ENERGY

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ENERGY

Issues surrounding energy:


• sources
• production,
• distribution, and
• consumption
How chemistry is used to produce energy:
• The combustion of gasoline,
• the production of electricity from coal,
• the heating of homes by natural gas, and
• the use of batteries to power electronic devices
• Even solar cells, rely on chemistry to produce the silicon and
other materials that convert solar energy directly to electricity.
• chemical reactions provide the energy that sustains living
systems. Plants use solar energy to carry out photosynthesis,
allowing them to grow.
• The plants in turn provide food from which humans derive the
energy needed to move, maintain body temperature, and carry
out all other bodily functions.
Energy is intimately related to chemistry. What exactly is
energy and what principles are involved in its production,
consumption, and transformation from one form to
another?
The study of energy and its transformations is known as
thermodynamics.

(Greek: thérme-, “heat”; dy’namis, “power”)


What is Energy?
• Energy is the capacity to do work or transfer heat.

• Work is the energy used to cause an object to move


against a force, and heat is the energy used to
cause the temperature of an object to increase.
How matter can possess energy?

How that energy can be transferred from one piece of matter


to another?
Energy Transformation: Kinetic Energy and Potential
Energy
 Kinetic energy, the energy of motion, Ek,of an object depends on its
mass, m, and speed, v:

 Potential energy is, in essence, the “stored” energy that arises from
the attractions and repulsions an object experiences in relation to
other objects.
 One of the most important forms of potential energy in chemistry is
electrostatic potential energy, Eel, which arises from the interactions
between charged particles.

 This energy is proportional to the electrical charges on the two


interacting objects, Q1 and Q2, and inversely proportional to the
distance, d, separating them:
 At the molecular level, the electrical charges Q1 and Q2 are typically
on the order of magnitude of the charge of the electron 1.60 x10-19
C2.

 The equation shows that the electrostatic potential energy goes to


zero as d becomes infinite. Thus, the zero of electrostatic potential
energy is defined as infinite separation of the charged particles.

 How Eel behaves as the distance between two charges changes?


 Many substances—fuels, for example—release energy when they
react. The chemical energy of a fuel is due to the potential energy
stored in the arrangements of its atoms.

 Chemical energy is converted to thermal energy, energy associated


with temperature.
Units of Energy

Joule (J) 1 J = 1 kg*m2/s2

Calorie (cal) 1 cal = 4.184 J

British Thermal Unit 1 Btu = 1055 J


The Law of Conservation of Energy
 When energy is converted from one form to the other, it is
conserved, not destroyed.

 Energy is often converted from one form to another during


transfers.
For example:
 Burning of gasoline in a car engine the reaction releases energy that
is transferred as heat and work.
 The heat warms the car parts.

 The work is done when mechanical energy turns the car's wheels and
belts.
 That energy is converted into the electrical energy of the sound
system, the radiant energy of the headlights, the chemical energy of
the battery, and so forth.
 The sum of all these forms equals the change in energy
between reactants and products as the gasoline is burned.
 Thus, energy changes form but does not simply appear or
disappear - energy cannot be created or destroyed.
 In another way, energy is conserved: the total energy of the
system plus the surroundings remains constant - Law of
conservation of energy.

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