Applied Thermodynamics: BITS Pilani
Applied Thermodynamics: BITS Pilani
Thermodynamics
BITS Pilani Sachin U Belgamwar
Pilani Campus
Instructor-in-charge : Sachin U.
Belgamwar
Reference Books:
Notices: All notices related to this course will be put on the CMT Web/
Mech.Engineering notice board only.
Make-up Policy: Make-up will be given only to the genuine students. The request
application for make-up test must reach the Instructor-in-charge before
commencement of the scheduled test (documentary proof is essential). No make-
up will be allowed for the tutorial test and quizzes.
BITS Pilani, Pilani Campus
IRRVERSIBILITY AND
AVAILABILITY
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Pilani Campus
• Work Potential of the source: Amount of energy we
can extract as useful work.
• Dead State: State of the system when it is in
thermodynamic equilibrium with surrounding (the
properties are denoted by subscript 0).
• Surroundings: Everything outside system boundary.
• Immediate surroundings: portion of surroundings that
is affected by process.
• Environment: Region beyond immediate surroundings
T0
Q 1 Is the availability related to heat
T transfer Q
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T-S diagram for Constant
temperature energy source
1 2
3 4
a b
Ti Te
Q rev Q 0
S
T T0
WrevH . E . Q T0 S
dEC .V .
Q j m i htot ,i m e htot ,e W c.v.,act
dt
dSC .V . Qj
m i si m e se S gen,ac
dt Tj
dEC .V .
Q j mi htot i me htot e Q0 W
rev rev
dt
dSC .V . Q j
Q0rev
m i si m e se
dt Tj T0
BITS Pilani, Pilani Campus
Q0rev
S gen ,ac
T0
Q0 T0 S gen ,ac
rev
Wcv ,ac Q0 W
rev rev
W Wcv ,ac Q0
rev rev
dEC .V .
Q j m i htot ,i m e htot ,e
dt
dS Q
mi si m e se
j
T0 C .V .
dt Tj
BITS Pilani, Pilani Campus
Now combining the similar terms
and rearrange to become
T0
W rev
1 Q j
T
j
m i (htot ,i T0 si ) m e (htot ,e T0 se )
dEC .V . dSC .V .
T0
dt dt
v
BITS Pilani, Pilani Campus
I 1W 2rev 1W 2 ac
1 2
Q0 rev
T
S
0 gen ac