AIR POLLUTION
By
Bibhabasu Mohanty
Assistant Professor
Department of Civil Engineering
SAL Institute of Technology &
Engineering Research
CONTENT
Definition, Composition of
atmospheric air, Classification and
sources of air pollutants. Effects of
air pollution on human, plant and
material, Air pollution control
methods, equipment and safety.
WHAT IS POLLUTION ???
Pollution
is change in background conc..
Any
substance introduced into the
environment that adversely affects the
usefulness of a resource.
Pollution
happens because no process is
100% efficient; each process produces
pollution.
AIR POLLUTION
Air
pollution defined as the of one or more
contaminants or combinations in such
quantities and of such durations as may be or
tend to be injurious to human, animal or
plant life, or property, or which unreasonably
interferes with the comfortable enjoyment of
life or property or conduct of business.
THE ATMOSPHERE
120
200
90
80
70
60
40
30
(Sea
Level)
Mesopause
Mesosphere
Stratopause
55
45
35
25
15
Tropopause
Ozone layer
Heating from the earth
Troposphere
0
40
Temperature (C)
Stratosphere
40
65
Heating via ozone
Thermosphere
80
1,000
75
10
Pressure
800
Temperature
20
600
50
400
100
Altitude
(kilometers)
110
Altitude (miles)
Atmospheric pressure (millibars)
80
120
Pressure = 1,000
millibars at
SOURCE AND CLASSIFICATION
Natural
Man-
made or anthropogenic
Natural-
pollen grains, volcanic eruptions,
forest fires, dust storms, spores, bacteria
and other microorganisms.
Man- made- industrial units, thermal
power plants, automobile exhausts, fossil
fuel burning, mining, nuclear explosions,
SOURCE AND CLASSIFICATION
Stationary
Mobile
Point
source- large stationary source
Area source- small stationary source
and mobile source with indefinite routes
Line source- mobile source with definite
routes
AIR POLLUTANTS
Substance dwelling temporarily or permanently in the
air.
Alters the environment by interfering with the health,
the comfort, or the food chain, or by interfering with the
property values of people.
A pollutant can be solid (large or sub-molecular), liquid
or gas .
It may originate from a natural or anthropogenic source
(or both).
It
is estimated that anthropogenic sources
have changed the composition of global air by
less than 0.01%.
Even
a small change can have a significant
adverse effect on the climate, ecosystem and
species on the planet.
CLASSIFICATION OF POLLUTANTS
Pollutants
can be grouped into two categories:
(1) primary pollutants, which are emitted
directly from identifiable sources, and
(2) secondary pollutants, which are
produced in the atmosphere when certain
chemical reactions take place among primary
pollutants.
PRIMARY POLLUTANTS
The major primary pollutants include:
particulate
matter (PM),
sulfur dioxide,
nitrogen oxides,
volatile organic compounds (VOCs),
carbon monoxide, and
lead.
SECONDARY POLLUTANTS
Some
primary air pollutants react with
one another or with other chemicals to
form secondary pollutants.
sulfuric acid is one example of a
secondary pollutant.
Air pollution in urban and industrial areas is
often called smog.
Photochemical smog, a noxious mixture of
gases and particles, is produced when strong
sunlight triggers photochemical reactions in
the atmosphere.
The major component of photochemical smog is
ozone.
Atmospheric
MAJOR POLLUTANTS SOURCES
AND EFFECTS
Carbon monoxide (CO)- colorless, odorless, tasteless gas.
No effect at normal conc. (0.1ppm)
but higher conc. seriously affect.
Volcanoes, natural gas emissions,
seed germination contribute to CO.
Transport sector contribute 75% CO.
Residential wood burning 10%, industrial process
15% CO.
Effects:
Reduce oxygen carrying capacity of blood.
Decrease in vision and causes cardio vascular
disorders.
Carbon dioxide (C02)- Fossil fuel combustion.
Jet plane use O2 and release CO2.
Burning
Effects:
Causes headache and nausea.
Effect on climate, increase global temp.
Oxides of nitrogen NOx group contains NO, NO2,
N2O.
Fuel combustion in automobiles and industries.
Lightening.
Forest fires.
Natural ionizing radiations.
Effects:
Reduce blood carrying capacity.
Causes lung problems.
Oxides of sulphur generally called SOx, include SO2,
SO3.
67% SOx pollution due to volcanic activities and other
natural sources.
Remaining due to fossil fuel burning, transportation.
Industrial activities.
Effects:
Respiratory problems
Marbles, clothes, paper, leather also affected.
Plants also heavily affected.
Hydrocarbons (HC) these include methane, ethylene,
acetylene, terpenes etc.
Sources include coal fields, natural fires.
Incomplete combustion
Forest fires
Agricultural burning
Effects:
Carcinogenic effect
Form ozone and PAN which are harmful.
Damage plants, rubber materials, fabric and paints.
PARTICULATE MATERIALS
Particles of different substances suspended in the
air
In the form of solid particles and liquid droplets
Particles vary widely in size
Different particulate materials are aerosols, dust,
smoke, fumes, mist, fog, fly ash etc.
Fine particles come from a variety of sources:
-diesel trucks and buses
-construction equipment
-power plants
-woodstoves
-wildfires
Also, Chemical reactions in the atmosphere can
transform gases into fine particles.
Effects:
Premature death
Aggravated asthma
Acute respiratory symptoms
Chronic bronchitis
Decreased lung function (shortness of breath)
People with existing heart and lung disease, as
well as the elderly and children, are particularly
at risk
EFFECTS OF AIR POLLUTION ON
HUMAN
around
30-40% of cases of asthma and 20-30% of
all respiratory disease.
effect our health in many ways with both short
term and long term effect.
Short term effect are: irritation to nose, eye,
throat, bronchitis, headache etc.
Long term affect are: lung disease, chronic
respiratory problem, damage to heart, brain,
eyes etc.
Eye irritation due to NOx, O 3, PAN,
particulates.
Nose and throat due to SO2, NOx etc.
Gaseous
pollutants like H2S, SO2, NO2 and
hydrocarbons cause odor nuisance.
Irritation of respiration tract caused by SOx,
NOx, CO, O3.
Increase in mortality.
High conc. of SO2, NO2 and SPM causes
bronchitis and asthma.
CO and NO react with haemoglobin and reduce
O2 carrying capacity of blood.
Heavy metals like lead can cause poisoning.
High conc. cause damage to liver and kidney.
FACTORS AFFECTING HUMAN
HEALTH
Nature of the pollutants
Concentration of the pollutants
Duration of exposure
State of health of receptor
Age group of the receptor
EFFECTS OF AIR POLLUTION ON
PLANT
Decrease
yield in agriculture.
Suppressed
Leaf
growth of vegetables.
injury and damage to young plants.
Decreased
growth rate and increased
death rate.
EFFECTS OF AIR POLLUTION ON
MATERIALS
Corrosion of metals due to SO2 in presence of oxygen
and moisture is converted into H2SO4 acid.
H2SO4 acid react with limestone, marble and other
building materials to cause deterioration.
Soiling and eroding of building materials.
SO , O H S and aerosols damage protective coating
2
3,
2
and paints of the surface.
O and PAN causes cracking of rubber and various
3
electrical insulations.
Deterioration of art work due to SPM.
AIR POLLUTION CONTROL
1.
2.
Cannot be fully prevented but can be
controlled.
Preventative measures
Control measures using equipments.
Preventative measures (source control)
. Selection of suitable fuel. (Low sulphur coal in
power plant, using of CNG)
. Modification in industrial process.
. Selection of suitable site and zoning for industrial
unit.
Control measures
When source control not possible some measures
taken to prevent pollution.
Collecting pollutants by using equipments.
Destroying the pollutants by thermal or catalytic
combustion.
Changing the pollutants to less toxic form.
By releasing the pollutants through tall chimneys
for greater dispersion.
PREVENTATION BY LAWS
Various laws has been established for the menace
of air pollution.
Air (Prevention & control of pollution ) Act,1981.
Air (Prevention & control of pollution )
Amendment Act,1987.
Motor vehicle Act, 1988.
Air (Prevention & control of pollution) Union
Territories Rules, 1983.
Environment Protection Act, 1986.
The government is trying to
remove the use of leaded petrol, a major
cause of air pollution.
the industrial acts are implemented to
control the harmful emission of gases.
the natural management team work to
minimize the effect of various natural
disaster like forest fire, volcanic eruption
that are causes of air pollution.
AIR POLLUTION CONTROLLING
EQUIPMENTS
Gravitational settling chamber
Used to remove particles with size greater than
50 m.
Velocity of flue gas reduced in large chamber.
Particles settle under gravitational force.
Advantages
Low initial cost.
Easy to design.
Low pressure drop.
Low maintenance cost.
Dry and continuous disposal of solid particulates.
Disadvantages
Require large space.
Less collection efficiency.
Only larger size particles can be collected.
Cyclone separator
Centrifugal force is utilized to
separate the particulate matter.
It can remove 10 to 50 m
particle size.
Used mostly in industries.
Advantages
Low initial cost.
Require less floor area.
Simple construction and maintenance.
Can handle large volume of gas at high temp.
Disadvantages
Requires large head room.
Less efficiency for smaller particles (<10m).
Sensitive to variable dust load and flow rate.
Electrostatic precipitators
Works on the principle of electrical charging of
particulate Matter (-ve) and collecting it in a
+ve charged surface.
99% efficiency.
Can remove particle size range of 0.1 m to 1
m.
Advantages
High collection efficiency.
Particles may be collected dry or wet.
Can be operated at high temp. (300-450c).
Maintenance is normal.
Few moving parts.
Disadvantages
High initial cost.
Require high voltage.
Collection efficiency reduce with time.
Space requirement is more.
Possible of explosion during collection of
combustible gases or particulates.
Fabric filters
Flue gas is allowed to
pass through a woven
Fabric, which filters out
Particulate matter.
Small particles are
retained on the fabric.
Remove particles up to 1 m.
Its efficiency up to 99%.
Advantages
Higher collection efficiency for smaller than
10 m particle size.
Performance decrease becomes visible, giving
prewarning.
Normal power consumption.
Disadvantages
High temp. gases need to be cooled.
High maintenance and fabric replacement cost.
Large size equipment.
Fabric is liable to chemical attack.
Scrubbers
Particulate matters are incorporated into liquid
droplets and removed from the gas stream.
Different types of scrubbers are- Spray tower
- Venturi scrubber
- Cyclone scrubber
Flue gas made to push up against a down falling
water current.
Particulate matter mix up with water thus falls
down and gets removed.
Spray tower
Cyclone scrubber
Advantages
Simultaneously remove particulates and gaseous
pollutants.
Hot gases can be cooled down.
Corrosive gases can be recovered and neutralize.
Disadvantages
Lot of waste waters produced.
Poses freezing problem in cold countries.
Maintenance cost is high when corrosive materials are
collected.
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