Scribd Logo
Upload

Welcome to Scribd!

  • 44 views

    Trial Ion Product TBP Durantekey

    Uploaded by

    Ananya Sharma - Lincoln Alexander SS (2132)
    1. The document discusses trial ion products (TIP), also known as trial Ksp or Q values, which are calculated when it is unknown if a solution is at equilibrium. A TIP is compared to the actual Ksp value to determine if a precipitate will form. 2. If the TIP is greater than the Ksp, a precipitate will form. If the TIP is less than the Ksp, no precipitate will form. If they are equal, the solution is saturated and at equilibrium. 3. Several examples are provided to demonstrate calculating TIPs to determine if precipitates will form when solutions are mixed. The key steps are writing dissociation reactions, determining ion concentrations, and

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd

    Trial Ion Product TBP Durantekey

    Uploaded by

    Ananya Sharma - Lincoln Alexander SS (2132)
    44 views14 pages
    1. The document discusses trial ion products (TIP), also known as trial Ksp or Q values, which are calculated when it is unknown if a solution is at equilibrium. A TIP is compared to the actual Ksp value to determine if a precipitate will form. 2. If the TIP is greater than the Ksp, a precipitate will form. If the TIP is less than the Ksp, no precipitate will form. If they are equal, the solution is saturated and at equilibrium. 3. Several examples are provided to demonstrate calculating TIPs to determine if precipitates will form when solutions are mixed. The key steps are writing dissociation reactions, determining ion concentrations, and

    Original Title

    5.-Trial-Ion-Product-TBP-durantekey-ppt.pptx

    Copyright

    © © All Rights Reserved

    Available Formats

    PPTX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    1. The document discusses trial ion products (TIP), also known as trial Ksp or Q values, which are calculated when it is unknown if a solution is at equilibrium. A TIP is compared to the actual Ksp value to determine if a precipitate will form. 2. If the TIP is greater than the Ksp, a precipitate will form. If the TIP is less than the Ksp, no precipitate will form. If they are equal, the solution is saturated and at equilibrium. 3. Several examples are provided to demonstrate calculating TIPs to determine if precipitates will form when solutions are mixed. The key steps are writing dissociation reactions, determining ion concentrations, and

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    44 views14 pages

    Trial Ion Product TBP Durantekey

    Uploaded by

    Ananya Sharma - Lincoln Alexander SS (2132)
    1. The document discusses trial ion products (TIP), also known as trial Ksp or Q values, which are calculated when it is unknown if a solution is at equilibrium. A TIP is compared to the actual Ksp value to determine if a precipitate will form. 2. If the TIP is greater than the Ksp, a precipitate will form. If the TIP is less than the Ksp, no precipitate will form. If they are equal, the solution is saturated and at equilibrium. 3. Several examples are provided to demonstrate calculating TIPs to determine if precipitates will form when solutions are mixed. The key steps are writing dissociation reactions, determining ion concentrations, and

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    You are on page 1of 14

    Solubility

    Trial Ion Product


    What we know so far…
    The concentrations in a Ksp expression are in fact
    equilibrium concentrations of ions in a saturated
    solution where the solid salt is at equilibrium with its
    respective ions in the solution.

    What if you are not sure if there is an equilibrium


    present?
    We calculate a trial ion product(TIP), also known as,
    Trial Ksp or Q.
    TIP meaning
    1- TIP > Ksp
    A precipitate forms
    2- TIP < Ksp
    No precipitate forms
    3- TIP = Ksp
    Solution is already at equilibrium (saturated)
    Another way to look at it…
    Ksp tells you the maximum product of the ion concentrations that
    would form a saturated solution.
    •Any value less than it won’t be saturated (no ppt)
    – Unsaturated solution.
    •Any value above it definitely will form a ppt
    – Supersaturated solution turning into saturated.
    •TIP= Ksp means it is already at equilibrium
    – A saturated solution.
    When two ionic solutions are mixed, and if one product has low solubility, a
    precipitate can potentially form.
    Pb(NO3)2(aq) + 2NaCl(aq) → PbCl2(s) + 2NaNO3(aq)
    low solubility
    1. 200.0 mL 0.10 M Pb(NO3)2 is mixed with 300.0 mL of 0.20 M NaCl, will a
    precipitate occur?
    You must write the dissociation equation for both

    Identify your potential precipitate


    Write the equation for the precipitate

    Pay extra attention to the source of the ions, and what their
    concentrations should be esp. after dilution!
    1. 200.0 mL 0.10 M Pb(NO3)2 is mixed with 300.0 mL of 0.20 M NaCl, will a
    precipitate occur?
    PbCl2(s) ⇌ Pb2+ + 2Cl-

    TIP = [Pb2+][Cl-]2

    Ksp = 1.2 x 10-5


    1. 200.0 mL 0.10 M Pb(NO3)2 is mixed with 300.0 mL of 0.20 M NaCl, will a
    precipitate occur?
    PbCl2(s) ⇌ Pb2+ + 2Cl-
    200 300
    0.10 M 0.20 M
    500 500

    0.040 M 0.12 M

    TIP = [Pb2+][Cl-]2

    TIP = [0.040][0.12] 2

    = 5.8 x 10-4 = 58 x 10-5

    Ksp = 1.2 x 10-5 TIP > Ksp ppt forms


    TRY: Will a precipitate form if 20.0 mL of 0.010M CaCl2 is mixed with 60.0 mL of
    0.0080 M Na2SO4?
    3. TOGETHER Will a precipitate form when equal volumes of 0.020 M AlCl3 and
    0.040 M AgNO3 are mixed.
    3. Will a precipitate form when equal volumes of 0.020 M AlCl3 and 0.040 M
    AgNO3 are mixed.
    The Cl- x 3
    AgCl(s) ⇌ Ag+ + Cl-
    1 1
    0.040 M 0.060 M
    2 2
    0.020 M 0.030 M

    TIP = [Ag+][Cl-]

    TIP = [0.020][0.030]

    = 6.0 x 10-4
    Ksp = 1.8 x 10-10

    TIP > Ksp ppt forms


    TRY: Will a precipitate form when equal volumes of 0.030 M NaCl and 0.020 M
    Pb(NO3)2 are mixed.
    4. Consider the two saturated solutions AgCl and Ag2CrO4. Which has the
    greater Ag+ concentration?

    AgCl ⇌ Ag+ + Cl- Ag2CrO4 ⇌ 2Ag+ + CrO42-


    s s s s 2s s

    Ksp = s2 Ksp = 4s3

    1.8 x 10 -10 = s2 1.1 x 10-12 = 4s3

    s = 1.3 x 10-5 M s = 6.5 x 10-5 M

    [Ag+] = 1.3 x 10-5 M [Ag+] = 2s = 1.3 x 10-4 M

    Ag2CrO4 has the greater Ag+ concentration


    Homework

    You might also like