07 - Redox Reactions
07 - Redox Reactions
07 - Redox Reactions
AS/A2 - Chemistry
07 - Redox Reactions
01 – Learning Outcomes
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
Introduction
Some types of reactions can cost a lot of money due to the
damage they cause. Rusting is an oxidation reaction that
destroys about 20% of iron and steel every year. Rust is
hydrated iron(III) oxide. This forms when iron reacts with
oxygen in the presence of water.
Another costly example of oxidation is the
reaction between hydrogen and oxygen that
is used to propel some types of rockets into
space. In this reaction, the hydrogen is
oxidised – but the oxygen is also reduced. In
fact, oxidation and reduction always take place
together, in what we call redox reactions.
Questions
1. a. In each of the following equations,
state which reactant has been oxidised:
i. PbO + H2 → Pb + H2O
ii. CO + Ag2O → 2Ag + CO2
iii. 2Mg + CO2 → 2MgO + C
b. In each of the following equations, state
which reactant has been reduced:
i. 5CO + I2O2 → 5CO2 + I2
ii. 2H2S + SO2 → 3S + 2H2O
iii. CH ==CH + H → CH CH
02 – Redox and Electron Transfer
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
Balancing half-equations
► We can construct a balanced ionic equation
from two half-equations by balancing the
numbers of electrons lost and gained and then
adding the two half-equations together.
► The numbers of electrons lost and gained in a
redox reaction must be equal.
02 – Redox and Electron Transfer
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
WORKED EXAMPLES
1. Construct the balanced ionic equation for the reaction
between nickel and iron(III) ions, Fe3+, from the half-
equations:
Ni(s) → Ni2+(aq) + 2e–
Fe3+(aq) + e– →Fe2+(aq)
Each Ni atom loses two electrons when it is oxidised.
Each Fe3+ ion gains one electron when it is reduced.
So two Fe3+ ions are needed to gain the two electrons
lost when each Ni2+ ion is formed
2Fe3+(aq) + 2e– → 2Fe2+(aq)
Ni(s) → Ni2+(aq) + 2e–
The balanced ionic equation is:
Ni(s) + 2Fe3+(aq) → Ni2+(aq) + 2Fe2+(aq)
note how the electrons have cancelled out.
02 – Redox and Electron Transfer
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
WORKED EXAMPLES
2. Construct the balanced ionic equation for the reaction of iodide
ions (I–) with manganate(VII) ions (MnO4–) in the presence of
hydrogen ions (H+). Use the following two half-equations to
help you:
i. 2I–(aq) → I2(aq) + 2e–
ii. MnO4–(aq) + 8H+(aq) + 5e–→ Mn2+(aq) + 4H2O(l)
• When two iodide ions are oxidised, they lose two electrons.
Each MnO4– ion gains five electrons when it is reduced.
• So we must multiply equation i by 5 and equation ii by 2 to
balance the number of electrons:
10I–(aq) → 5I2(aq) + 10e–
2MnO4–(aq) + 16H+(aq) + 10e– →2Mn2+(aq) + 8H2O(l)
• The balanced ionic equation is:
2MnO4–(aq) + 10I–(aq) + 16H+(aq)
02 – Redox and Electron Transfer
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
Questions
2. a. Write two half-equations for the following
reactions. For each half-equation state whether
oxidation or reduction is occurring.
i. Cl2 + 2I– → I2 + 2Cl–
ii. 2Mg + O2 → 2MgO
iii. 4Fe + 3O2 → 2Fe2O3
b. Zinc metal reacts with IO3– ions in acidic
solution. Construct a balanced ionic equation
for this reaction, using the two half-equations
below:
2IO3– + 12H+ + 10e– → I2 + 6H2O
Zn → Zn2+ + 2e–
03 – Oxidation Numbers
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
Calculating
Numbers
03 – Oxidation Numbers
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
zero (rule 4)
ox. no. of two N atoms = –4
ox. no. of each N atom = –2
03 – Oxidation Numbers
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
Compound ions
► Compound ions are ions with two or more different
atoms. Examples are the sulfate ion, SO42–, and the
nitrate ion, NO3–. We use rule 5 to work out
the ox. no. that we do not know.
► Nitrate ion, NO3–
ox. no. of each O atom = –2
for three oxygen atoms = 3 × (–2) = –6
NO3– has a charge of 1–, so the total ox. no. of N
Questions
3. State the ox. no. of the bold atoms in
these compounds or ions:
a. P2O5
b. SO4
c. H2S2–
d. Al2Cl6
e. NH3
f. ClO2–
04 – Redox and Oxidation Number
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
Questions
4. a. Deduce the change in ox. no. for the bold
atoms or ions in each of the following
equations. In each case, state whether
oxidation or reduction has taken place.
i. 2I– + Br2 → I2 + 2Br–
ii. (NH4)2Cr2O7 → N2 + 4H2O + Cr2O3
iii. As2O3 + 2I2 + 2H2O → As2O5 + 2H+ + 4I–
iv. 2KMnO4 + 16HCl
→ 2MnCl2 + 2KCl + 5Cl2 + 8H2O
b. Identify the reducing agent in each of the
equations above.
05 – Naming Compounds
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
Naming compounds
► We sometimes use Roman numbers, in brackets, to
name compounds. We use these systematic names to
distinguish different compounds made of the same
elements. E.g., there are two types of iron chloride. We
show the difference by naming them iron(II) chloride
and iron(III) chloride. The numbers in brackets are the
oxidation numbers of the iron.
In iron(II) chloride, the ox. no. of the iron is +2. The
compound contains Fe2+ ions. The formula is FeCl2.
In iron(III) chloride, the ox. no. of the iron is +3. The
compound contains Fe3+ ions. The formula is FeCl3.
► We can also use oxidation numbers to distinguish
between non-metal atoms in molecules and ions.
05 – Naming Compounds
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
Questions
WORKED EXAMPLE
3. We can work out the formula of the chlorate(V) ion
from the oxidation numbers of oxygen and chlorine (let
n be the number of oxygen atoms):
ox. no.(Cl) + ox. no.(O) = –1
+5 n x (–2) = –1
n=3
So the chlorate(V) ion is ClO3– and sodium chlorate(V)
is NaClO3.
Questions
6. Give the formulae of:
a. sodium chlorate(I) c. iron(III) oxide
b. potassium nitrate(III) d. phosphorus(III)
07 – Balancing chemical equations using oxidation numbers
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
WORKED EXAMPLE
Step 2 Deduce the ox.
no. changes.
WORKED EXAMPLE
Step 3 The change in ox. nos. are –2 for the
copper and +3 for the nitrogen. To
balance the ox. no. changes, we need to
multiply the copper by 3 and the nitrogen
in the ammonia by 2. The total ox. no.
changes are then balanced (–6 and +6).
Note that we do not multiply the N2 by 2
because there are already two atoms of
nitrogen present. Once these ratios have
been fixed you must not change them.
07 – Balancing chemical equations using oxidation numbers
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
WORKED EXAMPLE
Step 4 Balance the atoms.
There are six hydrogen atoms in the
2NH3 on the left. These are
balanced with six on the right
(as 3H2O). This also balances
the number of oxygen atoms.
The final equation is
3CuO + 2NH → 3Cu + N + 3H O
07 – Balancing chemical equations using oxidation numbers
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
WORKED EXAMPLE
5. Manganate(VII) ions (MnO4–) react with Fe2+ ions in
the presence of acid (H+) to form Mn2+ ions, Fe3+ ions
and water.
Step 1 Write the unbalanced equation and identify the
atoms that change in ox. no.
MnO4– + Fe2+ + H+ → Mn2+ + Fe3+ + H2O
+7 –2 +2 +1 +2 +3 +1 –
2
Step 2 Deduce the
ox. no. changes.
07 – Balancing chemical equations using oxidation numbers
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
WORKED EXAMPLE
5.
Step 3 Balance the ox. no. changes.
07 – Balancing chemical equations using oxidation numbers
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
WORKED EXAMPLE
Step 4 Balance the charges.
Initially ignore the hydrogen ions, as these will
be used to balance the charges.
The total charge on the other reactants is:
(1–)(from MnO4–) + (5 x 2+)(from 5Fe2+)
= 9+
The total charge on the products is:
(2+)(from Mn2+) + (5 x 3+)(from 5Fe3+) =
17+
To balance the charges we need 8 H+ ions on
the left.
MnO4– + 5Fe2+ + 8H+ → Mn2+ + 5Fe3+ +
08 – Summary 2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
?
stage 1 stage 2 stage 3 stage 4
N2 → NH3 → NO → NO2 → HNO3
a. Give the oxidation number of the nitrogen atom in each
molecule.
[5]
b. For each stage, state whether oxidation or reduction has
taken place. In each case explain your answer.
[2]
c. Give the full systematic name for NO2.
[1]
d. Nitric acid, HNO3, reacts with red phosphorus.
08 – End of Chapter Questions
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
[1]
ii. calcium hydroxide.
[1]
08 – End of Chapter Questions
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
?
c. Write two half-equations for the reaction
between water and calcium hydroxide to show:
i. the change from calcium to calcium ions
[1]
ii. the change from water to hydroxide ions and
hydrogen.
[1]
d. In which one of the half-equations in part c is a
reduction occurring? Give a reason for your
answer.
08 – End of Chapter Questions
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
?
3. The unbalanced equation for the reaction of sulfur
dioxide with bromine is shown below.
SO2 + Br2 + H2O → SO42– + Br– + H+
a. State the oxidation number of sulfur in:
i. SO2 [1] ii. SO42–
[1]
b. State the oxidation number of bromine in:
i. Br2 [1] ii. Br–
[1]
c. Identify the reducing agent in this reaction. Give a
reason for your answer.
[1]
d. State the change in oxidation number for:
08 – End of Chapter Questions
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
?
4. Aluminium reacts with hydrochloric acid to form
aluminium chloride, AlCl3, and hydrogen. This is a
redox reaction.
a. Explain in term of electrons, what is meant by a redox
reaction.
[3]
b. i. Write a half-equation to show aluminium
changing to aluminium ions.
[1]
ii. Write a second half-equation to show what
happens to the hydrogen ions from the acid.
[1]
iii. What is the change in oxidation number when a
08 – End of Chapter Questions
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
[1]
ii. a S4O62– ion.
08 – End of Chapter Questions
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
?
c. When a salt containing iodide ions is warmed with
concentrated sulfuric acid and MnO2, iodine is evolved.
2I– + MnO2 + 6H+ + 2SO42–
→ I2 + Mn2+ + 2HSO4– + 2H2O
i. State the systematic name for MnO2.
[1]
ii. What is the oxidation number of S in the SO 42– ion?
[1]
iii. Which reactant gets oxidised in this reaction?
Explain your answer by using oxidation numbers.
08 – End of Chapter Questions
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
[1]
ii. KBr.
[1]
08 – End of Chapter Questions
2 – Electron
1 - Reactions 3 - Oxidation 4 – Redox Number 5 - Compounds 6 - Formulas 7 - Balancing 8 - Questions
transfer
?
d. When KBrO3 reacts with hydrazine, N2H4,
nitrogen gas is evolved.
2KBrO3 + 3N2H4 → 2KBr + 3N2 + 6H2O
i. What is the oxidation number change of the
bromine atom when KBrO3 is converted to
KBr?
[1]
ii. What is the oxidation number change for each
nitrogen atom when N2H4 is converted to N2?
[2]