The Chemical World: Introductory Chemistry, 3

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Introductory Chemistry, 3rd Edition

Nivaldo Tro

Chapter 1
The Chemical
World

Roy Kennedy
Massachusetts Bay Community College
Wellesley Hills, MA
2009, Prentice Hall
What Is Chemistry?
• Observation: is sand different than water
• Test the similarities and differences between
sand and water.
Composition
Types & number of atoms, structure,
Properties
Chemical: how hot, how fast
Physical: size, ability to loose/gain electrons

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Chapter 1
Structure Determines Properties
• Everything is made of tiny particles called atoms and
molecules.
• Chemists study these particles, looking at the kinds,
numbers, structure, size which produce varying
chemical and physical properties.

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The Scientific Method
• Humans are by nature curious.
• Have you ever heard a 3 year old repeatedly ask
“why?”
• Science is just exploring nature.
• A scientists is just a person exploring.
• You begin to organize your thoughts into
Observation, you group those observations into
Hypotheses, using Experimentation, and
formulate Laws or Theories.
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Why Aren’t the Philosophers
Considered Scientists
Philosophers: Scientists:
• Observe nature. • Observe nature.
• Explain the behavior of • Explain the behavior of
nature. nature.
• Communicate and • Communicate and
debate ideas with other debate ideas with other
philosophers. scientists.
• Truth is revealed • Truth is revealed
through logic and through
debate. experimentation.
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Chapter 1
Observation
• Acquiring information or data

• Some observations are simple


descriptions
 “The soda pop is a liquid with a brown
color and a sweet taste. Bubbles are seen
floating up through it.”

• Some observations compare a


characteristic.
 “A 240-mL serving of soda pop contains
27 g of sugar.”

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Chapter 1
Hypothesis
• Looking at your observations you come up
with:
The sweetness of soda pop is due to the presence of
Sugar or
Aluminum

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Chapter 1
Experiments
• Test your hypotheses with a taste test: sugar and
aluminum.

Theory
• Sugar is sweet

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Chapter 1
Laws
• Typically a fact of nature, often a math
constant/number and unit.
Law of Conservation of Mass— “In a chemical
reaction matter is neither created nor destroyed.”
Speed of Light, E = mc2, Dalton’s Gas Law,
Universal Gas Constant, etc…
• Unlike California State laws, you cannot
choose to violate a scientific law 

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Chapter 1
Theories
• Explains how nature behaves.
Newton’s Gravitational Theory: how an apple falls
Dalton’s Atomic Theory: atoms look like…
Darwin’s Theory of Evolution: we always change
Einstein's Theory of Relativity: light is constant
• Used to predict future observations.

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Chapter 1
What’s the Difference Between a
Law and a Theory?

• Laws: Very specific, “What will happen”


often expressed in mathematical equations.
• Theories: Very general, “Why it will
happen,” often includes many “Laws”

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Chapter 1
Do we need science?
A history lesson in science
• A key feature of science are it’s experiments
• Experiments must be duplicated by other’s!!!
• Galileo (1564 - 1642) and Newton (1642 -
1727) worked on physics, the first Scientists
• Lavoisier is first to use the scientific method on
objects/nature on things that could not be
“Seen”
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Chapter 1
What causes Burning?
Phlogiston Theory
The mid-1700s theory of how wood or coal burned,
referred to as combustion.
• Wood and coal contained a substances called
phlogiston.
• When a substance burned it released all or some
of its phlogiston into the air .

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Problems with Phlogiston Theory
• When pure metals burn they should weigh
less (turns into calx)…however, metals
always weigh more when burned, that is the
clax always weighed more than the metal.
• The reverse experiment: If calx is heated, it
should remove phlogiston from the air be
converted back to the metal…however the
Burning Lens experiment by Lavoisier
observed “fixed air” being released back
into the air.
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The Great Burning Lens: Trying
to Find Phlogiston - ultimately it
was discredited

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Chapter 1
A Better Theory of Combustion
• Lavoisier purchased the most accurate
scales; scales that would cost over million
of dollars today
• Lavoisier carefully preformed his
experiments weighing them before and after
each combustion experiment.

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Chapter 1
A Better Theory of Combustion
Lavoisier proposed an alternative theory of
combustion based on his experiments:
1. When something burns, it can either remove or
combine with “fixed-air.”
2. He discovers Oxygen, hydrogen
Lavoisier literally, rewrites all chemistry textbooks.
Lavoisier’s idea starts modern chemistry based on
reproducible experimentation---backed with very
accurate measurements.
He is executed by a phlogiston believer-political
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Lord Kelvin, 1850’s
• "To measure is to know."
• "If you can not measure it, you can not
improve it."

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Chapter 1
How to Succeed in Chemistry
• Curiosity and your
imagination are your allies
Explore and investigate.
• Quantify and calculate
Even small differences can
be important!
• Commitment
Work regularly and carefully.

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Chapter 1
The Best Approach to
Learning Chemistry
• Learn the vocabulary of chemistry.
 Definitions and terms.
 How common vocabulary is applied to chemistry.
• Memorize important information.
 Names, formulas, and charges of polyatomic ions.
 Solubility rules.
• Learn and practice processes.
 Systematic names and formulas.
 Dimensional analysis.
• Do the questions and exercises in the chapter to test
your understanding and help you learn the patterns?
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Chapter 1

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