Green Chemistry

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Industrial and Engineering Chemistry

CHD223
Green Chemistry

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What is Green Chemistry?
Green chemistry in very simple terms is just a different way of thinking about how
chemistry and chemical engineering can be done. Over the years different principles
have been proposed that can be used when thinking about the design, development
and implementation of chemical products and processes. These principles enable
scientists and engineers to protect and benefit the economy, people and the planet by
finding creative and innovative ways to reduce waste, conserve energy, and discover
replacements for hazardous substances.

It’s important to note that the scope of these of green chemistry and engineering
principles go beyond concerns over hazards from chemical toxicity and include
energy conservation, waste reduction, and life cycle considerations such as the use of
more sustainable or renewable feedstocks and designing for end of life or the final
disposition of the product.

Green chemistry can also be defined through the use of metrics. While a unified set
of metrics has not been established, many ways to quantify greener processes and
products have been proposed. These metrics include ones for mass, energy,
hazardous substance reduction or elimination, and life cycle environmental impacts.

NB: Green Chemistry is not politics. Green Chemistry is not a public


relations ploy.  Green chemistry is not a pipe dream. Source: ACS Chemistry of life
Green Chemistry?

Waste

Materials

Hazard

Risk

Energy

Cost
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Catalyst

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Basic components of Green Chemistry
Alternative feedstocks or starting Materials

Alternative reaction conditions

Alternative reagent or transformation

Alternative products and target molecules


Alternative Feedstocks or Starting Materials

Reducing the amount of the feedstock used


Reducing the intrinsic toxicity of the
feedstock though structural modification
Replacing the feedstock.
Example: Synthesis of Adipic Acid:
Supercritical fluid system
Because of  their low viscosities, SCFs can be transferred in pipelines and pumped to high pressures requiring less
mechanical energy than liquids and subcritical gases. Because the density of an SCF can be altered continuously by
manipulating pressure and temperature, the solvation ability of the fluid is tunable. Thus, selective dissolution of
solutes in a SCF may be achieved by optimizing the density of the fluid phase. This tunable solvation characteristic is
a unique property that makes SCFs different from conventional liquid solvents. The other important advantage of
SCF extraction is rapid separation of solutes that can be easily achieved by a reduction of pressure.
Examples of large-scale commercial applications of the supercritical fluid extraction technology include
crystallization,
• Hu et al. (2004), extraction of vitamins, natural flavors, perfumes, and essential oils from fruits and plants,
Mansoori et al. (1988) and
• Martinelli et al. (1991), removal of unwanted materials, such as caffeine and cholesterol from food products,
• Mohamad and Mansoori (2000), and pollution remediation using environmentally friendly supercritical fluids
Ekhtera et al. (1997).
Aqueous solvent system
Immobilized solvent materials
THANK YOU

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