General Chemistry 2 - Introduction of The Subject

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This 

course covers laboratory aspects of the


fundamental facts, laws, principles, theories
and concepts of chemistry necessary for
further work in science or science-related
General subjects.

Chemistry General chemistry courses typically


2 introduce concepts such as
stoichiometry, prediction of reaction
products, thermodynamics,
nuclear chemistry,
electrochemistry, chemical kinetics, and
many of the rudiments of
physical chemistry.
Chemistry is the science of making things
and transforming things. Chemistry is often
called the central science because it
connects so strongly to other sciences,
among them physics, biology, engineering,
medicine, materials science, and
pharmacology.
Overview: In Chemistry 2 students will build on
concepts from Chemistry 1 as they explore
characteristics of chemical reactions related
to chemical kinetics, chemical equilibrium,
acid/base and organic chemistry,
thermodynamics, and electrochemistry.
The properties of liquids
and solids to the nature
of forces between
Content particles
Standard:
2. Phase changes in
Week 1 terms of the
accompanying changes in
energy and forces
between particles
1. Use the kinetic molecular model to
explain properties of liquids.
2. Describe and differentiate the types of
intermolecular forces.
3. Describe the following properties of
Most Essential liquids and explain the effect of
Learning intermolecular forces on these
properties : surface tension, viscosity,
Competencies_Wee vapor pressure, boiling point, and
k1 molar heat of vaporization.
4. Explain the properties of water with its
molecular structure and intermolecular
forces
5. Describe the difference in structure of
crystalline and amorphous solids
Content
Standard:
Week 2
and Week PROPERTIES OF SOLUTIONS, ENERGY CHANGES IN CHEMICAL

3 SOLUBILITY, AND THE STOICHIOMETRY


OF REACTIONS IN SOLUTIONS
REACTIONS
Most Essential Learning
Competencies_Week 2
Interpret the phase diagram of water and carbon dioxide Week

Determine and explain the heating and cooling curve of a substance

Use different ways of expressing concentration of solutions: percent by mass, mole fraction,
molarity, molality, percent by volume, percent by mass, ppm

Perform stoichiometric calculations for reactions in solution

Describe the effect of concentration on the colligative properties of solutions


Differentiate the colligative properties of nonelectrolyte
Differentiate solutions and of electrolyte solutions

Calculate boiling point elevation and freezing point depression


Calculate from the concentration of a solute in a solution
Most Essential
Learning
Competencies_Week
3
Calculate Calculate molar mass from colligative property data

Describe laboratory procedures in determining concentration


Describe of solutions
5. EXPLAIN ENTHALPY OF A REACTION 6. CALCULATE THE CHANGE IN
ENTHALPY OF A GIVEN REACTION USING
HESS LAW
the rate of a reaction
and the various
factors that influence
Content it
Standard:
Week 4
The collision theory
DESCRIBE HOW VARIOUS DIFFERENTIATE ZERO, FIRST-, EXPLAIN REACTIONS
FACTORS INFLUENCE THE AND SECOND-ORDER QUALITATIVELY IN TERMS OF
Most Essential RATE OF A REACTION REACTIONS MOLECULAR COLLISIONS

Learning
Competencies_Week
4

EXPLAIN ACTIVATION CITE AND DIFFERENTIATE


ENERGY AND HOW A THE TYPES OF CATALYSTS
CATALYST AFFECTS THE
REACTION RATE
Grades Evaluation of
your learning
• Your scores are always available to
you RIGHT after the test via
quiziz.com. There are no
opportunities for extra credit. You
must successfully complete the
assignments to receive a passing
grade in this course.
Academic Integrity
We expect all students to conduct themselves
with honesty, integrity, and professionalism.
Remember that it is not ok to simply copy and
paste material from the Web or from another
student into your own work.

Passing off someone else's lab reports or exam answers as your own
work is academic misconduct. Misrepresenting your class attendance
by asking a student to answer Test questions for you when absent
from class or by answering questions remotely while not in class is
also academic misconduct. Submitting an altered exam question for
regrading is academic misconduct. Such behavior is not tolerated and
is grounds for a failing grade in this course and other disciplinary
actions.
Make-up exams
• There are no make-up exams given in this
course. If you have a family emergency or
other extenuating circumstances that
might impact your ability to sit for an
exam, please talk to or chat your
instructor as soon as possible.
Student Contract
You will I have read and understand the expectations of this subject. I
be asked understand that I am expected to contribute to a productive
atmosphere, to show respect to my peers, to be responsible for my
to agree work and my preparation for deadlines, and to ask for clarification when
I need it.
to the
I expect to participate fully in an engaging learning experience in
following Chemistry 2 and to optimize the learning opportunities available to me.
contract
Finally, in all virtual meetings of this course, I will contribute to positive
classroom etiquette by:

being seated before the bell rings

refraining from packing up until after the classis over, even if the bell
rings(this will not happen often)

using my phone for texting or using my phone for other reasons.


Lesson 1: Kinetic Molecular
Model of Liquids and Solids . .

At the end of the lesson, the learners


will be able to:
1. apply the kinetic molecular theory
to describe liquids and solids
2. identify the types of intermolecular
forces that may operate in each
molecular substance
Vocabulary:
• Phase -A homogeneous part of a system in
contact with other parts of the system, but
separated from t h e s e other parts by well-
defined boundaries.
• Condensed phases -Liquids and solids
• Intramolecular forces – Intermolecular forces are
attractive forces between molecules.
• Intermolecular forces -hold atoms together in a
molecule.
1. All matter is made of tiny particles.

2. These particles are in constant motion.

Kinetic 3. The speed of particles is proportional to temperature.


Molecular Increased temperature means greater speed.

Theory 4. Solids, liquids, and gases differ in distances between


particles, in the freedom of motion of particles, and in the
extent to which the particles interact.
5. For an animation showing the motion of particles in a
solid, liquid or gas, the lesson below may be viewed.
http://preparatorychemistry.com/KMT_fla
sh.htm
a. Compare the distances among molecules in the gas,
liquid and solid and rank the phases in increasing distance
Compare the between particles.
properties of b. Describe the characteristic movement of the particles of
gases, liquids, gas, liquid and solid.

and solids in c. How are the molecules of gas, liquid and solid arranged?
terms of
distances and d. Arrange the three phases of matter in order of increasing
arrangement volume of empty space between its molecules.
of their
e. Identify the property of matter that corresponds to the
molecules molecular behavior.
Use the table to present the comparison of
the properties of gases, liquids and solids.
Materia's:
• Water
Laboratory:Kineti • Acetone
c Molecular • ethanol
Theory of Liquids • Medicine dropper
and Solids
Questions to investigate:
• 1. How many drops of liquid can a 25-cent coin hold?
• 2. How long will it take for one drop of a liquid to
evaporate?
The activity should be performed in an airy or
well-ventilated room. Use proper handling of
the substances you will be using. Avoid contact
with the skin and direct inhalation of the vapors
of the substances. It is best if you use safety
gloves, goggles and mask.

Safety 1. Work in groups of 4 members.


2. Acetone and ethanol can be purchased as
Precautions: aqueous solutions. Pure or absolute
samples are expensive. The presence of
water in these samples may affect the
results, particularly the evaporation part.
3. Prepare the labeled vials with the liquid
before the start of the activity. Make sure
that you label the droppers they will be
using with the liquid it is intended for so
that contamination or mixing is avoided.
5.Paper or paper towels are useful in these types of activities.
Place the coin on top of a sheet of paper or paper towel, coin
and 4 droppers.
6. Drop each liquid on a 25-centavo coin and count the number
of drops the coin can hold.
7. Then on the next 4 coins, put a drop of the liquid and
determine how much time it takes one drop to evaporate.
8.Record your results.
Answer the following questions:

a. Which molecules can hold more drops on the


coin?
b. Which molecules took longer to evaporate?
c. Are the molecules that can hold the lesser number
of drops the same as the molecules that took less
time to evaporate?
d. Are the molecules that can hold more drops on
the coin polar or nonpolar? What about those that
took longer to evaporate?
What holds the particles in the solid and
liquid states?
• Intermolecular forces are attractive forces that act between
molecules or particles in the solid or liquid states. Generally, these
attractive forces are much weaker than bonding forces.
The different types of
intermolecular forces
are the following:
• Dispersion forces –
these forces of
attraction result from
temporary dipole
moments induced in
ordinarily nonpolar
molecules.
Dipole-dipole
forces

• Are attractive
forces between
polar molecules
(molecules that
possess dipole
moments).
Hydrogen bond

• A special type of dipole-dipole interaction between the


hydrogen atom in a polar bond, such as N‒H, O‒H, or F‒
H, and an electronegative O, N, or F atom. Hydrogen
bonds between water molecules are particularly strong.
• The interaction is written as A ‒ H ••• B or A ‒ H ••• A

A and B represent O, N, or F; A ‒ H is one molecule or part of a


molecule and A or B is a part of another molecule; the dotted
line represents the hydrogen bond.

• Examples of hydrogen bonding in water (H2O), ammonia


(NH3) and hydrogen fluoride (HF):
Schematic diagram for determining intermolecular forces
in a substance

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