Energetics

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Energy and Chemical Reactions

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Learning objectives

• To be to quantify the heat produced or absorbed during a reaction.


Heat and Temperature

• Heat is energy that is transferred from one object


to another due to a difference in temperature
• Temperature is a measure of how cold or hot a
body is
• Heat is always transferred from objects at a higher
temperature to those at a lower temperature

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Factors Affecting Heat Quantities
• The amount of heat contained by an object depends
primarily on three factors:
• The mass of material
• The temperature
• The kind of material and its ability to absorb or retain heat.

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Heat Quantities

• The heat required to raise the temperature of 1.00 g of water


1 oC is known as a calorie
• The SI unit for heat is the joule. It is based on the mechanical
energy requirements.
Where have you heard the word
• 1.00 calorie = 4.184 Joules

CALORIE?

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Calorie = energy

• https://www.youtube.com/watch?v=tEckkY2ogGs
• Storage of energy in human =
Calorimetry

• Calorimetry involves the measurement of heat


changes that occur in chemical processes or
reactions.
• The heat change that occurs when a substance
absorbs or releases energy is really a function of
three quantities:
• The mass
• The temperature change
• The heat capacity of the material

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Heat Capacity and Specific Heat
• The ability of a substance to absorb or retain heat varies
widely.
• The heat capacity depends on the nature of the material.
• The specific heat of a material is the amount of heat
required to raise the temperature of 1 gram of a substance
1 oC (or Kelvin)

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Specific Heat values for Some
Common Substances
Substance CJ g
-1
K-1 C J mol-1
K-1

Water (liquid) 4.184 75.327

Water (steam) 2.080 37.47

Water (ice) 2.050 38.09


Copper 0.385 24.47
Aluminum 0.897 24.2
Ethanol 2.44 112
Lead 0.127 26.4
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Heat Changes
The heat equation may be stated as

Q = m C T
where:
Q = Change in heat
m = mass in grams
C = specific heat in J g-1 oC-1
T = Temperature change

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Heat Transfer Problem 1
Calculate the heat that would be required an aluminum
cooking pan whose mass is 400 grams, from 20oC to 200oC. The
specific heat of aluminum is 0.902 J g-1 oC-1.

Solution
Q = mCT
= (400 g) (0.902 J g-1 oC-1)(200oC – 20oC)
= 64,944 J

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Heat Transfer Problem 2
What is the final temperature when 50 grams of water at
20oC is added to 80 grams water at 60oC? Assume that the
loss of heat to the surroundings is negligible. The specific
heat of water is 4.184 J/ g /oC
Solution: Q (Cold) = Q (hot) mCT= mCT
Let T = final temperature
(50 g) (4.184 J g-1 oC-1)(T- 20oC)
= (80 g) (4.184 J g-1 oC-1)(60oC- T)
(50 g)(T- 20oC) = (80 g)(60oC- T)
50T -1000 = 4800 – 80T
130T =5800
T = 44.6 oC
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