Carboxylic Acids Asam Karboksilat
Carboxylic Acids Asam Karboksilat
Carboxylic Acids Asam Karboksilat
Asam karboksilat
Introduction
The functional group of carboxylic acids
consists of a CO with OH bonded to
the same carbon.
Carboxyl group is usually written COOH.
Aliphatic acids have an alkyl group bonded
to COOH.
Aromatic acids have an aryl group.
Fatty acids are long-chain aliphatic acids.
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Common Names
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Aromatic Acids
Br
HOOCCH2CHCH2CH2COOH
3-bromohexanedioic acid
-bromoadipic acid
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Structure of Formic Acid
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Solubility
Water solubility decreases with the length of the
carbon chain.
With up to 4 carbons, acid is miscible in water.
Very soluble in alcohols.
Also soluble in relatively nonpolar solvents like
chloroform because the hydrogen bonds of the
dimer are not disrupted by the nonpolar solvent.
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Acidity of Carboxylic Acids
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Acetate Ion Structure
potassium 3-chloropentanoate
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Properties of Acid Salts
Usually solids with no odor.
Carboxylate salts of Na+, K+, Li+, and
NH4+ are soluble in water.
Soap is the soluble sodium salt of a
long chain fatty acid.
Salts can be formed by the reaction of
an acid with NaHCO3, releasing CO2.
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Hydrolysis of Fats and Oils
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Alkyne Cleavage Using Ozone or
KMnO4
OLi OH O
O
2 R' Li H3O+
R C OH R C OLi R C OH R C R' + H2 O
R' R'