Renewable Energy Sources

Renewable Energy Sources

Lecture Question
What are the renewable energy sources? Make a list, as
comprehensive as possible.
What are the environmental impacts of these energy sources?

Renewable Energy Sources

Radiant solar energy
Solar heating (passive and active), solar power plants, photovoltaic
cells
Biomass energy
Direct: combustion of biomass
Indirect: chemical conversion to biofuel
Wind energy
Hydro energy
Geothermal energy
Power plants, direct use, heat pumps
Ocean energy
Tidal; salinity-driven
 Hydro Energy
Advantages
Cheap to operate
Long life and lower operating costs than all other power plants
Renewable
High yield
Lower energy cost than any other method
Pretty plentiful
Some countries depend almost entirely on it
Not intermittent (if reservoir is large enough)
Reservoirs have multiple uses
Flood control, drinking water, aquaculture, recreation
Less air pollution than fossil fuel combustion
 Hydro Energy
Disadvantages:
Human population displacement
More significant breeding ground for disease
Reduces availability of water downstream
Ecosystem impacts
Barriers to migrating fish
Loss of biodiversity both upstream and downstream
Coastal erosion
Reduces nutrient flow (dissolved and particulate)
Water pollution problems
Low dissolved oxygen (DO)
Increased H2S toxicity; other DO-related problems
Siltation a big problem (also shortens dam life)
Air pollution
Actually may be a significant source of GHGs (CH4, N2O, CO2)
Decommissioning is a big problem
The Size Issue
Many (most) of the above problems are significantly worse for larger dams
However, small dams have shorter lifetimes, less capacity, and are more
intermittent
 Wind Energy
How it works
Wind turbines directly generate electricity
Quite efficient (not a heat engine)

Wind Energy Potential

shading gives potential for in-
state electrical needs
numbers give total potential
for total US needs
 Wind Energy
Advantages
High net energy yield
Renewable and free
Very clean source of energy
No pollution (air or water) during operation
Long operating life
Low operating/maintenance costs
Can be quickly built; not too expensive
Now almost competitive with hydro and fossil fuels
Land can be used for other purposes
Can combine wind and agricultural farms
 Wind Energy
Disadvantages
Energy storage issues
An intermittent source of energy; need backup (eg stored energy)
for low-wind days
Or must be connected to the electrical grid
Only practical in areas that are windy enough
Visual pollution
Danger to birds
New (slow turning) designs largely eliminate this problem
Low energy density of wind
Must use large areas of land
 Biomass Energy
What is it?
Biomass energy is the use of living and recently dead biological material as
an energy source
Ultimately dependent on the capture of solar energy and conversion to a
chemical (carbohydrate) fuel
Theoretically it is a carbon neutral and renewable source of energy
How it works?
Traditional: forest management, using wood as fuel
Use of biodegradable waste
Examples: manure, crop residue, sewage, municipal solid waste
Recent interest in agricultural production of energy crops
Should be high yield and low maintenance
Examples: corn, sugarcane, switchgrass, hemp, willow, palm oil, rapeseed, and
many others
Does not have to be a food crop
Recent interest in bioengineered (GM) plants as fuel sources
Production of a liquid or gaseous biofuel
Biogas due to the breakdown of biomass in the absence of O 2
Includes capture of landfill methane
Bioethanol from fermentation, often from corn. Cellulosic bioethanol is usually
from a grass (switchgrass)
Biodiesel from rapeseed and other sources
 Biomass Energy
Carbon neutral
CO2 ultimately released in energy generation is recently captured and so ideally
does not change total atmospheric levels
Carbon leaks can result in a net increase in CO2 levels
Sequestration in soil can result in a net decrease in CO2 levels
 Biomass Energy
Advantages
Versatile
Renewable
No net CO2 emissions (ideally)
Emits less SO2 and NOx than fossil fuels
Disadvantages
Low energy density/yield
In some cases (eg, corn-derived bioethanol) may yield no net energy
Land conversion
Biodiversity loss
Possible decrease in agricultural food productivity
Usual problems associated with intensive agriculture
Nutrient pollution
Soil depletion
Soil erosion
Other water pollution problems
 Geothermal Energy
How it works
Geothermal power plants
Use earths heat to power steam turbines
Geothermal direct use
Use hot springs (etc) as heat source
Geothermal heat pumps
Advantages
Renewable
Easy to exploit in some cases
CO2 production less than with fossil fuels
High net energy yield
Disadvantages
Not available everywhere
H2S pollution
Produces some water pollution (somewhat similar to mining)
 Radiant Solar Energy
How it works
Solar power plants
Steam produced to turn turbine
Solar heating
Active and passive systems
Photovoltaic cells
Solar batteries use special semiconductors
Advantages
Renewable and free
High energy yield
A very clean source of energy
No air/water pollution during operation
Low operating costs
Will pay for themselves over time
Disadvantages
Intermittent source
Energy storage issues
Low energy density
Requires pretty much land
 The Hydrogen Economy
Lecture Questions
What is the hydrogen economy?
Explain how the hydrogen economy could potentially serve as the basis
for a renewable energy system that emits little or no air pollution

Definition
The Hydrogen Economy is a hypothetical large-scale system in which
elemental hydrogen (H2) is the primary form of energy storage
Fuel cells would be the primary method of conversion of hydrogen to
electrical energy.
Efficient and clean; scalable
In particular, hydrogen (usually) plays a central role in transportation.
Potential Advantages
Clean, renewable
Potentially more reliable (using distributed generation)
BUT many roadblocks including potential showstoppers
Poses great technological challenges for efficient hydrogen production,
storage, and transport
Components of the Hydrogen Economy

Infrastructure needs
Production
Storage
Delivery
End use
Hydrogen as a Transportation Fuel
 Hydrogen Production
Fossil Fuels
Steam Reforming of Natural Gas
Combination of methane and steam produces hydrogen gas
Carbon monoxide is also produced
The water gas shift reaction can produce further hydrogen from the
carbon monoxide. Carbon dioxide is produced too.
Most economical; main current method
Carbon sequestration one method to reduce CO2 emission
Partial Oxidation (POX) of Hydrocarbons
HC partially oxidized to produce hydrogen and carbon monoxide
Coal Gasification
Gasified at high temps, then processed
Can also be used to get hydrogen from biomass
 Hydrogen Production
Electrolysis
Efficiencies 70-85%
Produces highest purity of hydrogen
Currently, the electricity consumed is usually worth more than
the hydrogen produced
Experimental methods
Biological hydrogen production
Direct photolysis
Thermolysis
Renewable Solar Paths to Hydrogen
Solar Energy

Heat Biomass

Mechanical
Energy

Electricity

Conversion

Thermolysis Electrolysis Photolysis

Hydrogen
 Hydrogen Storage
Large-Scale Stationary Storage
Underground in depleted oil/gas fields, aquifers, caverns
Intermediate- and Small-Scale Stationary/Mobile Storage
The focus of most current research
As a liquid
Advantage: higher energy density, cheaper transport
Disadvantage: economic/energy cost of liquefaction is significant
As a compressed gas
Probably best short-term method, particularly with advanced materials to decrease
weight
Advantages
Rapid charging/discharging
Lower costs than liquid storage
Disadvantages:
Low energy density, Probably still acceptable for motor vehicles
Safety (esp public perception)
Metal hydrides
Hydrogen is absorbed under pressure, released when heated
Less filling pressure needed
Low energy density, long recharge time, expensive
Experimental Methods
Improved hydrides; carbon nanotubes; many other materials (eg conversion to
ammonia)
 Chemical Batteries
Lecture Questions
What are batteries and how do they work?
Whats the difference between a regular and a rechargeable battery?
Why are rechargeable batteries sometimes referred to as storage
batteries?

Chemical batteries are based on reduction-oxidation (redox) reactions,

which are reactions where electron transfer occurs.
The oxidation half-reaction occurs at the anode
Electrons flow from the anode, through an external circuit, and to the
cathode, where the reduction half-reaction occurs
Chemical batteries are a very efficient method of generating electricity
Efficiencies of 80% are regularly achieved
Significantly (2-3 times) more efficient than heat engines
Rechargeable batteries can be hooked up to an external source of
electricity to regenerate the redox reactants through electrolysis.
Rechargeable batteries thus provide a means of storing electricity in
chemical form. They are thus sometimes called storage batteries.
The Alkaline Battery
The Lead Storage Battery
 Fuel Cells
Lecture Questions
What is a fuel cell and how does it work?
What is distributed generation?

A fuel cell is basically a battery in which the reactants are

continually supplied to the electrodes, and the products are
continually removed.
Much more efficient (2-3 times) than heat engines at generating
electricity
Most common type of fuel cells based on hydrogen (there are
others)
Fuel cells are scaleable
Large ones can power homes or neighborhoods
Small ones can be used in appliances
Distributed generation is a decentralized power system consisting of
hydrogen generators and fuel cells
A Hydrogen Fuel Cell
Hydrogen Fuel Cells: Scalable
Polymer Electrolyte Fuel Cell
Alkaline Fuel Cell (AFC)