Classification of Emulsions

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Classification of Emulsions

BY : AIMAN HAMEED
Classification of Emulsions

Simple Multiple Micro


Emulsions Emulsions Emulsions
1. Simple Emulsions
• Also known as macro emulsions
• Droplet size 0.2mm to 50mm

Types

i. Oil in Water Emulsions (O/W)


ii. Water in Oil Emulsions (W/O)
Differences between O/W and W/O
Oil in Water Emulsions Water in Oil Emulsions
Dispersion Medium: Water Dispersion Medium: Oil
Dispersed Medium: Oil Dispersed Medium: Water
Non greasy Greasy
Easily removable from skin Non water washable
Used externally to provide cooling effect Used externally to prevent evaporation of moisture
e.g. Vanishing creams from surface of skin
e.g. Cold Creams
Preferred for internal use as bitter taste of oils can Preferred for external use only
be masked
Gives positive conductivity as water is the external Do not give positive conductivity test as oil is the
phase external phase
2. Multiple Emulsions

• Emulsion systems in which the dispersed phase contain smaller droplets that have the same composition
as the external/ dispersion phase

Types
i. Oil-in-Water-in-Oil (O/W/O) emulsion system
ii. Water-in-Oil-in-Water (W/O/W) emulsion system

Oil-in-Water-in-Oil Water-in-Oil-in-Water
In O/W/O system, an aqueous phase (hydrophilic) In W/O/W system, an organic phase (hydrophobic)
separates internal and external oil phase. separates internal and external aqueous phase.

A system in which water droplets are surrounded A system in which oil droplets are surrounded by
by oil phase, which encloses one or more oil aqueous phase, which encloses one or several water
droplets. droplets.
3. Micro emulsions
• Droplet size 10-100nm
• A thermodynamically stable dispersion consisting of
Advantages
 Oil
 Surfactant • Increase the rate of absorption
 Co-surfactant • Increase bio-availability
 Water
• Helpful in taste masking
Types • Eliminates variability in absorption

i. Oil in Water Emulsions (O/W)


ii. Water in Oil Emulsions (W/O)
Difference between Macro emulsion and Micro emulsion
Features Micro emulsions Macro emulsions

Droplet diameter 10-100nm 1-20mm

Appearance Transparent Opaque (White)

Stability Thermodynamically stable Kinetically stable

Preparation Generally obtained by general Require intense agitation for their formation
mixing of the ingredients

Surfactant 6-8% by weight 2-3% by weight


concentration

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