THERMOLUMINESCENCE

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FLUORESCENCE PHOSPHORESCENCE

- The emission of light by a substance which has absorbed light or other - Phosphorescence is a specific type of photoluminescence related to fluorescence.
electromagnet radiation - A process in which energy absorbed by a substance is released relatively slowly in the form of light.
- It is one type of luminescence and occurs in different form which is solid, liquid and - Phosphorescence is a light energy produced by a particular type of chemical reaction where the excess
gas. chemical energy of the reactants is given off as light energy.
- It also has a much longer wavelength then compared to absorbed radiation and - Phosphorescence materials store and re-emit light because of their usual property of trapping electrons in a
contain low of energy. higher state of movement.
- Flourescence materials cease to glow almost instantly when the radiation source - Examples of phosphorescence materials:
stops. i) In sea creatures:
- The most common application is in energy-saving fluorescence lamps and LED Jellyfish, as well as various species of worms, shrimp,
lamps. and squid, all produce their own light through
- Fluorescence also can be occurs often in nature like minerals & biological forms phosphorescence
across all kingdoms of life. Sometimes this is called biofluorescence. ii) glow-in-the-dark stars
iii) some safety signs
iv) glowing paint

DIFFERENT OF PHOSPHORENCENCE AND FLUORESCENCE


THERMOLUMINESCENCE
Phosphorencence Fluorescence - Is a form of luminescence that is exhibited - A thermoluminescent dosimeter (TLD), is a passive radiation
by certain crystalline materials, such as dosimeter, that measures ionizing radiation exposure by
Change in electron spin Involves a change in Do not involve change in
electron spin electron spin some minerals. measuring the intensity of visible light emitted from a sensitive
- - When exposed to electromagnetic crystal in the detector when the crystal is heated. The intensity
radiation or other ionizing radiation, it of light emitted is measure by TLD reader and it is dependent
Excited state lifetime Longer lived, continues Short lived, occurs very absorb energy from it. Some energized upon the radiation exposure.
long after photoexcitation short after photoexcitation electrons trapped in defects the molecular
crystal structure.
Glow Afterglow with fractions of The glow stops right after - The electrons cannot escape because
a second up to hours can the source radiation is don’t have enough energy.
occur switched off - When heated, (about °C), the electrons
gets excited and energized, the electrons
return to normal position (escape).
Release of absorbed light Delayed and occurs at a Spontaneously emitted - Resulting release of energy as light
slower rate seconds after excitation
(emission of Light).
- Longer time exposed to radiation, more
Transition of electron back Forbidden or highly Occur spontaneously
to ground level improbable, electron stays electrons get trapped then, Greater the
until it makes a forbidden intensity off energy release (light) when
transition or until further heated.
excited - TL seems to have been discovered by
Robert Boyle who, in 1663
Energy of radiation Intermediate energy which Lower energy - Useful of dating various minerals and
is a metastable level archaeological artifacts
interposed between
ground and excited level

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