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The document discusses calculating properties of naphthalene using the Clausius-Clapeyron equation. It then: (1) Calculates the enthalpy of vaporization of naphthalene as 49095 J/mol using vapor pressure and temperature data. (2) Calculates the normal boiling point of naphthalene as 488K. (3) Calculates the enthalpy of vaporization at the boiling point as 49072 J/mol. It also calculates the melting point of ice under 50 bar of pressure as 272.80K.

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553 views9 pages

Presentation 2

The document discusses calculating properties of naphthalene using the Clausius-Clapeyron equation. It then: (1) Calculates the enthalpy of vaporization of naphthalene as 49095 J/mol using vapor pressure and temperature data. (2) Calculates the normal boiling point of naphthalene as 488K. (3) Calculates the enthalpy of vaporization at the boiling point as 49072 J/mol. It also calculates the melting point of ice under 50 bar of pressure as 272.80K.

Uploaded by

lucas
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Naphthalene, C10H8, melts at 80.2°C.

If the vapour pressure of the


liquid is 1.3 kPa at 85.8°C and 5.3 kPa at 119.3°C.
Use the Clausius–Clapeyron equation to calculate :
(a) The enthalpy of vaporization
(b) The normal boiling point
(c) The enthalpy of vaporization at the boiling point
6.9 (A) Diketahui
R : 8.3145 J/K Mol
P-1 : 10 Torr = 1.3 × 103 Pa
P-2 : 50 Torr = 5.3 × 103 Pa
T-1 : 85.8°C = 358.8 K
T-2 : 119.3°C = 392.3 K
𝑑𝑃 ∆𝑆 𝑑𝑃 ∆𝐻
= =
𝑑𝑇 ∆𝑉 𝑑𝑇 𝑇∆𝑉
𝑑𝑃 ∆𝐻𝑃
=
𝑑𝑇 𝑅𝑇 2
𝑑𝑃 ∆𝐻
CLASIUS = 2
𝑑𝑇
𝑃 𝑅𝑇
CLAPEYRON 𝑃2 𝑇2
𝑑𝑃 ∆𝐻
න =න 2
𝑑𝑇
𝑃1 𝑃 𝑇1 𝑅𝑇

𝑃2 ∆𝐻 1 1 𝑃2 ∆𝐻 1 1
ln = − ×( − ቇ ln = ×( − ቇ
𝑃1 𝑅 𝑇2 𝑇1 𝑃1 𝑅 𝑇1 𝑇2
𝑃2 ∆𝐻 1 1
ln = ×( − ቇ
𝑃1 𝑅 𝑇1 𝑇2
−1
THE 𝑃2 1 1
R × ln × − = ∆𝐻
𝑃1 𝑇1 𝑇2
ENTHALPY
−1
OF 8.3145 × ln
5.3 𝑘𝑃𝑎
×
1
−
1
= ∆𝐻
VAPORIZATI 1.3 𝑘𝑃𝑎 353.2 𝐾 392.3 𝐾

ON 49095 JΤMol = ∆𝐻
𝑃2 ∆𝐻 1 1
ln = ×( − ቇ
𝑃1 𝑅 𝑇1 𝑇2

R 𝑃2 1 1
൬ × ln ) + =
THE ∆𝐻 𝑃1 𝑇2 𝑇1
NORMAL
8.3145 5.3 𝑘𝑃𝑎 1 1
BOILING ቆ
49095 𝐽Τ𝑀𝑜𝑙
× ln
101.3 𝑘𝑃𝑎
)+ =
392.5 𝐾 𝑇1
POINT
1 1
−3
= 488 𝐾 = 𝑇1
2.048 × 10 𝑇1
𝑃2 ∆𝐻 1 1
ln = ×( − ቇ
𝑃1 𝑅 𝑇1 𝑇2
THE 𝑃2 1 1
−1
R × ln × − = ∆𝐻
ENTHALPY 𝑃1 𝑇1 𝑇2
OF 5.3 𝑘𝑃𝑎 1 1
−1

VAPORIZATI 8.3145 × ln × − = ∆𝐻
101.3 𝑘𝑃𝑎 488 𝐾 392.3 𝐾
ON AT THE
BOILING 49072 JΤMol = ∆𝐻
POINT
6.10 (A)
Calculate the melting point of a cube of ice under a pressure of
50 bar. Assume that the density of ice under these conditions is
ca. 0.92 g cm−3 and that of liquid water is 1.00 g cm−3.

Diketahui :
P = 50 Bar = 50 X 106 Pa
d-1 = 0.92 g cm−3
d-2 = 1.00 g cm−3
𝑑𝑃 ∆𝑆 𝑑𝑃 ∆𝐻
= =
𝑑𝑇 ∆𝑉 𝑑𝑇 𝑇∆𝑉
𝑑𝑃 × ∆𝑉 𝑑𝑃 × ∆𝑉
= 𝑑𝑇 න = න 𝑑𝑇
∆𝐻 ∆𝐻
∆𝑃 × ∆𝑉
= ∆𝑇
CLAPEYRON ∆𝐻
∆𝑃 × 𝑀 1 1
× ( − ) = ∆𝑇
∆𝐻 𝑃2 𝑃1
∆𝑃 × 𝑀 × 𝑇 1 1
× ( − ) = ∆𝑇
∆𝐻 𝑃2 𝑃1
𝑔
50 × 106 𝑃𝑎 × 18.02 × 273.15 𝐾 1 1
𝑚𝑜𝑙 × ( − ) = ∆𝑇
THE CHANGE 3
6.01 × 10 𝐽/𝑚𝑜𝑙 1 𝑔/𝑐𝑚 3 0.92 𝑔/𝑐𝑚 3

IN −0.35 𝐾 = ∆𝑇
TEMPERATUR
E
𝑇 50 𝐵𝑎𝑟 = 273.15 − 0.35 𝐾 = 272.80 𝐾

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