Characteristics of Solutions

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Characteristics of a

Solutions
Mixtures – a review
• Mixture: a combination of two or more
substances that do not combine
chemically, but remain the same
individual substances; can be separated
by physical means.

• Two types:
– Heterogeneous
– Homogeneous
Heterogeneous Mixture
• “Hetero” means “different”

• Consists of visibly different substances or


phases (solid, liquid, gas)

• Can be separated by filtering

• Example:
Homogeneous Mixture
• “Homo” means the same
• has the same uniform appearance and
composition throughout; maintain one phase
(solid, liquid, gas)
• Commonly referred to as solutions
• Example:

Salt Water
2.1 The Characteristics of a Solution

A solution is a homogeneous mixture of two or more substances. A solution may


exist in any phase.

Characteristics of a Solution

A chemical solution exhibits several properties:

• A solution consists of a homogeneous mixture.

• A solution is composed of one phase (e.g., solid, liquid, gas).

• Particles in a solution are not visible to the naked eye.

• A solution does not scatter a light beam.

• Components of a solution cannot be separated using simple mechanical filtration.


Solution
• Solution: a mixture of two or more substances
that is identical throughout (homogeneous)
• can be physically separated Salt water is
• composed of solutes and solvents considered a
solution. How can it
be physically
separated?
the substance being dissolved
the substance that dissolves the solute

Iced Tea Mix Iced Tea Water


(solute) (solution) (solvent
)
2.2 Solution Terminology
Solute and Solvent - When one substance dissolves into another, a solution
is formed. A solution is a homogeneous mixture consisting of a solute
dissolved into a solvent . The solute is the substance that is being
dissolved, while the solvent is the dissolving medium. Solutions can be
formed with many different types and forms of solutes and solvents .
Types of Solutions

• Gaseous solutions – air = Oxygen + Nitrogen

• Liquid solutions – drinks = mix + water

• Solid solutions – alloys = steel, brass, etc


Concentration
• the amount of solute dissolved in a
solvent at a given temperature

• described as dilute if it has


a low concentration of solute
dissolved

• described as concentrated
if it has a high concentration
of solute dissolved
Concentration
• Unsaturated - has a less than the
maximum concentration of solute
dissolved

• Saturated - has the maximum


concentration of solute dissolved
(can see solid in bottom of
solution)

• Supersaturated -contains more


dissolved solute than normally
possible (usually requires an
increase in temperature followed
by cooling)
Solubility
• the amount of solute that
dissolves in a certain amount of a
solvent at a given temperature
and pressure to produce a
saturated solution
Factors affecting solubility of solids
Temperaturee Shaking
increased
temperature causes
solids to dissolve Shaking (agitation)
faster causes
solids to dissolve
faster
Particle Sizee
Smaller particles
dissolve
Faster because they
have
more surface area
Note: Increasing the amount of solute
DOES NOT increase the rate of dissolving
• Miscible liquids can easily dissolve in one
another.
• Immiscible liquids are not soluble in
each other.

Chemistry-Borders
Polarity and Dissolving
• Chemists use the saying
“like dissolves like”:
⮚Polar solutes tend to
dissolve in polar solvents.
⮚Nonpolar solutes tend to
dissolve in nonpolar
solvents.

Oil is nonpolar while water is


polar. They are immiscible.
READ ONLY SECTION:
● HOW DO SUBSTANCES DISSOLVE?
– “According to the kinetic theory, the water
molecules in each glass of tea are always
moving. Some moving water molecules collide
with sugar crystals. When this happens, energy
is transferred to the sugar molecules at the
surface of the crystal.”

– (Holt, p. 192)
The process of dissolution is
favored by:
● A decrease in the energy of the system
(exothermic)
● An increase in the disorder of the
system (entropy)
Liquids Dissolving in Liquids
● Liquids that are soluble in one another (“mix”)
are MISCIBLE.
– “LIKE dissolves LIKE”
● POLAR liquids are generally soluble in other
POLAR liquids.
● NONPOLAR liquids are generally soluble in
other NONPOLAR liquids.
Mass Percent

Chemistry-Borders IPC-Solutions-Borders
Mass Percent
• Solutions can also be represented as percent
of solute in a specific mass of solution.
• For a solid dissolved in water, you use percent
by mass which is Mass Percent.

• % by mass = mass solute x 100


mass of solution

**Mass of solution = solute mass + solvent mass


Example 1
• If a solution that has a mass of 800.0
grams contains 20.0 grams of NaCl,
what is the concentration using Percent
by Mass?
% by mass = mass solute x 100
mass of solution

% by mass = 20.0g NaCl x 100


800.0g solution
= 2.50% NaCl
Example 2
• If 10.0 grams of NaCl is dissolved in
90.0 grams of water, what is the
concentration using Percent by Mass?

% by mass = mass solute x 100


mass of solution 

% by mass = 10.0g NaCl x 100 = 10.0%NaCl


100.0g solution 
Example 3
• How many grams of sodium bromide are
in 200.0g of solution that is 15.0%
sodium bromide by mass?

% by mass = mass solute x 100


mass of solution 

% by mass = ? g NaBr x 100 = 15.0%NaBr


200.0g solution 

g NaBr = 200.0 x 15.0 = 30 g NaBr


100

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