Chembond

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Atom – the smallest unit of matter “indivisible”

Helium
atom
electron shells
a) Atomic number = number of Electrons

b) Electrons vary in the amount of energy


they possess, and they occur at certain
energy levels or electron shells.

c) Electron shells determine how an atom


behaves when it encounters other atoms
Electrons are placed in shells
according to rules:
1) The 1st shell can hold up to two electrons,
and each shell thereafter can hold up to 8
electrons.
Octet Rule = atoms tend to gain, lose or share electrons so
as to have 8 electrons
C would like to Gain 4 electrons
N would like to Gain 3 electrons
O would like to Gain 2 electrons
Why are electrons important?
1) Elements have different electron
configurations
 different electron configurations mean
different levels of bonding
Electron Dot Structures
Symbols of atoms with dots to represent the valence-
shell electrons

1 2 13 14 15 16 17 18
H He:
      

Li Be  B  C  N  O : F  :Ne :


    

      

Na Mg  Al  Si   P S


  :Cl  :Ar :
    
Learning Check

A. X would be the electron dot formula for
1) Na 2) K 3) Al

B. X would be the electron dot formula

1) B 2) N 3) P
Chemical Bond
• A bond results from the attraction of nuclei
for electrons
– All atoms trying to achieve a stable octet

• IN OTHER WORDS
– the p+ in one nucleus are attracted to the e- of
another atom
• Electronegativity
Two Major Types of Bonding

• Ionic Bonding
– forms ionic compounds
– transfer of e-

• Covalent Bonding
– forms molecules
– sharing e-
One minor type of bonding
• Metallic bonding
– Occurs between like atoms of a metal in the
free state
– Valence e- are mobile (move freely among all
metal atoms)
– Positive ions in a sea of electrons

• Metallic characteristics
– High mp temps, ductile, malleable, shiny
– Hard substances
– Good conductors of heat and electricity as (s) and (l)
It’s the mobile electrons
that enable me-tals to
conduct electricity!!!!!!
IONIC BOND
bond formed between
two ions by the
transfer of electrons
Formation of Ions from Metals
 Ionic compounds result when metals react with
nonmetals
 Metals lose electrons to match the number of valence
electrons of their nearest noble gas
 Positive ions form when the number of electrons are
less than the number of protons
Group 1 metals  ion 1+
Group 2 metals  ion 2+
• Group 13 metals  ion 3+
Formation of Sodium Ion
Sodium atom Sodium ion
Na  – e  Na +

2-8-1 2-8 ( = Ne)

11 p+ 11 p+
11 e- 10 e-
0 1+
Formation of Magnesium Ion
Magnesium atom Magnesium ion

Mg  – 2e  Mg2+

2-8-2 2-8 (=Ne)

12 p+ 12 p+
12 e- 10 e-
0 2+
Learning Check

A. Number of valence electrons in aluminum


1) 1 e- 2) 2 e- 3) 3 e-

B. Change in electrons for octet


1) lose 3e- 2) gain 3 e- 3) gain 5 e-

C. Ionic charge of aluminum


1) 3- 2) 5- 3) 3+
Solution

A. Number of valence electrons in aluminum


3) 3 e-

B. Change in electrons for octet


1) lose 3e-

C. Ionic charge of aluminum


3) 3+
Learning Check

Give the ionic charge for each of the following:


A. 12 p+ and 10 e-
1) 0 2) 2+ 3) 2-
B. 50p+ and 46 e-
1) 2+ 2) 4+ 3) 4-
C. 15 p+ and 18e-
2) 3+ 2) 3- 3) 5-
Ions from Nonmetal Ions

In ionic compounds, nonmetals in 15, 16, and 17


gain electrons from metals

Nonmetal add electrons to achieve the octet


arrangement

Nonmetal ionic charge:


3-, 2-, or 1-
Fluoride Ion
unpaired electron octet
  1-
:F + e : F:
 

2-7 2-8 (= Ne)

9 p+ 9 p+
9 e- 10 e-
0 1-
ionic charge
IONic Bonding

• electrons are transferred between valence


shells of atoms
• ionic compounds are
made of ions NOT MOLECULES

• ionic compounds are called Salts or


Crystals
IONic bonding
• Always formed between metals and non-
metals

[METALS ]+ [NON-METALS ]-

Lost e- Gained e-
IONic Bonding
• Electronegativity difference > 2.0
– Look up e-neg of the atoms in the bond and
subtract
NaCl
CaCl2
• Compounds with polyatomic ions
NaNO3
Ionic Bonds: One Big Greedy Thief Dog!
1). Ionic bond – electron from Na is transferred to Cl,
this causes a charge imbalance in each atom. The Na
becomes (Na+) and the Cl becomes (Cl-), charged
particles or ions.
Properties of Ionic Compounds
SALTS
• hard solid @ 22oC Crystals
• high mp temperatures
• nonconductors of electricity in solid phase
• good conductors in liquid phase or
dissolved in water (aq)
COVALENT BOND
bond formed by the
sharing of electrons
Covalent Bond
• Between nonmetallic elements of similar
electronegativity.
• Formed by sharing electron pairs
• Stable non-ionizing particles, they are not
conductors at any state
• Examples; O2, CO2, C2H6, H2O, SiC
Bonds in all the
polyatomic ions
and diatomics are
all covalent bonds
NONPOLAR
COVALENT BONDS
when electrons are
shared equally
H2 or Cl2
2. Covalent bonds- Two atoms share one or more pairs of outer-shell
electrons.

Oxygen Atom Oxygen Atom

Oxygen Molecule (O2)


POLAR COVALENT
BONDS
when electrons are
shared but shared
unequally
H2O
Polar Covalent Bonds: Unevenly
matched, but willing to share.
- water is a polar molecule because oxygen is more
electronegative than hydrogen, and therefore electrons
are pulled closer to oxygen.
METALLIC BOND
bond found in
metals; holds metal
atoms together
very strongly
Metallic Bond
• Formed between atoms of metallic elements
• Electron cloud around atoms
• Good conductors at all states, lustrous, very
high melting points
• Examples; Na, Fe, Al, Au, Co
Metallic Bonds: Mellow dogs with plenty
of bones to go around.
Ionic Bond, A Sea of Electrons
Metals Form Alloys
Metals do not combine with metals. They form
Alloys which is a solution of a metal in a metal.
Examples are steel, brass, bronze and pewter.
Formula Weights
• Formula weight is the sum of the atomic
masses.
• Example- CO2
• Mass, C + O + O
12.011 + 15.994 + 15.994
43.999
Practice
• Compute the mass of the following compounds
round to nearest tenth & state type of bond:
• NaCl;
• 23 + 35 = 58; Ionic Bond
• C2H6;
• 24 + 6 = 30; Covalent Bond
• Na(CO3)2;
• 23 + 2(12 + 3x16) = 123; Ionic & Covalent
Some Typical Ions with Positive
Charges (Cations)
Group 1 Group 2 Group 13
H+ Mg2+ Al3+
Li+ Ca2+
Na+ Sr2+
K+ Ba2+

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