Solvay Novecare

Oil & Gas Product Line

2016
SOLVAY’S OIL & GAS BUSINESSES
Novecare Specialty Polymers Soda Ash & Derivatives
Offers a wide range of oil & gas Offers the broadest choice of polymers
specialty chemicals & formulations for of high performance to meet Oil & Gas Soda Ash & Calcium Chloride for
drilling, cementing, stimulation, critical requirements in many drilling and cementing applications
production & EOR applications applications
• Gelling Agents • Breaker • Downhole Pipe Lining, Rehabilitation
• Friction • Green Solvents Pipe Lining
Reducers • Buffer • Downhole Equipment components • Soda ash: used to treat most types
• Biocides • Biocide • HPHT Hydraulic Fluids of calcium ion contamination in
• Demulsifiers • Seals for Downhole & Offshore E&P freshwater and seawater muds, for
• Corrosion cement contamination
• Non-Emulsifiers Inhibitor • Insulation Structures for Offshore
• Foam Control • Foamer E&P and LNG
• LNG Cryogenic Systems • Calcium Chloride:
• Clay / Iron • Defoamer
Control • LNG Distribution Pipes & Fittings • Because of its thermally stability, it is
• Flow Improver used in Drilling to prevent walls of
• Dispersant • Scale Inhibitor • Offshore E&P Flexible Risers and the bore hole from closing up
• Emulsifier Flowlines
• Scavenger • Hydrocarbon Drying: used to absorb
• Cementing • Hydrate • Umbilicals water without modifying the chemical
Additives Inhibitor • Anti-Wear Tapes & Insulation Film composition of its finished products.
• Fluid-loss • Viscosity • Compatibility with Supercritical CO2
Additive Modifiers • Compressor Valve Plates
• Cross-linker • IFT Modifiers • Rod Guide

Solvay offers the products & experience to meet oilfield chemical needs

2 22 February 2018 (Confidential)

NOVECARE O&G PORTFOLIO
DRILLING CEMENTING STIMULATION/EOR PRODUCTION

UNDER Fluid Loss Additives Stimulation: Biocides

DEVELOPMENT Gas Migration Control Gelling Agents Scale Inhibitors
Emulsifiers Retarders Cross-Linker Emulsion Breakers
Accelerators Friction Reducers Water Clarifier
Spacers Iron Control Corrosion Inhibitors
Dispersants Clay Stabilizer Flow Improver
Viscosifiers H2S Scavengers
Thixotropic Agents EOR: Paraffin Inhibitor
Defoamers Surfactants Foamers
Polymers

3 22 February 2018 (Confidential)

A LEADER IN OILFIELD Clay / Iron Control 
SPECIALTY CHEMICALS Dispersant 
Drilling Weighting Agent
Related
Emulsifier 
Cementing Additive 
• A more robust O&G offer to Cementing
Related Fluid-loss Additive 
provide complete solutions Rheology Modifier 
to our customers Cross-linker 
Non-Emulsifier 
Friction Reducer 
• Enhanced understanding of Stimulation Acid 
Related
technologies & formulation Breaker 
capabilities to address Solvents 
market needs Buffer 
Biocide 
Corrosion Inhibitor 
Foamer 
• Transfer these technologies Production Defoamer 
into the emerging markets Related
Flow Improver 
capturing the growth in Demulsifier 
China, Russia, Australia & Flocculant
Argentina Scale Inhibitor 
Scavenger 
Hydrate Inhibitor 

4 22 February 2018 (Confidential)

 Active Segment

D C S P
Drill Cement Stim Prod

Cementing Additives
• Cement additives to ensure well integrity
• Largest supplier of specialty cementing
chemicals in North America
• Products for both off and on-shore use
• Fluid Loss Additives
• Polymer based chemistry
• Both liquid and dry additives
• Offering gas-migration control
• Working in a range of temperatures up to 400F
• Stable & reliable performance
• No impact on slurry rheology
• Other Additives offered by Solvay
• Gas Migration Control Additives, Set Retarders & Schematic representation of
cement placement versus
Accelerators, Spacers, Dispersants, Lost Circulation rock formation and filter cake
Aids, Suspension Aids, Viscosifiers formation by fluid loss
control additive

5 22 February 2018 (Confidential)

 PRODUCT LINE:
STIMULATION:
• Gelling Agents
• Cross-Linker
• Flow Improvers
• Biocides

EOR:
• Surfactants
• Polymers
STIMULATION • Biocides
& EOR

6 22 February 2018 (Confidential)

 Active Segment

D C S P
GELLING AGENTS & CROSS-LINKER Drill Cement Stim Prod

Linear gel
• Worldwide guar leader Linear gel

• Back-integration through our 50 year

Hichem Joint Venture that is the world’s
largest supplier of guar splits, powder &
slurries
• Ability to supply native guars & full range
Cross-linked gel
of derivative guars (HPG, CMG, CMHPG) Cross-linked gel

• Derivative production capabilities at three

plants with 2 different processes
• Ability to formulate guar slurries
• Know-how to develop custom derivatives
for customers

7 22 February 2018 (Confidential)

 Active Segment

D C S P
Drill Cement Stim Prod

FRICTION REDUCERS
• Friction Reducer leader with 2 plants in US
• Unique technology and manufacturing
processes creating significant competitive
advantage via –
• Product stability and hydration speed
• Ease of use at low temperatures
• Environmentally friendly product profile
• Total flexibility to produce emulsion and
inverse emulsion polymers tailored to meet
customer needs
• Excellent performing FR’s for ultra-high
salinity/TDS waters
• Cationic, Anionic, Nonionic and
Polyampholytic FR’s
• Competitive offer for fresh water FR’s
• FR’s for acidizing

8 22 February 2018 (Confidential)

TOLCIDE®4FRAC : The First Use of the
Polymer Compatibility Technology

* 0.05% anionic polyacrylamide solution, pH~5 * 5 lb / 1000 gallon native guar (i.e.TIGUAR ® 322), pH~5

• No loss in PAM or guar efficacy regardless of dose level

• Controls microbes and maintains rheology
• Flexibility to treat any system effectively.

9 22 February 2018 (Confidential)

 PRODUCT LINE:
• Biocides
• Scale Inhibitors
• Emulsion Breakers
• Water Clarifier
• Corrosion Inhibitors
• Flow Improver
• H2S Scavengers
• Paraffin Inhibitor
• Foamers
PRODUCTION

10 22 February 2018 (Confidential)

 BIOCIDES - INTEGRITY MANAGEMENT –
MICROBIOLOGICAL CONTROL
• SOLVAY is the leading producer of THPS biocides (TOLCIDE ® PS) & FeS
dissolvers (BRICORR A series®)
• TOLCIDE ®PS50A / BRICORR®50A
• Third generation THPS formulation
• 50 & 70% ai grades available
• Enhanced FeS control with BRICORR®50AE
• Shot and continuous applications
• Applications
• MIC control / FeS dissolution / Schmoo control
• Water injection / PWRI / Topsides / Flowlines

• Quaternary ammonium compounds ( Quats) – non-regulated markets only

• Di Alkyl DiMethyl Ammonium Chlorides
• DiDecylDiMethyl Ammonium Chloride (“DDAC”)
• Benzalkonium Chlorides
• Coco Dimethyl Benzyl Ammonium Chloride (“Coco BAC” / ADBAC)
• Alkyl Trimethyl Ammonium Chlorides
• CTAC
11 22 February 2018 (Confidential)
 Active Segment

D C S P
SCALE INHIBITORS Drill Cement Stim Prod

• AQUARITE ® End-capped P polymers

• AQUARITE ® ESL : highly suitable HT/HP/HS and low pH brines – good environmental
profile

• RHODAFAC ® BN936/S : TEAPE

• High performance, iron tolerant topside inhibitor

12 22 February 2018 (Confidential)

 Active Segment

D C S P
AQUARITE ® ESL Drill Cement Stim Prod

 Biodegradable and Low

Aquatic Toxicity
environmentally acceptable
Polymer
OECD306 data
• 33% biodegradation after 28 days
• 79% biodegradation after 60 days
 Able to be used in high
temp (5 to 250°C) and high
pressure systems
 Maximum adsorption
New unique patented technology, “End capped efficiency on surfaces
Phosphonated polymer”. (includes crystalsurfaces)
High performance polymeric scale inhibitor for  Proven performance in the
control of carbonate, sulphate and exotic scale. North Sea and Approved by
APPLICATIONS: Multi-functional Products
CENPES
Squeeze treatment High Temperature Systems  Good Solvent compatibility
Topside High Salinity Systems
Thermal EOR Severe Scaling Environment
Subsea Flowlines Exotic Scale Control (ZnS, PbS)

13 22 February 2018 (Confidential)

 Active Segment

D C S P
DEMULSIFIERS Drill Cement Stim Prod

• Wide range of surfactant-based

demulsifiers/ emulsion breakers
• Resin Alkoxylates
• Polyol/acrylic copolymer
• Polyol
• Ester
• Diepoxides
Simulated performance of
• Polyglycol competitive (above) vs
Solvay (below) Demulsifiers

• Unique technical know-how to adjust

formulations and address all types of
demulsifier needs

• Product allows for better water

recycling by improving oil/water
separation yields

• Green solvent formulations available

14 22 February 2018 (Confidential)

 Active Segment

D C S P
WATER CLARIFIER – RHODASURF DE Drill Cement Stim Prod

RHODASUF DE
 New cationic polymer
developed to treat oil in water
emulsion.
 High performance / lower
dosages
 Ready for use, do not need
previous dilution.
 Approved by Cenpes

APPLICATIONS:
Topside Oil in Water emulsions Petrochemical Quench Water Systems
Refinery Dessalting Brine Water Clarification
Refinery Tanking Offspecs Waste Water Treatment

15 22 February 2018 (Confidential)

 Active Segment

D C S P
CORROSION INHIBITORS Drill Cement Stim Prod

• Aids in eliminating pipeline leakage &

hydrocarbon spills
• Extends equipment life
• Used either in drilling mud or injected
into produced fluid for pipeline
protection.
• Key organic nitrogen compounds as
corrosion inhibitor:
• Neutralizing amines
• Film forming amines
• Imidazoline Miramine® series
• Fatty amine or fatty ethoxylated amine
Fentacare series
• Phosphate ester Lubrhophos®/
Rhodafac® series
• Quats Fentacare series

16 22 February 2018 (Confidential)

 Active Segment

D C S P
H2S SCAVENGERS - SOUR GAS Drill Cement Stim Prod

MANAGEMENT
• MDEA and activated MDEA
• (N-methyl-diethanolamine),
• FENTAMINE® DC-EP

• MACKTERRA® HHT78
• (Hexahydro-1,3,5-tris(hydroxyethyl)-s-triazine)

17 17 22 February 2018 (Confidential)

 Active Segment

D C S P
FOAMERS Drill Cement Stim Prod

• Offer a wide range of technologies to

address all challenges of producing gas
from mature, depleted wells
• Alkyl Ether sulphate for low temperature, low
salt systems
• Amphoteric: Betaines and Sultaines, high salt
high temperature wells
• Alpha olefin sulphonate for high temperature
low salt
• Optimised formulations
• Performance optimisation (foam quality,
stability, temperature, condensate)
• Cost/efficiency optimisation
• Winterisation of blends
• Global industrial footprint

18 22 February 2018 (Confidential)