Transition Metals 1

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Thursday, March 18, 2

Transition metal electron


configurations
Learning objectives.
I will know that transition metals are d-
block elements that form one or more stable
ions with incompletely filled d-orbitals
Be able to deduce the electronic
configurations of atoms and ions of the d-
block elements of period (Sc-Zn) given
atomic number and charge(if any)
I will be able to explain why transition
metals show variable oxidation numbers
What are transition
metals?
What is the definition of a transition
element?
Do all of the d-
The effective definition is: an element
block elements in
which forms one or more stable ions period 4 have all
which have incompletely filled d sub- of these
characteristics?
shells.
What properties do transition metals
have in common?
They are hard metals, with high melting
and boiling temperatures; they have
more than one oxidation number in their
compounds; form coloured compounds;
show catalytic activity.Is a d-block element and a
transition metal the same
thing?
Electron configurations.
Write down the electron configurations Show the 3d
and 4s electron
for the first row of transition metals, in box
using s, p, d, f notation. configuration
Why is the next orbital to be filled not for the first row
of the d-block
4p? elements
Is the filling of the d orbital
straightforward?
No. A stable energy sub-shell is always
desired. This means that electrons will
provide the most stability. When losing
electrons the 4s electrons go first.

Be careful with Chromiun and Copper!


Electronic configurations of d-block
elements in period 4
Common oxidation numbers and compounds
for period 4 transition metals

Which oxidation states are most common?


Why do you think this could be? (What electrons are
lost?)
How can Manganese be at a 7+ oxidation state?
Which electrons must be used for this to occur?
Knowledge check

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