3 Dispersed Systems
3 Dispersed Systems
3 Dispersed Systems
Food Dispersions
1. True solution
2. Colloidal dispersion
3. Emulsion
4. Foam
5. Gel
Dispersions
1. Continuous phase
2. Dispersed phase
May be solid, liquid, or gas.
True Solution
The dispersion of particle < 1 nm in liquid.
Examples: sugar, lactose, minerals, and vitamins.
Example: milk.
Emulsions
Liquid/liquid systems of 2 immiscible substances are called
emulsion. Substances or particle size = 10-100 microns.
Oil
Oil Oil H2O HO
2
Oil Oil
Oil Oil HO
2
H2O
Oil
Water Oil Oil Oil
Oil/Water Water/Oil
DESTABILIZATION OF THE DISPERSION
Oil Oil
Oil Oil Oil Oil
Oil
Oil Oil Oil Oil Oil
Oil
Oil Oil
Oil
Water
Water
Oil Water
Emulsifier Hydrophilic
group
Margarine
Hydrophobicgroup
Water Oil
CHEMICAL STRUCTURE OF EMULSIFIERS
Phospholipids (Lecithin) O
CH2 O C (CH2 )16 CH3
O
CH3 O CH O C (CH2 )14 CH3
HO CH
HO CH2 Hydrophobic
Hydrophilic
Di-glycerides ( di-stearate)
O
CH2 O
C (CH2 )16 CH3
O
CH O C (CH2 )16 CH3
HO CH2
Hydrophobic
Hydrophilic
Span 60 (sorbitan mono-stearate)
O O
H 2C CH CH 2 O C (CH 2 ) 16 CH 3
HO HC CH OH
C Hydrophobic
H OH
Hydrophilic
O C CH OH
Hydrophobic
CH 2 C
CH 2 O CH 2 CH 2 O CH 2 CH 2 OH
O CH 2 CH 2 OH
Hydrophilic
SOME DESIRABLE CHARACTERISTICS OF
FOOD EMULSIFIERS
1. Surface tension
2. Concentration of separate phase
3. Presence of foaming agent to lower surface tension
4. Viscosity of liquid - the higher the viscosity,
the more stable the foam.
5. Presence and thickness of adsorption layer
(a 3rd stabilizing material).
GEL