CHPT04
CHPT04
An Engineering
Approach
Eighth Edition
Introduction
• The first law of thermodynamics is essentially an
expression of the conservation of energy principle.
Energy can cross the boundaries of a closed
system in the form of heat or work.
Introduction
• Heat is transferred in three ways: conduction,
convection, and radiation.
Introduction
• The three modes of heat transfer are expressed
as:
3-25
Introduction
• Various forms of work are expressed as follows:
Introduction
Introduction
• The energy balance for any system undergoing any
process can be expressed as:
3-28
Introduction
• The energy balances for any system undergoing any
process can be expressed in the rate form as:
3-29
Introduction
• Taking heat transfer to the system and work done by
the system to be positive quantities, the energy
balance for a closed system can also be expressed
as:
where:
3-30
Introduction
• For a constant-pressure process, .
Thus
3-31
Introduction
• The amount of energy needed to raise the
temperature of a unit of mass of a substance by one
degree is called the specific heat at constant volume
Cv for a constant-volume process and the specific heat
at constant pressure Cp for a constant pressure
process. They are defined as:
3-32
Introduction
• For ideal gases u, h, Cv, and Cp are functions of
temperature alone. The u and h of ideal gases can
be expressed as:
3-33
Introduction
• For ideal gases Cv, and Cp are related by:
3-34
Introduction
• The specific heat ratio k is defined as:
3-35
Introduction
• For incompressible substances (liquids and solids),
both the constant-pressure and constant-volume
specific heats are identical and denoted by C:
3-36
Introduction
• The u and h of incompressible substances are
given by
3-37
Introduction
Heat Transfer
• (Fig. 4-3)
3-2
Adiabatic Process
• (Fig. 4-4)
3-3
• (Fig. 4-8)
3-4
Convection: Cooling
• (Fig. 4-9)
3-5
Radiation
• (Fig. 4-10)
3-6
• (Fig. 4-15)
3-7
Path Functions
• (Fig. 4-16)
3-8
Boundary Work
• (Fig. 4-27)
3-9
• (Fig. 4-29)
3-10
• (Fig. 4-31)
3-11
• (Fig. 4-32)
3-12
Schematic/Diagram for the Polytropic Process
• (Fig. 4-33)
3-13
• (Fig. 4-43)
3-14
• (Fig. 4-45)
3-15
• (Fig. 4-52)
3-16
• (Fig. 4-54)
3-17
Closed-Systems, First-Law
• (Fig. 4-55)
3-18
• (Fig. 4-72)
3-19
• (Fig. 4-76)
3-20
• (Fig. 4-91)