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From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
ISBN-13: 978-0078028182
ISBN-10: 0078028183
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
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From: S.O. the
Kasap, Principles
following referenceof Electronic
under Materials and
each figure
Devices, Fourth Edition, © 2018 McGraw-Hill Education
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Thermally Activated Processes: Diffusion
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Diamond Unit Cell
The diamond unit cell is cubic. The cell has eight atoms. Grey Sn (α-Sn) and the
Elemental semiconductors Ge and Si have this crystal structure.
Fig 1.35
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Zinc Blende Cubic Crystal Structure
The Zinc blende (ZnS) cubic crystal structure. Many important compound crystal
Structures have the zinc blende structure. Examples: AlAs, GaAs, Gap, GaSb, InAs, InP,
InSb, ZnS, ZnTe.
Fig 1.36
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Misfit and Threading Dislocations
(a) The epitaxial layer crystal has the same lattice constant (ae) as the substrate (as). The crystals are
matched and there are no defects at the interface. (b) The epitaxial layer has a larger lattice constant
than the substrate, ae > as, and misfit dislocations are created; otherwise, the epitaxial layer becomes
highly strained. The example here may be a Si substrate on which Si 1−xGex alloy is grown or a GaAs
substrate on which an InxGa1−xAs epilayer is grown.
Fig 1.52
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Surfaces of Solids
At the surface of a hypothetical two dimensional crystal, the atoms cannot fulfill their
bonding requirements and therefore have broken, or dangling, bonds. Some of the surface
atoms bond with each other; the surface becomes reconstructed. The surface can have
physisorbed and chemisorbed atoms.
Fig 1.55
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Metallic Glasses (or Glassy Metals) by Melt Spinning
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Amorphous Silicon
Left: A polycrystalline diamond film on the (100) surface of a single crystal silicon wafer
where the growth chemistry has been changed to produce predominantly square-faceted
(100) diamond crystallites. The film thickness is 6 microns and the SEM magnification is
6000.
Right: A 6-micron-thick polycrystalline CVD diamond film grown on a single crystal silicon
wafer where the crystallites have random orientation. SEM magnification is 8000.
(Courtesy of Professor Paul May, The School of Chemistry, University of Bristol, England. Used with permission.)
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Pb-Sn Binary Alloys: Solders
Pb (lead) Sn (Tin)
FCC Tetragonal
a = 0.495 nm a = b = 0.583 nm
Tm = 327.5 C c = 0.318 nm
Winters© McGraw-Hill Tm = 231.9 C
Education/Charles D. Winters © McGraw-Hill
Education/Charles D. Winters
60-40 Solder
Tm = 183 – 188 C
Solder
Photo by S. Kasap
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
The Drude Model
The motion of a single electron in the presence of an electric field E. During a time
Interval ti, the electron traverses a distance si along x. After p collisions, it has drifted a
Distance s = x.
Fig 2.4
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Resistivity vs Temperature
The resistivity of copper from lowest to highest temperatures (near melting temperature, 1358 K) on a log-log plot.
Above about 100 K, ρ T1.16 (approximately T), whereas at low temperatures, ρ T5 and at the lowest
temperatures approaches the residual resistivity ρR. The inset shows the ρ vs. T behavior below 100 K on a linear
plot (ρR is too small on this scale). (Data combined from various sources to generate a representative curve. Lowest
residual resistivity from Basinski and Dugdale's 1985 work.)
Fig 2.8
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Temperature Coefficient of Resistivity Depends on the Reference Temperature
1
0
0 T T T0
at T = T0 Gradient at T = T0
1 1 (T1 ) 0
0
0 T T T0 0 (T1 T0 )
Use 293 K Use 273 K
1 16.78 n m 15.43 n m
273
(15.43 n m) (293 K 273 K )
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Strain Gauges
A commercial strain gauge by Micro- Measurements (Vishay Precision Group). This gauge has a
maximum strain range of ±5%. The overall resistance of the gauge is 350 W. The gauge wire is a
constantan alloy with a small thermal coefficient of resistance. The gauge wires are embedded in
a polyimide polymer flexible substrate. The external solder pads are copper coated. Its useful
temperature range is –75 C to +175 C. (Photo by S. Kasap)
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Hall Effect in Semiconductors
(a) Grain boundaries cause scattering of the electron and therefore add to the
Resistivity by the Matthiessen’s rule.
(b) For a very grainy solid, the electron is scattered from grain boundary to grain boundary
and the mean free path is approximately equal to the mean grain diameter.
Fig 2.33
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
X-rays are photons
X-ray image of an American one-cent
coin captured using an x-ray a-Se
HARP camera. The first image at the
top left is obtained under extremely
low exposure and the subsequent
images are obtained with increasing
exposure of approximately one order
of magnitude between each image.
The slight attenuation of the X-ray
photons by Lincoln provides the
image. The image sequence clearly
shows the discrete nature of x-rays,
and hence their description in terms
of photons.
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Diffraction of Electrons
Left: Circular bright rings make up the diffraction pattern obtained when
an electron beam is passed through a thin polycrystalline aluminum
sheet. The pattern results from the wave behavior of the electrons; the
waves are diffracted by the Al crystals.
Center and Right: A magnet brought to the screen bends the electron
paths and distorts the diffraction pattern. The magnet would have no
effect if the pattern was due to X-rays, which are electromagnetic waves.
Courtesy of Farley Chicilo
Fig 3.13
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Diffraction of Electrons
Fig 3.14
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Wave-Particle Duality
Drawing by SK
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Magnetic Dipole Moment of the Electron
(a) The orbiting electron is equivalent to a current loop that behaves like a bar magnet.
(b) The spinning electron can be imagined to be equivalent to a current loop as shown.
This current loop behaves like a bar magnet, just as in the orbital case.
Fig 3.33
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Characteristic emission wavelengths from gas discharge tubes
Helium gas Neon gas Argon gas Krypton gas Xenon gas
(red) (violet/lavender)
© McGraw-Hill Education/Mark Dierker
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Energy diagram for the Er3+ ion in the glass fiber
Energy diagram for the Er3+ ion in the glass fiber medium and light amplification by
Stimulated emission from E2 to E1.
Dashed arrows indicate radiationless transitions (energy emission by lattice vibrations).
Fig 3.48
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Energy band diagram of a semiconductor
Energy band diagram of a semiconductor. CB is the conduction band and VB is the valence
band. AT 0 K, the VB is full with all the valence electrons.
Fig 4.19
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Density of States
(a) In the solid there are N atoms and N extended electron wavefunctions from 1 all the way
to N. There are many wavefunctions, states, that have energies that fall in the central regions
Of the energy band.
(b) The distribution of states in the energy band; darker regions have a higher number of
states.
(c) Schematic representation of the density ofFig
states
4.23 g(E) versus energy E.
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Soft X-Ray Emission
= nE
Emission of soft X-rays from a sodium sample that is bombarded by electrons (in
a suitable high vacuum). An impinging electron knocks out an electron from an
inner core shell (L-level). A conduction electron falls down and fills this space
and emits an X-ray photon. The X-ray emission intensity is proportional to the
number of conduction electrons available, f(E)g(E) = nE, and to hf3, a quantum
mechanical transition probability. The vertical axis has been scaled to make the
peak 100 percent
Data extracted from Cady, W.M. and Tomboulian D.H., Physical Review 59, 381, 1941, Table 1.
Fig 4.30
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Thermal Conductivity k
Phonons transfer heat Phonons transfer heat Electrons transfer heat
Silver
Diamond Si crystal and wafers
© McGraw-Hill Education/Mark Dierker
Full-length view of two cut diamonds Courtesy of SunEdison Semiconductor (mhhe022468.jpg)
© McGraw-Hill Education (mhhe017428-S.jpg)
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
n-Type Silicon
Arsenic-doped Si crystal.
The four valence electrons of As allow it to bond just like Si, but the fifth electron is left
orbiting the As site. The energy required to release the free fifth electron into the CB is
very small.
Fig 5.9
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Direct and Indirect Recombination
(a) The electron energy (E) versus electron’s crystal momentum (ħk) in a direct bandgap semiconductor. Each
circle represents a possible state, an electron wavefunction (y), a solution of Schrodinger’s equation in a
crystal, with a wave vector k. These solutions fall either into the CB or the VB; there are no solutions within
the bandgap. The sketches are highly exaggerated because the circles are so close that they form a
continuous energy versus momentum behavior. (b) Energy versus crystal momentum for an indirect bandgap
semiconductor such as Si.
Fig 5.23
From Principles of Electronic Materials and Devices, Third Edition, S.O. Kasap (© McGraw-Hill, 2005)
Schottky Junction
Before
After
(b)
(c)
Fig 6.1
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Short Diode
x'
Energy band diagrams for a pn junction under (a) open circuit and (b) forward bias
Fig 6.11
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Reverse Bias
(a) (b)
Reverse biased pn junction. (a) Minority carrier profiles and the origin of the reverse
current. (b) Hole PE across the junction under reverse bias
Fig 6.8
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Junction Field Effect Transistor (JFET)
(a) The basic structure of the junction field effect transistor (JFET) with an n-channel. The two p+
regions are electrically connected and form the gate.
(b) A simplified sketch of the cross section of a more practical n-channel JFET
Fig 6.55
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Enhancement MOSFET
Fig 6.64
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
III-Nitride
LEDs
Fig 6.28
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Solar Cells
Fig 6.37
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Useful Photogeneration Volume is Lh + W + Le
Iph
An np junction solar cell in short circuit. Photogenerated carriers within the
volume Lh + W + Le give rise to a photocurrent Iph. The variation in the
photogenerated EHP concentration with distance is also shown where α is the
absorption coefficient at the wavelength of interest.
Fig 6.39
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
An inverted pyramid textured surface
An inverted pyramid textured surface substantially reduces reflection losses and increases
absorption probability in the device.
Fig 6.46
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Enhancement MOSFET
Fig 6.64
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Electrolytic Polypropylene Ceramic
Polypropylene Polyester
Electrolytic
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Ceramic
Polypropylene
Polypropylene
Polyester Polyester Polyester Electrolytic
Ceramic
Polypropylene
Ceramic
1F
6.3 V
4.7 F
50 F 2.5 V
350 F 2.7 V
2.7 V All photos by S. Kasap, 2016
Supercapacitors with energy in the range to 0.3 J to 1.27 kJ
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
A Dielectric Inserted into a Capacitor
(a) Parallel plate capacitor with free space between the plates.
(b) As a slab of insulating material is inserted between the plates, there is an external current
flow indicating that more charge is stored on the plates.
(c) The capacitance has been increased due to the insertion of a medium between the plates.
Fig 7.1
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
The Origin of Electronic Polarization
Relaxation
Resonance
The frequency dependence of the real and imaginary parts of the dielectric constant in the
presence of interfacial, orientational, ionic, and, electronic polarization mechanisms.
Fig 7.15
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Debye Equations
[ r (0) 1] [ r (0) 1]
r 1
1 ( ) 1 ( )
2 r 2
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Electrical Treeing Breakdown in a High Voltage Coaxial
Fig 7.28
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Electrical Branch Trees in Dielectric Breakdown
Left: An electric tree spreading from a needle electrode to the counter electrode in
cross-linked polyethylene (XLPE) insulation under an ac voltage of 11 kV (rms) after 20
minutes of voltage application. These types of open tree-like structures are usually
called branch trees. Notice that a tree brunch just reaches the counter electrode.
Right: About 20 seconds later, a dielectric breakdown ensues with a large discharge
current along a thick (about 0.1 mm thick) conducting channel (black).
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Super vs Electrolytic Capacitors
Maximum 50 F, 2.7 V
350 F, 2.7 V 5,500 μF, 350 V
energy stored in 1,275 J 336 J 182 J
Joules
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Piezoelectric Effect
In a magnetized region of a ferromagnetic material such as iron all the magnetic moments
are spontaneously aligned in the same direction.
There is a strong magnetization vector M
even in the absence of an applied field
Fig 8.15
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Inductors use soft magnetic materials
10 mH (23.2 W)
L (r)
Photo by SK
Inductance, L Resistance, r
Resistance of windings and
ferrite losses
Simplest equivalent circuit with losses
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Rare-Earth Magnets
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Pauli Spin Paramagnetism
Fig 8.44
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Giant Magnetoresistance (GMR)
Magnet with air gap. Point P is the operating point of the magnet and determines
the field inside the magnet and in the air gap, that is Bg'. The corresponding
magnetizing field is Hm'
Energy density in the gap is proportional to BH, and for a given geometry and
size of gap, this is a maximum at a particular magnetic field Bm* or Bg*
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Definitions in Magnetic Data Storage
Liquid N2
Hollow
former
HT
S
Dielectri
HTc
Liquid
DielectriS
HTc
DielectriS N2
Copperc
screen
Inner cryostat wall
Insulation
A high temperature superconductor (HTS) power cable for use at 10 kV and 2,300
A. The HTS is Bi223.. The cable has been installed
in the city center of Essen (Germany) by a German utility company RWE
Deutschland; and it has been in use since 2014. The superconductor
shown is manufactured by Nexans.
© Reuters/Alamy Stock Photo
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Fresnel's Equations
Light wave traveling in a more dense medium strikes a less dense medium.
The plane of incidence is the plane of the paper and is perpendicular to the flat interface between
the two media. The electric field is normal to the direction of propagation. It can be resolved into
perpendicular (⊥) and parallel (||) components.
Fig 9.11
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Dielectric mirrors
A dielectric mirror consists of a stack of dielectric layers of alternating refractive
indices: n1|n2|n1|n2|n1|n2|n1|n2| ….
Fig 9.16
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Lattice Absorption: Reststrahlen Absorption
Lattice absorption through a crystal. The field in the EM wave oscillates the ions,
which consequently generate "mechanical" waves in the crystal; energy is thereby
transferred from the wave to lattice vibrations
Fig 9.21
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Optical Activity
Fig 9.40
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Luminescent Emission
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)
Sample Slides
The End
Email errors and corrections to
[email protected]
From Principles of Electronic Materials and Devices, Fourth Edition, S.O. Kasap (© McGraw-Hill Education, 2018)