Under The GHS, Proper Labeling Is Composed of The Following Elements and Their Respective Definitions
The document discusses the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) which provides standardized labels and safety data sheets to communicate chemical hazards. It outlines the key elements of GHS labels including signal words, hazard statements, pictograms, and supplier information. The document also discusses operational controls for chemical management including elimination, substitution, engineering controls like ventilation, and administrative controls. Emergency response plans and equipment for fires, spills, and medical emergencies are also outlined.
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Under The GHS, Proper Labeling Is Composed of The Following Elements and Their Respective Definitions
The document discusses the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) which provides standardized labels and safety data sheets to communicate chemical hazards. It outlines the key elements of GHS labels including signal words, hazard statements, pictograms, and supplier information. The document also discusses operational controls for chemical management including elimination, substitution, engineering controls like ventilation, and administrative controls. Emergency response plans and equipment for fires, spills, and medical emergencies are also outlined.
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Globally Harmonized System of
Classification and Labelling of Chemicals
(GHS) • Under the GHS, proper labeling is composed of the following elements and their respective definitions 1. Signal Word – words such as “Danger” and “Warning” to indicate level of severity of hazard. 2. Hazard Statement – describes the nature of a hazardous product, including the degree of hazard. 3. Precautionary Statement – describes recommended measures taken to minimize effects after exposure to hazard 4. Pictogram – includes graphic elements that is intended to convey information 5. Product Identifier – used on a GHS label, matches the one used in MSDS 6. Supplier Identifier – contains the name, address, and telephone number of the supplier Guides for GHS Label Elements • Combination packaging for flammable substances (box as outer packaging and inner packaging) typical for a paint product. • Single packaging for flammable substances typical for a paint product Material Safety Data Sheet (MSDS) • Provides comprehensive information about a chemical to both employees and employers. • OSHA requires that all hazardous substances should be provided with MSDSs. A complete MSDS has 16 sections following the GHS:
• Identification • Stability and reactivity
• Hazards • Toxicological information • composition • Ecological information • First aid measures • Disposal considerations • Fire-fighting measures • Transport information • Accidental release measures • Regulatory information • Handling and storage • Other information • Exposure ontrols • Physical and chemical properties Operational controls on Chemical Management • Elimination – involves proper planning and designing during the formulation of products is necessary • Substitution – involves substituting raw materials containing toxic substances, e.g., lead driers or leaded pigments, with lead-free raw materials • Engineering control – eliminates or minimizes workplace hazards through the process of shielding or isolating a hazard by enclosing it so that worker exposure is minimized Industrial Ventilation • it is done when airborne contaminants cannot be removed by elimination or substitution method • way to minimize employee exposure to air contaminants by the removal and replacements of hazardous air with lean air • three types of ventilation: indoor air quality, dilution, and local exhaust Table 21.11 Advantages and Disadvantages of Two Types of Ventilation Administrative Control • The most common form of this control is by developing standard operating procedures on the proper handling of chemicals • Includes work instructions and guidance for the workers • Limiting the exposure hours of workers and the number of exposed can also be done Emergency Plans 1. Fire and explosion 2. Chemical Spills • Major • Minor 3. Medical emergencies 4. Emergency equipment, facilities, and resources Fire and Explosion Sources: 1. Fuels • Liquids: Gasoline, kerosene, toluene, xylene, acetone • Solids: Paper, plastics, packing materials, solid raw materials • Gas: Acetylene, carbon monoxide 2. Oxidizers • Gases: Oxygen, chlorine • Liquids: Hydrogen peroxide • Solids: Ammonium nitrate 3. Ignition Sources – sparks, open flames, static electricity, heat from equipment North American Emergency Response Guidebook (NAERG) provides additional fire fighting response procedures for various flammable or dangerous chemicals. This guidebook assists the emergency responders in developing initial decisions when arriving at the scene of emergency Chemical Spills • During a major chemical spill, it is recommended that workers must evacuate the workplace immediately and proceed to a safe area before contacting the emergency response team • During a minor chemical spill, contact the emergency response team or the safety officer for proper clean-up and disposal of waste Medical Emergencies • Inhalation of chemicals • Chemicals in the eyes • Chemicals in the skin • Ingestion or Injection of chemicals Emergency equipment facilities and resources • Exits and egress – provided in accordance with the provisions of the Fire Code of the Philippines, Division 5 • Fire extinguishers – must conform to the Philippine National Standards (PNS) • Emergency lighting – provided in case of power interruptions or emergencies • Automatic sprinklers and other suppression systems – these systems should be inspected, tested, and maintained in accordance with NFPA 2, standard for inspection Examples of Fire Extinguishers Available in the Market TYPE MATERIAL A Burning wood, paper, plastics, and fabrics