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Bonding Covalent CRG

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Covalent Bonding

As well as properties of ionic bonding


• Draw dot and cross diagrams
for the following ionic
compounds
• MgS: magnesium
sulfide
Starter • MgSe: magnesium
selenide
• CaCl: calcium chloride
• KBr: potassium bromide
• Li2O: lithium oxide
• Ionic compounds are made of charged particles
called ions which form a giant lattice structure
• Ionic substances have high melting and boiling
Properties – Giant points due to the presence of strong electrostatic
forces acting between the oppositely charged ions
ionic lattice • These forces act in all directions and a lot of energy
is required to overcome them
Properties
• Ionic compounds are usually solid at room temperature and are non-
volatile
• They have high melting and boiling points
• They are usually water soluble as both ionic compounds and water are
polar substances
• Polarity - in chemical bonding, the distribution of electrical charge
over the atoms joined by the bond.
• For electrical current to flow
there must be present freely
moving charged particles such
as electrons or ions
• Ionic compounds can conduct
Properties- electricity in the molten state or
conductivity in solution as they have ions
that can move and carry charge
• They cannot conduct electricity
in the solid state as the ions are
in fixed positions within the
lattice and are unable to move
Properties - EXTENTION
• Ionic substances have high melting and boiling points due to the presence
of strong electrostatic forces acting between the oppositely charged ions
• These forces act in all directions and a lot of energy is required to overcome them
• The greater the charge on the ions, the stronger the electrostatic forces and the
higher the melting point will be
• For example, magnesium oxide consists of Mg2+ and O2- so will have a higher
melting point than sodium chloride which contains the ions, Na+ and Cl-
• For electrical current to flow there must be freely moving charged particles such as
electrons or ions present 
• Ionic compounds are good conductors of electricity in the molten state or
in solution as they have ions that can move and carry a charge
• They are poor conductors in the solid state as the ions are in fixed positions within
the lattice and are unable to move
Covalent bonds
What is a covalent bond?

• Non-metal atoms can share electrons with other non-metal


atoms to obtain a full outer shell of electrons
• When atoms share pairs of electrons, they form covalent
bonds
• Covalent bonds between atoms are very strong
• When two or more atoms are chemically bonded together,
they form ‘molecules’
• Covalently bonded substances may consist of small
molecules or giant molecules
More about covalent bonds
• Weak intermolecular forces exist between individual molecules
• E.g. Each liquid water molecule consists of two hydrogen atoms
covalently bonded to an oxygen atom, and in between two
individual water molecules there are weak intermolecular forces
• Shared electrons are called bonding electrons and occur in pairs
• Electrons on the outer shell which are not involved in the
covalent bond(s) are called non-bonding electrons
• Simple covalent molecules do not conduct electricity as they do
not contain free electrons
• Covalent substances tend to have small
molecular structures, such as Cl2, H2O or
CO2
• These small molecules are known as simple
molecules
• Small covalent molecules can be
Covalent dot- represented by dot and cross diagrams
and-cross • You need to be able to describe and draw
the structures of the following molecules
using dot-and-cross diagrams: hydrogen
(H2), chlorine (Cl2), oxygen (O2), nitrogen
(N2), hydrogen chloride (HCl), water (H2O),
ammonia (NH3) and methane (CH4)
Practice Problems
• Easy – • Harder -
• H2 • Carbon dioxide
• Cl2 • Methane
• Ethane (C2H6)
• Medium –
• O2 • Challenge –
• Nitrogen (Remember diatomics) • Ethene (C2H4)
• Hydrogen Chloride • HCN (MOST DIFFICULT)
• Water
• ammonia

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