment,

 Time-independent Schrodinger equation for wave function,

 Physical significance of the wave function,

 Schrodinger equation for one dimensional problems–particle in a


box.
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Matter wave Properties
The wavelength of matter is . So, wavelength is inversely proportional to
velocity.
A group of waves each wave having wavelength given above, is associated with the
particle. This group as a whole must travel with the particle velocity v. Hence group
velocity of matter waves= vgr = v.
Each wave of the group of matter waves travel with a velocity known as phase
velocity of the wave.
Wavelength of electron: A0

We have to remember that no single phenomena either matter or radiation exhibits


both particle nature and wave nature simultaneously.
Waves can be in a group and such groups are called wave packets so the velocity
with which a wave packets travels is called group velocity
The velocity with which the phase of a wave travels is called phase velocity
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Difference between Matter wave and EM waves

MATTER WAVE EM WAVE


Matter wave is associated with Oscillating charged particle
a particle. gives rise to electromagnetic
wave.
Wavelength depends on the Wavelength depends on the
mass of the particle and its energy of the photon λ= hC/E
velocity λ= h/mv
Can travel with a velocity Travels with velocity of light.
greater than the velocity of
light.
Matter wave is not Electric field and magnetic field
electromagnetic wave. oscillate perpendicular to each
other.
Matter wave require medium Electromagnetic waves do not
for propagation require medium i.e., they travel
in vacuum also. 4
Davisson - Germer’s Experiment
Initial atomic models proposed by scientists could only explain the particle nature of
electrons but failed to explain the properties related to their wave nature. C.J.
Davisson and L.H. Germer, in the year 1927, carried out an experiment, popularly
known as Davisson Germer’s experiment, to explain the wave nature of electrons
through electron diffraction.

Electron gun G
Filament F.
Target T (large single crystal
of Ni)
Detector D
Faraday cylinder C
Semi circular Scale S
Galvanometer G

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Davisson - Germer’s Experiment
The electrons emitted from gun
strikes, the target which is rotated
about an axis along the direction
of beam.
The speed of the electrons can be
measured by the voltage used for
accelerating electrons.
The scattered beam is detected
by the chamber D and its intensity
is measured in different
directions.
The plot of the electron beam
intensity I versus the angle Φ
between the incident and
Davisson- Germer’s Experiment

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Davisson-
Davisson- Germer’s Experiment

If θ is the correspondence angle of diffraction at the Bragg’s plane


then θ and Φ are related as θ=
So if θ is diffraction angle, n is order of maxima, then from Bragg’s
law 2dsinθ=nλ.
Davisson & Germer observed that maximum diffraction occurs at
Φ=500 & d=0.91 A0.
Now, Φ=500 => θ= =650.
Therefore, λ=2dsinθ {for n=1}
= > 2×0.91×sin 65
= 1.65 A0.

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Davisson- Germer’s Experiment
 So, the values of λ determined in these two ways are in
agreement thus confirming the existence of matter waves.

 The drawback of this experiment is that whether the diffraction


pattern formed is due to electrons or E.M radiation generated by fast
moving electrons is not known.

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