Acids, Bases
Acids, Bases
Acids, Bases
&
Salts
CHEMISTRY 0620
pH scale
• The pH scale is logarithmic, meaning that each change of 1 on the scale represents a change in concentration by a factor of 10
• Therefore an acid with a pH of 3 has ten times the concentration of H+ ions than an acid of pH 4
• An acid with a pH of 2 has 10 x 10 = 100 times the concentration of H + ions than an acid with a pH of 4
pH Indicators
Universal Indicator
Mixture of indicators that give different colours in solutions of different pH
It is used to determine the pH of a substance by matching the color change to the pH
color chart.
Acids
• Proton donors
• Produces hydrogen ions (H+) when dissolved in water
HCl (aq) → H+ (aq) + Cl- (aq)
Indicators
• pH between 1 (strong) and 6 (weak)
• Turns blue litmus red
• Turns methyl orange indicator red
• Colorless in thymolphthalein
• Colorless in phenolphthalein
Comparing Acids
HCl (aq) → H+ (aq) + Cl- (aq) CH3COOH (aq) ⇌ H+ (aq) + CH3COO- (aq)
Chemical Properties of Acids
• Displacement reaction
• Metals above hydrogen give this reaction
• Neutralization reaction
Proton Transfer
Bases
• Proton acceptors
• Soluble bases are called alkalis
• When alkalis are added to water, they give negative hydroxide ions (OH –)
• Bases include alkalis, and insoluble metal oxides, hydroxides, and carbonates.
NaOH (s) → Na+ (aq) + OH- (aq)
Indicators
• Have pH between 8 (weak) and 14 (strong)
• Turns red litmus blue
• Turns methyl orange indicator yellow
• Turns Blue in Thymolphthalein
• Turns pink in phenolphthalein
Comparing Alkalis
• This reaction is used as a chemical test to confirm the presence of the ammonium ion (NH 4+)
• Alkali is added to the substance with gentle warming followed by the test for ammonia gas using damp red
litmus paper
• The damp litmus paper will turn from red to blue if ammonia is present
Neutralisation Reaction
A chemical reaction between an acid and a base to produce salt and water only.
Ionic Equation: H+ + OH- H2O
Neutralisation with insoluble base
How to write Ionic
Equation?
Metal oxides are basic in nature e.g. Copper oxide and Calcium oxide, will neutralize acids
Non-metal oxides are acidic in nature e.g. sulfur dioxide and carbon dioxide, will turn litmus paper
red and neutralize bases
Aluminum, zinc form amphoteric oxides e.g. zinc oxide that react with both acids and bases to
produce salt and water
Oxides that react with neither acids nor bases are neutral e.g. nitrous monoxide and carbon
monoxide
Reactions of Amphoteric Oxides
Behaving as a base
Reactions of Amphoteric Oxides
Behaving as an acid