CO2 EOR Modelling Using GEM - V3
CO2 EOR Modelling Using GEM - V3
GEM
Agenda
• Introduction, concepts for CO2-EOR.
• Lab experiments.
• Lab data and fitting EOS parameters.
• Slim tube simulations.
• Sweep efficiency and gravity segregation.
Tutorials
• Matching PVT experiments and swelling tests.
• Core-flood History Matching using GEM
• Full field History Match
• Predictions using WAG
• CO2 optimization using CMOST
Introduction
Concepts
Introduction
What is CO2-EOR?
• CO2-EOR is a technology that
MISCIBLE
targets the residual oil in depleted Pressure >> MMP
medium oil reservoirs by injecting
CO2 at miscible conditions.
MISCIBLE CONDITIONS
Introduction
Types of miscibility: First Contact (FCM)
• First contact (FCM).
When an injected fluid
• Multi-contact. becomes instantaneously
miscible with the reservoir oil,
the fluid is said to be ‘first
CO2
C1 D e v e lo p e d -
contact miscible’ (FCM) with
M is c ib ilit y
(V a p o riz in g
the reservoir oil at the
G a s D r iv e ) displacement conditions
(Mihcakan et al. 1993)
F ir s t- C o n ta c t
M is c ib ility
R E S . O IL
C 7+ C 2 -6
Introduction
Multiple contact.
• CO2 is not first contact miscible
process with most crude oils
within the reasonable range of
reservoir pressures.
mechanisms
Vaporization.
• The ability of dense-phase CO2 to
extract hydrocarbon components
from oil helps to promote dynamic Vaporization, Extraction or Condensing, and first
contact miscibility depends upon:
miscibility. • Reservoir pressure
• Availability of solvent
• Oil viscosity / API
Extraction. • Reservoir heterogeneity
• The ability of dense-phase CO2 to
extract hydrocarbon components Typical oil characteristics for vaporizing gas
from oil helps to promote dynamic drive:
Deep reservoirs/high pressure
miscibility.
Oil contains significant C2-6 fraction (volatile oil)
Multiple contact
mechanisms
line length
Oil Oil
process is characterized by a
two-phase pseudo-ternary INTERMEDIATES
envelope which does not close P(a) < P(b) < P(c)
Injection Gas
and has an hour glass shape
Oil
The pinching in the phase LIGHT HEAVY
envelope indicates a region of (c)
reduced IFT
Benefits of CO2 compared to
other gases
IN J E C T O R PR O DU CER
ne
le Z o
ank
C O2 R e s id u a l O il
O il B
ib
M is c
b) Gravity override
CO2 R e s id u a l O il
c) Viscous fingering
Most common situation CO2 R e s id u a l O il
due to low CO2 viscosity
Effect of Viscous and Capillary Forces on Sor
FO
DO M
ST
M
S O R /( S O R ) W
O
ER
O
BR O
RE
AB
&
RA
W SK
SL DU
MS
O PR
BO EY
TAB
0 .5
I & B
D
ER
R OW
Nc = Ratio of Viscous Energy/unit
N ELL
N o n w e ttin g R e s id u a l
W e ttin g R e s id u a l
area To Interfacial Energy/unit area 0
-8 -6 -4 -2 0
10 10 10 10 10
Low σ large Nc low Sor C A P IL L A R Y N U M B E R , N c
Differential Liberation
Properties of Liberated Gas
Pressure Cum. GOR(1) Shrinkage(2) Compressibility Viscosity
(psig) (SCF/BBL) (V/Vbp) Factor (cp)
(1) Barrels of residual oil at 60oF and 14.7 psia per barrel of oil at 256 oF and 2500 psig
Separator tests.
To help determine what is
optimum pressure to run
separator
Measured and Calculated BP’s
P r e s s u r e , p s ia
15 component model. 5 0 0 0 .0
4 0 0 0 .0
Regressed on compositions
for multi-contact process to 3 0 0 0 .0
% R E C O V E R Y A T 1 .2 H C P V O F C O 2 IN J E C T E D
90
I n i ti a lly in t e r p r e t e d t o b e
m i n i m u m m is c ib le p r e s s u r e
80
70
M is c ib le
60
Im m is c ib le
50
1000 1100 1200 1300 1400 1500 1600
T E S T P R E S S U R E ( P S IG )
Slim Tube Recoveries
1 0 0 .0
O il R e c o v e r y a t 1 . 0 P V In je c t e d , %
9 0 .0
8 0 .0
7 0 .0
15 C o m p o n e n ts ( IF T )
15 C o m p o n e n ts ( n o IF T )
6 0 .0
6 C o m p o n e n t s ( IF T )
E x p e r im e n ta l D a ta
5 0 .0
2 0 0 0 .0 4 0 0 0 .0 6 0 0 0 .0 8 0 0 0 .0
P r e s s u r e , p s ia
4
~ 1 S wc S org S g
krog
1 S wc S org
2
~ Sg
krg
1 S wc
IFT Effects on Rel. Perm. In GEM
With Swc = 0.0 and Sorg = 0.3. The previous relative permeability
curves are allowed to approach straight lines as the IFT is
lowered.
The following expressions are used:
~
k rog f krog 1 f S o
~
k rg f krg 1 f S g
f / ref 2
Where σ is the IFT between the oil and gas phase in mN.m
calculated from the Macleod-Sugden correlation and σref is the
reference interfacial tension, below which the effect of IFT on
relative permeability is taken into account
Ternary Diagram at 4015 psia
C7+
p = 4 0 1 5 p s ia
C H4 , C O2 , N 2 C2 - C 6
V a p o r (1 5 c o m p o n e n ts ) S o lv e n t
L iq u id (1 5 c o m p o n e n t s ) O il
x E x p e r im e n ta l d a ta
Ternary Diagram at 5091 psia
C7+
p = 5 0 9 1 p s ia
C H4 , C O2 , N 2 C2 - C 6
V a p o r (1 5 c o m p o n e n ts ) S o lv e n t
L iq u id (1 5 c o m p o n e n t s ) O il
Phase Density Profiles Along Slim Tube
8 0 0 .0
7 0 0 .0
3
P h a s e M a s s D e n s ity , k g /m
6 0 0 .0
5 0 0 .0
4 0 0 .0
3 0 0 .0
2 0 0 .0
In je c te d
H2 0
1 0 0 .0
0 .0 5 .0 1 0 .0 1 5 .0 2 0 .0 2 5 .0 3 0 .0 Sw + C O 2
D is ta n c e , fe e t
D C B A
Vapor L iq u id TW O PH ASE ZO N E
2 9 1 6 p s ia C O 2 S w o lle n C O 2 S w o lle n O il D is p la c e d S o lu tio n R e s e r v o ir
C O 2 D is s o lv e d in O il
4 3 6 6 p s ia R e s id u a l O il N e a rly M is c ib le G a s - I m m is c ib le F lu id
5 0 9 1 p s ia C O 2 In j e c t i o n w it h In je c t e d G a s w ith R e s e r v o ir F lu id
1
10
In te r fa c ia l T e n s io n , m N /m
0
10
1 0 -1
IF T P r o f ile s a t 0 .8 P . V . I n je c te d
2 9 1 6 p s ia
-2 3 8 5 8 p s ia
10
4 3 6 6 p s ia
5 0 9 1 p s ia
1 0 -3
0 .0 5 .0 1 0 .0 1 5 .0 2 0 .0 2 5 .0 3 0 .0
D i s ta n c e , fe e t
1 5 ,0 0 0 k P a 1 4 C o m p o n e n ts
9 6 .6 o C 6 C o m p o n e n ts
In je c tio n G a s
R e s e rv o ir O il
C1 , N 2, C O 2 C 6+
Principles of Miscible Flooding
Slim Tube Simulations and Effects of IFT
C2 - C5
1 9 ,0 0 0 k P a 1 4 C o m p o n e n ts
9 6 .6 o C 6 C o m p o n e n ts
In je c tio n G a s
R e s e r v o ir O il
C1 , N 2, C O 2 C 6+
Principles of Miscible Flooding
Slim Tube Simulations and Effects of IFT
C2 - C 5
1 5 ,0 0 0 k P a 1 4 C o m p o n e n ts
9 6 .6 o C 6 C o m p o n e n ts
In je c tio n G a s
R e s e r v o ir O il
C1 , N 2, C O 2 C 6+
Recap of Laboratory Data
The break in oil recovery for slim tube tests does not always indicate
thermodynamic miscibility
• Viscous fingering
• Slug size
• Displacement efficiency
Field Applications of Miscible Flooding - Target Oil
In general, water flooding and primary depletion give recoveries in the 20-40%
range, this means that 60-80% of the original oil is not recovered
Primary considerations
– Vertical permeability and solvent-oil segregation
– Reservoir heterogeneity (permeability distribution)
– Injectivity and productivity of wells
– Loss of miscibility pressure
– Inter-pattern flow
Secondary considerations
– Water blocking
– Viscous fingering
– Hysteresis in relative permeability
Miscible flooding simulation studies cannot take all factors into account
simultaneously, they must be studied in steps.
Field Applications of Miscible Flooding
Design and Prediction Considerations
Reservoir description
– Areal permeability distribution
– Vertical permeability distribution
– Distribution of fractures and faults
– Fluid distribution
– Injectivity and productivity
– Barriers
– Continuity
Sweep efficiency
– Gravity
– Viscous fingering
– Fractures
– Permeability stratification
– Mobility ratio
Sweep Efficiency
Field Applications of Miscible Flooding
Macroscopic View of Oil Recovery
In je c tio n In je c t io n
C O 2/
Use large scale models to s o lv e n t o il
•
Pattern influx / outflux
Field Applications of Miscible Flooding
Illustration of Types of Sweep Efficiency
P ro d u c e r I n je c t o r P ro d u c e r
B
A B
C r o s s S e c t io n a l V ie w
In je c to r A r e a l V ie w
A r e a l S w e e p E f f ic ie n c y V e r t ic a l S w e e p E f f ic ie n c y
Field Applications of Miscible Flooding
Sweep Efficiency
CO 2 INJECTOR WELLBORE
LOW PERMEABILITY
INTERMEDIATE PERMEABILITY
HIGH PERMEABILITY
LOW PERMEABILITY
INTERMEDIATE PERMEABILITY
Compositional Versus
Pseudo-Miscible Simulation
Field Applications of Miscible Flooding
Rule of thumb:
– When the process is first contact miscible use pseudo-miscible option
– When the process is multi-contact miscible with long transition zones use
compositional simulation
– When chase gas following solvent will cause loss of miscibility use
compositional model
– For volatile oils, use compositional simulator
Field Applications of Miscible Flooding
Choice of Simulators
Dilemma
– Use of compositional simulator is probably more rigorous but more intense
CPU use means that less geological heterogeneity can be accounted for
P s e u d o M is c i b le C o m p o s it i o n a l
P hase
G e o lo g y
B e h a v io r
+
V is c o u s
F in g e ri n g
Flow Regimes and
Gravity Segregation
Field Applications of Miscible Flooding - Flow Regimes
N o n - G r a v ity D o m in a te d
V e r tic a l F lo o d
Classification of miscible flooding
process according to impact of gravity
G r a v ity D o m in a te d
Field Applications of Miscible Flooding - Flow Regimes
G a s i n je c t e d a b o v e o i l -
o il p ro d u c e d fro m b e lo w
Vertical miscible flood illustration of a gravity
stabilized miscible flood
G as
O il
W a te r Z o n e
Schematic of Gravity Stabilized Flood
10% G as ( T r a ilin g E d g e )
9 0 % S o lv e n t
D ry G a s
M is c ib le
S lu g
q
< V c
O il A
9 0 % S o lv e n t ( L e a d in g E d g e )
1 0 % O il
O r ig in a l O il- W a t e r
In modelling vertical miscible floods, simulations require a large number of grid blocks in the
vertical direction to account for heterogeneity and mixing zone
Gravity Segregation in a Horizontal Reservoir
P VIS 2050q oL
P GR KAh
Gravity Segregation in a Horizontal Reservoir
Where:
A - Area, ft2
q - Flow rate, Res bbl/day (can't control that much)
µo - Oil viscosity, CP
L - Length, Ft
K - Absolute permeability, mD K K h xK v
∆ρ - Density difference, gm/cm3
h - Thickness, ft
For an un-isotropic system,
IN J E C T O R PR O D U C ER
S O LV EN T
O IL
H O R IZ O N T A L R E S E R V O IR
Gravity Override
100
C O N T A C T E F F IC IE N C Y A T B T , %
80
60
40
M = 5 .7 6
20
M =200
0
0 .1 1 10 100
( P )V IS
( P )G R
IN J E C T O R PRO D U C ER
LO W R ATES
L O W IN J E C T IO N R A T E S
IN J E C T O R PRO D U C ER
H IG H R A T E S
0 .6
C O2
0 .4
0 .2
N2
0
0 500 1000 1500 2000 2500
P R E S S U R E , P S IA