EE 152 Chapter 1
EE 152 Chapter 1
EE 152 Chapter 1
GIDEON ADOM-BAMFI
Course Content
Semiconductor
Semiconductor Operational
Materials and
Diodes & Amplifiers and
Properties Transistor as an
Applications Switching Theory
Amplifier
Semiconductor Bipolar
Diodes Junction
Transistor
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Course Objective:
The course is designed to give students knowledge in the analysis, selection,
biasing, and applications of semiconductor devices and circuits as well as the
design principles.
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Course Content
Grading System:
• Exams 70%
• Quizzes 5%
• Mid-Semester Exams 15%
• Lab Work 10%
Software: Multisim
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Recommended Textbooks
1. Electronic Principles by Albert Pual Malvino and David Bates
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1
SEMICONDUCTOR
MATERIALS AND
PROPERTIES
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1. CONDUCTORS, INSULATORS AND
SEMICONDUCTORS
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Electronic Materials
The goal of electronic materials is to generate and control the flow of an electrical
current.
Electronic materials can be classified into the following:
1. Conductors
Have low resistance which allows electrical current flow.
2. Insulators
have high resistance which suppresses electrical current flow.
3. Semiconductors
Can allow or suppress electrical current flow
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Conductors, semiconductors and insulators
The difference in the behaviour of electronic materials in terms of their conductivity can
be beautifully explained with the help of energy bands.
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Atomic Structure of Conductors
• The atomic structure of good conductors
usually includes only one electron in their
outer shell.
Copper Atom
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Insulators
• Insulators have a high resistance so current does not flow in them.
• The atoms are tightly bound to one another so electrons are difficult to
strip away for current flow.
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Semi-Conductors
• A semiconductor is a material with conducting properties between those
of a good insulator and a good conductor.
Questions
1. Why is Silicon the most widely used semiconductor?
2. Why is Silicon preferred to Germanium?
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Semi-Conductors Elements in the Periodic Table
Question
1. Why are Group 2 or
Group 6 elements not used
to dope semiconductors?
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Semi-Conductor Valence Orbit
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Crystal Lattice Structure
• A crystal is a substance whose atoms or
molecules are arranged in a ordered
pattern.
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Electronic Properties of Si
• Silicon is a semiconductor material.
• Pure Si has a relatively high electrical resistivity at room temperature.
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Semiconductors are classified into two types:
a) Intrinsic semiconductors
b) Extrinsic semiconductors
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Intrinsic Semiconductors
• A semiconductor is said to be intrinsic if it contains no impurities and no crystalline
defects.
• The structure has zero overall charge.
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Intrinsic Semiconductors
Behaviour at room or higher temperatures
• At room or higher temperatures, electrons acquire thermal energy, which is
transferred to them from the crystal lattice.
• The atoms in the crystal lattice vibrate, and these vibrations can be transmitted
through the crystal as acoustic waves called phonons.
• Phonons can excite electrons from the valence band (VB) to the conduction band
(CB).
• Electrons leaving the VB to CB creates a vacancy called hole in the valence band. A
hole is a vacancy in a covalent bond with a unit positive charge associated with it.
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Intrinsic Semiconductors
Behaviour at room or higher temperatures
• The electron is now free, and there is a free hole in the valence band.
• Every electron that escapes to conduction band creates a corresponding hole in the
valence band, creating an electron-hole pair.
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Intrinsic Semiconductors
• The free electrons in the semiconductor can fall into holes in a process known as
recombination.
• This is due to fact that when an electron makes a transition to the conduction band,
it leaves a hole behind in valence band .
• Thus the number of holes and electrons are equal, hence
np = ni2
• This equation is called as mass-action law.
• This equation is valid for extrinsic as well.
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Carrier Concentration in Intrinsic Si
The intrinsic carrier concentration ni depends on;
• the semiconductor material, and
• the temperature
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Doping
• To increase the conductivity of an intrinsic semiconductor, one can introduce an
impurity in a process known as doping.
• These impurities are atoms from column III or V of the periodic table. They are
referred to as dopants
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Extrinsic Semiconductors
• Intrinsic conduction is very small.
• Conductivity levels can be raised and controlled by doping with minute levels of
impurity atoms to give extrinsic or doped semiconductors.
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N-type Semiconductors
• This is formed by adding a pentavalent atom to the intrinsic semiconductor.
• These atoms with five valence electrons are known as donor atoms because they
provide an extra electron to the semiconductor’s crystal structure.
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N-type Semiconductors
• The energy needed to free the electron from its parent is usually small compared
to the thermal energy so each impurity atom contributes one hole for conduction
(fully ionised).
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P-type Semiconductors
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Electron and Hole Concentrations
Under thermal equilibrium conditions, the product of the conduction-electron
density and the hole density is ALWAYS equal to the square of n i:
np = ni2
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Question 1
▷
Calculate the hole and electron densities in a piece of p-type silicon that has been doped
with 5 × 1016 acceptor atoms per cm3. ni = 1.5 × 1010 cm3 (at room temperature).
Solution
P-type ; p ≫ n
np = ni2
NA = p = 5 × 1016 cm-3
n==
n = 4.5 × 103 electrons per cm3
NB: p ≫ ni and n ≪ ni in a p-type material. The more holes you put in the less electrons
you have and vice versa
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Carrier Movement
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1. Drift Current
2. Diffusion Current
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Carrier Movement
There are two mechanisms by which holes and free electrons move through a silicon
crystal.
Drift
The carrier motion is generated by the electrical field across a piece of silicon. This
motion will produce drift current.
Diffusion
The carrier motion is generated by the different concentration of carrier in a piece of
silicon. The diffused motion, usually carriers diffuse from high concentration to low
concentration, will give rise to diffusion current.
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Carrier Mobility
▷
Mobility
• Mobility is a measure of how easily a carrier moves in particular material.
• It is normally expressed in centimetres squared per volt-second (cm 2/Vs).
• Carrier mobility, µ = and it is the drift velocity per unit field.
Drift velocity
• Drift velocity is the average velocity with which the charge carriers drift in a definite
direction under the influence of an applied electric field.
• The unit of µ is = cm2/Vs
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1. Drift Current
• Drift current is produced by the motion of electrons and holes under an electric
field.
• The net current is always in the direction of applied electric field.
• The current due to both charges move in the same direction.
Idrift = In(drift) + Ip(drift)
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Current Density
•▷ In
a semiconductor, it is often more useful to talk about current density.
• Current Density (J) is the amount of charge crossing a plane unit area per unit time.
J=
• For a semiconductor with an applied electric field, the total drift current is:
Jdrift = Jn(drift) + Jp(drift)
Where
• Jn(drift)is the current due to electrons
• Jp(drift) is the current due to holes
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Conductivity
• When an electric field E is applied to a semiconductor, the free electrons drift with
average velocity ve = −µeE , where µe is the electron mobility.
• The holes drift with a velocity vh = +µhE, where µh is the hole mobility.
• Although the free electrons and holes drift in opposite directions, the current
densities add because the charge polarities are opposite.
• The electron charge density is ρe = −nq and the hole charge density is ρh = +pq,
where n and p represent the electron and hole concentrations respectively.
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Conductivity
• The total conduction current density can be written as:
Jdrift = ρeve + ρhvh = (nµe + pµp)qE = σE
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Conductivity
•▷ From
ohm’s law, the resistance R of a uniform sample of length L and cross-sectional
area A as illustrated in the semiconductor block below, is
R==
• Since the semiconductor is uniform, V = EL and using I = JA,
Jdrift = = σE
• where σ = is the conductivity.
• E is the electric field and ρ is the resistivity
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Example 2
A rod of intrinsic silicon is 1 cm long and has a diameter of 1mm. At room temperature,
the intrinsic concentration in the silicon is n i = 1.5 × 1016 per m3. The electron and hole
mobilities are µe = 0.13 m2V−1 s−1 and µh = 0.05 m2V−1 s−1.
Calculate the conductivity of the silicon and the resistance R of the rod.
Solution
The conductivity is calculated as follows:
σ = ni(µe + µh)q
σ = 1.5 × 1016 × (0.13 + 0.05) × 1.602 × 10-19
σ = 4.33 × 10-4 S/m
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▷
Solution
Resistance is calculated as:
R==
R = 29.4 MΩ
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Temperature sensitivity
• In both types of extrinsic semiconductor virtually all available charge carries are
freed from their parent atoms at room temperature.
• For intrinsic conductivity the number of carriers, and thus, increases rapidly with
temperature.
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2. Diffusion Current
• The directional movement of charge carriers due to their concentration gradient
produces a component of current known as diffusion current.
• With no applied voltage, if the number of charge carriers (either holes or electrons)
in one region of a semiconductor is less compared to the rest of the region, then
there exists a concentration gradient.
• As a result, the carriers tend to move gradually or diffuse from the region of higher
concentration to the region of lower concentration.
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2. Diffusion Current
• This process is called diffusion and electric current produced due to this process is
called diffusion current.
• This process continues until all the carriers are evenly distributed through the
material.
• Hence when there is no applied voltage, the net diffusion current will be zero.
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2. Diffusion Current
• In general, the hole diffusion current density is given by:
Jp(diff) = − qDh∇p
• Where Dh is the hole diffusion constant and ∇p is the gradient of p
• Similarly, the electron diffusion current density is given by
Jn(diff) = + qDe∇n
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Total Current
The total current in a semiconductor = the electron and hole drift currents + the
electron and hole diffusion currents.
Jtotal = Jdrift + Jdiffusion
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Carrier Lifetime /Mean Lifetime
• Because hole-electron pairs are continually created by thermal agitation of a
semiconductor lattice, it might seem that the number of holes and free electrons
would continually increase with time.
• This does not happen because free electrons are continually recombining with holes.
• At any temperature, a stable state is reached when the creation rate of hole-electron
pairs is equal to the recombination rate.
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Carrier Lifetime /Mean Lifetime
• The mean lifetime 𝜏n of a free electron is the average time that the electron exists in
the free state before recombination.
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Terminologies
Donor Majority carrier
Impurity atom that increases n The most abundant carrier
Minority carrier
Acceptor the least abundant carrier
Impurity atom that increases p
Intrinsic semiconductor
n = p = ni
N-type material
Contains more electrons than holes Extrinsic semiconductor
Doped semiconductor
P-type material
Contains more holes than electrons
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Summary
• In its pure state, semiconductor material is an excellent insulator.
• The heavier the doping, the greater the conductivity or the lower the resistance.
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Thanks!
Any questions?
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