Analyti Cal Inst Rument S
Analyti Cal Inst Rument S
L IN ST R
A L YT IC A
AN
ANALYTICAL INSTRUMENTS
• In mineral processing, there are several analytical
instruments used for various purposes; such as the
following
1. X-ray fluorescence (XRF)
2. X-ray diffraction (XRD)
3. Scanning electron microscopy (SEM)
4. Transmission electron microscopy (TEM)
5. Raman spectroscopy
6. Fourier Transform Infrared (FTIR)
7. Atomic absorption spectroscopy (AAS)
8. Inductively Coupled Plasma (ICP)
X-ray diffraction (XRD)
• The atomic planes of a crystal cause an incident
beam of Xrays to interfere with one another as they
leave the crystal. The phenomenon is called X-ray
diffraction.
(010)
Atomic Planes
(hkl)
d-interspacing
distance
where n (an integer) is the "order" of reflection, λ is the wavelength of the incident X-
rays, d is the interplanar spacing of the crystal and Θ is the angle of incidence.
Derive Bragg’s law
xy + yz = nλ ……… (1)
Substitute xy & yz
xy + yz = nλ ……… (1)
dSin Ө + dSin Ө = nλ
λ
}
Ө Ө
Ө Ө
d d
X Z
Ө Ө
Y
Ө Sin Ө = Opp/Hyp Sin Ө =
Ө
Sin Ө = xy/d Opp/Hyp
X d xy = dSin Ө Sin Ө = yz/d
d
z yz = dSin Ө BRAGG’S LAW
Y Y 2dSinӨ = nλ
BRAGG’S LAW
Typical questions
2dSinӨ = nλ
1. X-ray with wavelength of 125 pm (peak meters) was used to
study a crystal which was produced a reflection at an angle
of 17.4 degrees . Assuming first order diffraction, what is the
distance between planes of atoms
2. The second order diffraction for a certain crystal was 18.4
degrees using X-ray with a wavelength of 1.42 angstrom.
What is the interplanar spacing of atoms in this crystal?
3. Crystal XYZ has an interplanar spacing of 94.3 pm. Using first
order diffraction, what is the X-ray wavelength that should
be used to produce a reflaction with an angle of 19.5 degrees
Answ: λ= 62.96
X-ray Powder Diffraction (XRD) Instrumentation - How
Does It Work?