Acids, Bases

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Acids, Bases

&
Salts
CHEMISTRY 0620
pH scale

• pH is the concentration of H+ ions per dm3 of solution


• Lower pH  more acidic
• Higher pH  more basic

• The pH scale is logarithmic, meaning that each change of 1 on the scale represents a change in concentration by a factor of 10

• Therefore an acid with a pH of 3 has ten times the concentration of H+ ions than an acid of pH 4

• An acid with a pH of 2 has 10 x 10 = 100 times the concentration of H + ions than an acid with a pH of 4
pH Indicators

Substance that changes colour when added to acidic or basic solution


e.g. litmus, thymolphthalein, methyl orange
1. Litmus
2. Thymolphthalein
3. Methyl orange

Universal Indicator
 Mixture of indicators that give different colours in solutions of different pH
 It is used to determine the pH of a substance by matching the color change to the pH
color chart.
Acids

• Proton donors
• Produces hydrogen ions (H+) when dissolved in water
HCl (aq) → H+ (aq) + Cl- (aq)
 Indicators
• pH between 1 (strong) and 6 (weak)
• Turns blue litmus red
• Turns methyl orange indicator red
• Colorless in thymolphthalein
• Colorless in phenolphthalein
Comparing Acids

Strong acids Weak acids


 Completely dissociate in aqueous  Partially dissociate in aqueous
solution producing lots of H+ ions solution producing few H+ ions
 Very low pH  Closer to pH 7
 Mostly mineral acids e.g:  Mostly organic acids e.g:

HCl (aq) → H+ (aq) + Cl- (aq) CH3COOH (aq) ⇌ H+ (aq) + CH3COO- (aq)
Chemical Properties of Acids

• Displacement reaction
• Metals above hydrogen give this reaction
• Neutralization reaction
Proton Transfer
Bases

• Proton acceptors
• Soluble bases are called alkalis
• When alkalis are added to water, they give negative hydroxide ions (OH –)
• Bases include alkalis, and insoluble metal oxides, hydroxides, and carbonates.
NaOH (s) → Na+ (aq) + OH- (aq)
Indicators
• Have pH between 8 (weak) and 14 (strong)
• Turns red litmus blue
• Turns methyl orange indicator yellow
• Turns Blue in Thymolphthalein
• Turns pink in phenolphthalein
Comparing Alkalis

Strong alkalis Weak alkalis


 Alkalis which ionize to a large extent in dilute  Alkalis which ionize poorly in dilute aqueous
aqueous solution and release hydroxide ions in solution and release hydroxide ions in a small
a large number are called strong alkalis. number are called weak alkalis
NaOH, KOH NH3 solution, CH3NH2 (methylamine)
Chemical Properties of Bases

Acid + Base → Salt + Water


• Neutralization reaction
Reaction with Ammonium Salts

Base + ammonium salt → salt + ammonia gas + water

• This reaction is used as a chemical test to confirm the presence of the ammonium ion (NH 4+)
• Alkali is added to the substance with gentle warming followed by the test for ammonia gas using damp red
litmus paper
• The damp litmus paper will turn from red to blue if ammonia is present
Neutralisation Reaction

A chemical reaction between an acid and a base to produce salt and water only.
Ionic Equation: H+ + OH-  H2O
Neutralisation with insoluble base
How to write Ionic
Equation?

1. First write down all the


ions present in the equation
2. Now cross out any ions
that appear, unchanged, on
both sides of the equation
3. What’s left is the ionic
equation for the reaction
Oxides

 Metal oxides are basic in nature e.g. Copper oxide and Calcium oxide, will neutralize acids

 Non-metal oxides are acidic in nature e.g. sulfur dioxide and carbon dioxide, will turn litmus paper
red and neutralize bases

 Aluminum, zinc form amphoteric oxides e.g. zinc oxide that react with both acids and bases to
produce salt and water

 Oxides that react with neither acids nor bases are neutral e.g. nitrous monoxide and carbon
monoxide
Reactions of Amphoteric Oxides

Behaving as a base
Reactions of Amphoteric Oxides

Behaving as an acid

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