01 CMP Crystal Structure
01 CMP Crystal Structure
Classification of solids
Solids are broadly classified into two types
crystalline solids and amorphous solids.
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2D Crystal
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3D Crystal
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3D Crystal
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Unit cell
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Bravais lattice
Where are any integers and are known as the primitive vectors
which lie in different directions and span the lattice. This discrete set
of vectors must be closed under vector addition and subtraction. For
any choice of position vector , the lattice looks exactly the same.
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2D Crystal
1 0
0 1
1 1
2 2
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2D Crystal
1 0
0 1
-1 1
1 1
-2 2
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Bravais lattice in 3D
epionelynx.wordpress.com
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Bravais lattice in 3D
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Primitive translational vector of fcc lattice
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Primitive translational vector of bcc lattice
Conventional Unit Cell
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Primitive lattice cell
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3D view
showing the
number of
atoms per
unit cell
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Characteristics of cubic lattices
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Wigner-Seitz cell
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Wigner-Seitz cell
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Bravais lattice
Reciprocal Lattice
The reciprocal lattice
represents the Fourier
transform of the Bravais
lattice.
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Crystal structure
basis + lattice = crystal structure
+ =
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Crystal structure
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Crystal structure
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Crystal structure
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Miller Indices
The Miller indices of a lattice plane are the
coordinates of the shortest reciprocal lattice
vector normal to the plane, with respect to a
specific set of primitive reciprocal lattice
vectors. Thus a plane with Miller indices (h k l),
is normal to the reciprocal lattice vector
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The rules for Miller Indices:
•Determine the intercepts of the face along the crystallographic
axes, in terms of unit cell dimensions.
•Take the reciprocals
•Clear fractions
•Reduce to lowest terms
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Miller Indices
Miller Indices are the reciprocals of the parameters of each crystal face.
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Miller Indices
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Miller Indices
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Draw your own lattice
planes
https://www.doitpoms.ac.uk/tlplib/miller_indices/lattice_draw.php
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Band Theory of
Solids
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Energy Bands for Solids
E E E
Empty
conduction band Empty
conduction band Conduction band
Large energy gap Eg Small energy gap Eg Overlap
Balance band
Filled balance band
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Crystal Defects
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Crystal Defects
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Crystal Defects
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Crystal Defects
nde-ed.org
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