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Lecture 16.3 - Sample Problems Application of The 1st Law

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50 views5 pages

Lecture 16.3 - Sample Problems Application of The 1st Law

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Abi VA
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© © All Rights Reserved
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LECTURE 16.

3:
SAMPLE PROBLEMS
(THE FIRST LAW :
THE MACHINERY)

Physical Principles 1 Lecture


Sherrie Mae M. Vinluan
Adamson University
Chemical Engineering Department
SAMPLE PROBLEMS
1) A vapour at 22 atm and 5.0°C was allowed
to expand adiabatically to a final pressure of
1.00 atm; the temperature fell by 10.0 K.
Calculate the Joule–Thomson coefficient, μ, at
5.0°C, assuming it remains constant over this
temperature range.
SAMPLE PROBLEMS
2) The isothermal compressibility of lead at
293 K is 2.21×10−6 atm−1. Calculate the pressure
that must be applied in order to increase its
density by 0.08 per cent.
SAMPLE PROBLEMS
3) Given that μ = 1.11 K atm−1 for carbon
dioxide, calculate the value of its isothermal
Joule–Thomson coefficient. Calculate the
energy that must be supplied as heat to
maintain constant temperature when 12.0 mol
CO2 flows through a throttle in an isothermal
Joule–Thomson experiment and the pressure
drop is 55 atm.
SAMPLE PROBLEMS
4) The volume of a certain liquid varies with
temperature as
V = V ′{0.77 + 3.7 × 10−4(T/K) + 1.52 ×
10−6(T/K)2}
where V ′ is its volume at 298 K. Calculate its
expansion coefficient, α, at 310 K.

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