Halogenoalkanes

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What are halogenoalkanes?

Halogenoalkanes are similar


to alkanes but with one or
more of the hydrogen atoms
replaced by a halogen. trichloromethane

Halogenoalkanes can
contain more than one type
of halogen. For example,
CFCs (chlorofluorocarbons)
contain both chlorine and
chloro-pentafluoroethane
fluorine atoms.

Some halogenoalkanes are useful themselves, but many are


valuable intermediates in the production of other molecules.
Naming halogenoalkanes
A prefix is added to the name of the alkane depending on
what halogens are attached.
halogen prefix no. halogen atoms prefix
fluorine fluoro- one –
chlorine chloro- two di-
bromine bromo- three tri-
iodine iodo- four tetra-
five penta-
Another prefix is used to indicate how many atoms of each
halogen is present.
Numbers are used, where necessary, to indicate to which
carbon atom(s) each halogen is attached.
Primary, secondary and tertiary
A chain of carbon atoms can be represented by R when
drawing the structure. This is referred to as an R group.

 Primary (1°) halogenoalkanes


have one R group attached to
the carbon linked to the halogen.

 Secondary (2°) halogenoalkanes


have two R groups attached to the
carbon linked to the halogen.

 Tertiary (3°) halogenoalkanes


have three R groups attached to
the carbon linked to the halogen.

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